Search Results - "Milanov, Andrian"
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Synthesis, Characterization, and Thermal Properties of Homoleptic Rare-Earth Guanidinates: Promising Precursors for MOCVD and ALD of Rare-Earth Oxide Thin Films
Published in Inorganic chemistry (01-12-2008)“…Eight novel homoleptic tris-guanidinato complexes M[(N i Pr)2CNR2]3 [M = Y (a), Gd (b), Dy (c) and R = Me (1), Et (2), i Pr (3)] have been synthesized and…”
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Journal Article -
2
Homoleptic Gadolinium Guanidinate: A Single Source Precursor for Metal−Organic Chemical Vapor Deposition of Gadolinium Nitride Thin Films
Published in Journal of the American Chemical Society (02-12-2009)“…Deposition of a rare earth nitride thin film using a chemical gas phase deposition technique is reported for the first time. The gadolinium tris-guanidinate…”
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3
Atomic Layer Deposition of Gd2O3 and Dy2O3: A Study of the ALD Characteristics and Structural and Electrical Properties
Published in Chemistry of materials (28-02-2012)“…Gd2O3 and Dy2O3 thin films were grown by atomic layer deposition (ALD) on Si(100) substrates using the homoleptic rare earth guanidinate based precursors,…”
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4
Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films
Published in Chemistry of materials (22-03-2011)“…Metal−organic chemical vapor deposition (MOCVD) of thin films of two representative rare-earth nitrides is reported here for the first time. Four homoleptic,…”
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5
Growth of Crystalline Gd2O3 Thin Films with a High-Quality Interface on Si(100) by Low-Temperature H2O-Assisted Atomic Layer Deposition
Published in Journal of the American Chemical Society (13-01-2010)“…This work documents the first example of deposition of high-quality Gd2O3 thin films in a surface-controlled, self-limiting manner by a water-based atomic…”
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6
Lanthanide Oxide Thin Films by Metalorganic Chemical Vapor Deposition Employing Volatile Guanidinate Precursors
Published in Chemistry of materials (24-11-2009)“…The application of two novel metalorganic complexes, namely the isostructural tris(N,N’-diisopropyl-2-dimethlyamido-guanidinato)gadolinium(III) (1) and…”
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Journal Article -
7
Rare-earth substituted HfO2 thin films grown by metalorganic chemical vapor deposition
Published in Thin solid films (01-05-2012)“…Thin films of HfGdOx and HfDyOx were deposited by metalorganic chemical vapor deposition (MOCVD) utilizing guanidinate precursors for Hf, Gd and Dy. The close…”
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Journal Article Conference Proceeding -
8
Influence of process parameters on the crystallinity, morphology and composition of tungsten oxide-based thin films grown by metalorganic chemical vapor deposition
Published in Thin solid films (01-11-2012)“…The growth of tungsten oxide (WO3) based thin films was achieved via metalorganic chemical vapor deposition using an all-nitrogen coordinated tungsten…”
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Journal Article Conference Proceeding -
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Heteroleptic Guanidinate- and Amidinate-Based Complexes of Hafnium as New Precursors for MOCVD of HfO2
Published in European Journal of Inorganic Chemistry (01-04-2010)“…The synthesis and characterization of four new heteroleptic complexes [Hf{η2‐(iPrN)2CNMe2}2Cl2] (1), [Hf{η2‐(iPrN)2CNMe2}2Me2] (2), [Hf{η2‐(iPrN)2CMe}2Cl2]…”
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Book Review -
10
Bis(2-butyl-N,N′-diisopropylamidinato)dichlorohafnium(IV)
Published in Acta crystallographica. Section C, Crystal structure communications (01-07-2005)“…The title compound, [Hf(C11H23N2)2Cl2], is a monomeric hafnium(IV) complex containing two bidentate amidinate ligands and two cis Cl atoms. The crystals are…”
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Journal Article -
11
Bis(2-butyl-N,N'-diisopropyl-amidinato)dichlorohafnium(IV)
Published in Acta crystallographica. Section C, Crystal structure communications (01-07-2005)“…The title compound, [Hf(C11H23N2)2Cl(2)], is a monomeric hafnium(IV) complex containing two bidentate amidinate ligands and two cis Cl atoms. The crystals are…”
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Journal Article -
12
Dry Reforming and Reverse Water Gas Shift: Alternatives for Syngas Production?
Published in Chemie ingenieur technik (01-04-2015)“…Dry reforming and reverse water gas shift are often discussed as potential carbon dioxide sinks. They may in the near future act as enablers for improving…”
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13
Structure-Activity Relationships of Nickel-Hexaaluminates in Reforming Reactions Part II: Activity and Stability of Nanostructured Nickel-Hexaaluminate-Based Catalysts in the Dry Reforming of Methane
Published in ChemCatChem (01-05-2014)“…Ni–hexaaluminates exhibiting a high magnetoplumbite or β“‐alumina phase content (>80 wt %) and high specific surface areas (10–30 m2 g−1) were investigated…”
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Journal Article -
14
Structure-Activity Relationships of Nickel-Hexaaluminates in Reforming Reactions Part I: Controlling Nickel Nanoparticle Growth and Phase Formation
Published in ChemCatChem (01-05-2014)“…The controlled synthesis of hexaaluminates ANiyAl12−yO19−δ (A=Ba, La, Sr, and y=0.25, 0.5, 1) is reported by a freeze drying route. This route allows the use…”
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Journal Article -
15
Guanidinate-Stabilized Monomeric Hafnium Amide Complexes as Promising Precursors for MOCVD of HfO2
Published in Inorganic chemistry (25-12-2006)“…Novel guanidinato complexes of hafnium [Hf{η2-(iPrN)2CNR2}2(NR2)2] (R2 = Et2, 1; Et, Me, 2; Me2, 3), synthesized by insertion reactions of…”
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Journal Article -
16
Stability of Ni/SiO2-ZrO2 catalysts towards steaming and coking in the dry reforming of methane with carbon dioxide
Published in Frontiers of chemical science and engineering (01-06-2016)“…Ni/SiO 2 -ZrO 2 catalysts with Ni loadings of 1 to 13 wt-% were prepared, characterized by elemental analysis, X-ray diffraction, N 2 sorption, temperature…”
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Journal Article -
17
Stabilization of Amide-Based Complexes of Niobium and Tantalum Using Malonates as Chelating Ligands: Precursor Chemistry and Thin Film Deposition
Published in Chemistry of materials (11-12-2007)“…The stabilization of the reactive amide complexes of niobium and tantalum with malonates as chelating ligands leads to stable six-coordinated monomeric…”
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Journal Article -
18
Structure-Activity Relationships of Nickel-Hexaaluminates in Reforming Reactions PartII: Activity and Stability of Nanostructured Nickel-Hexaaluminate-Based Catalysts in the Dry Reforming of Methane
Published in ChemCatChem (01-05-2014)“…Ni-hexaaluminates exhibiting a high magnetoplumbite or [beta]"-alumina phase content (>80wt%) and high specific surface areas (10-30m2g-1) were investigated…”
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Journal Article -
19
Structure-Activity Relationships of Nickel-Hexaaluminates in Reforming Reactions PartI: Controlling Nickel Nanoparticle Growth and Phase Formation
Published in ChemCatChem (01-05-2014)“…The controlled synthesis of hexaaluminates ANiyAl12-yO19-[delta] (A=Ba, La, Sr, and y=0.25, 0.5, 1) is reported by a freeze drying route. This route allows the…”
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Journal Article -
20
Atomic Layer Deposition of Gd 2 O 3 and Dy 2 O 3 : A Study of the ALD Characteristics and Structural and Electrical Properties
Published in Chemistry of materials (28-02-2012)Get full text
Journal Article