Search Results - "Mienert, Bernd"
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An Octanuclear Metallosupramolecular Cage Designed To Exhibit Spin‐Crossover Behavior
Published in Angewandte Chemie International Edition (24-04-2017)“…By employing the subcomponent self‐assembly approach utilizing 5,10,15,20‐tetrakis(4‐aminophenyl)porphyrin or its zinc(II) complex, 1H‐4‐imidazolecarbaldehyde,…”
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Iron Metal-Organic Frameworks MIL-88B and NH2-MIL-88B for the Loading and Delivery of the Gasotransmitter Carbon Monoxide
Published in Chemistry : a European journal (17-05-2013)“…Crystals of MIL‐88B‐Fe and NH2‐MIL‐88B‐Fe were prepared by a new rapid microwave‐assisted solvothermal method. High‐purity, spindle‐shaped crystals of…”
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3
Octahedral Coordination Complex of Iron(VI)
Published in Science (American Association for the Advancement of Science) (30-06-2006)“…The hexavalent state, considered to be the highest oxidation level accessible for iron, has previously been found only in the tetrahedral ferrate dianion,…”
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4
Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)FeIII(N3)]+ and Ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in Water/Acetone Mixtures
Published in Inorganic chemistry (13-11-2000)“…Reaction of the monoanionic, pentacoordinate ligand lithium 1,4,8,11-tetraazacyclotetradecane-1-acetate, Li(cyclam-acetate), with FeCl3 yields, upon addition…”
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5
Characterization of a Genuine Iron(V)−Nitrido Species by Nuclear Resonant Vibrational Spectroscopy Coupled to Density Functional Calculations
Published in Journal of the American Chemical Society (12-09-2007)“…The characterization of high-valent iron species is of interest due to their relevance to biological reaction mechanisms. Recently, we have synthesized and…”
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6
A PAS domain with an oxygen labile [4Fe-4S](2+) cluster in the oxygen sensor kinase NreB of Staphylococcus carnosus
Published in Biochemistry (Easton) (30-12-2008)“…The cytoplasmic histidine sensor kinase NreB of Staphylococcus carnosus responds to O(2) and controls together with the response regulator NreC the expression…”
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7
Frontispiece: An Octanuclear Metallosupramolecular Cage Designed To Exhibit Spin‐Crossover Behavior
Published in Angewandte Chemie International Edition (24-04-2017)“…Metallosupramolecular ChemistryThe synthesis and properties of a supramolecular octanuclear cage exhibiting spin‐crossover behavior in solution are…”
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8
Mössbauer Studies of the Iron−Sulfur Cluster-Free Hydrogenase: The Electronic State of the Mononuclear Fe Active Site
Published in Journal of the American Chemical Society (27-07-2005)“…The iron−sulfur cluster-free hydrogenase (Hmd) from methanogenic archaea harbors an iron-containing, light-sensitive cofactor of still unknown structure as…”
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9
The Geometric and Electronic Structure of [(cyclam-acetato)Fe(N)]+: A Genuine Iron(V) Species with a Ground-State Spin S=1/2
Published in Angewandte Chemie International Edition (06-05-2005)“…Low‐spin, high‐valent iron centers: A high‐valent iron–nitrido species containing a FeV center is accessible by the photolysis of [(cyclam‐ac)FeIIIN3]+. The…”
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10
Photolysis of cis- and trans-[FeIII(cyclam)(N3)2]+ Complexes: Spectroscopic Characterization of a Nitridoiron(V) Species
Published in Journal of the American Chemical Society (26-05-1999)“…Reaction of cis-[FeIII(cyclam)Cl2]Cl in acidic H2O/CH3OH or CH3CN/H2O mixtures with NaN3 at 50 °C produced upon addition of NaClO4 or NaPF6 the complex…”
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11
Characterization of a Genuine Lron(V)-Nitrido Species By Nuclear Resonant Vibrational Spectroscopy Coupled to Density Functional Calculations
Published in Journal of the American Chemical Society (19-10-2007)“…The characterization of high-valent iron species is of interest due to their relevance to biological reaction mechanisms. Recently, we have synthesized and…”
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12
Iron Metal–Organic Frameworks MIL‐88B and NH 2 ‐MIL‐88B for the Loading and Delivery of the Gasotransmitter Carbon Monoxide
Published in Chemistry : a European journal (17-05-2013)“…Abstract Crystals of MIL‐88B‐Fe and NH 2 ‐MIL‐88B‐Fe were prepared by a new rapid microwave‐assisted solvothermal method. High‐purity, spindle‐shaped crystals…”
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13
Iron Metal-Organic Frameworks MIL-88B and NH sub(2)-MIL-88B for the Loading and Delivery of the Gasotransmitter Carbon Monoxide
Published in Chemistry : a European journal (01-05-2013)“…Crystals of MIL-88B-Fe and NH sub(2)-MIL-88B-Fe were prepared by a new rapid microwave-assisted solvothermal method. High-purity, spindle-shaped crystals of…”
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14
A PAS Domain with an Oxygen Labile [4Fe-4S]2+ Cluster in the Oxygen Sensor Kinase NreB of Staphylococcus carnosus
Published in Biochemistry (Easton) (30-12-2008)“…The cytoplasmic histidine sensor kinase NreB of Staphylococcus carnosus responds to O2 and controls together with the response regulator NreC the expression of…”
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15
Frontispiz: Ein achtkerniger metallosupramolekularer Würfel mit Spin‐Crossover‐Eigenschaften
Published in Angewandte Chemie (24-04-2017)“…Metallosupramolekulare ChemieA. Lützen und Mitarbeiter beschreiben in ihrer Zuschrift auf S. 5012 die Synthese und Eigenschaften eines achtkernigen…”
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16
Ein achtkerniger metallosupramolekularer Würfel mit Spin‐Crossover‐Eigenschaften
Published in Angewandte Chemie (24-04-2017)“…Nach dem Ansatz der Subkomponenten‐Selbstorganisation lassen sich aus 5,10,15,20‐Tetrakis(4‐aminophenyl)porphyrin oder dessen Zink(II)‐Komplex,…”
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17
Oxidation behavior of ferrous cations during ion exchange into zeolites under atmospheric conditions
Published in Microporous and mesoporous materials (15-09-2005)“…During ion exchange under atmospheric conditions, zeolites A, X, and Y facilitate the oxidation of Fe 2+ to Fe 3+ to very different extents, ranging from…”
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18
Frontispiz: Ein achtkerniger metallosupramolekularer Wurfel mit Spin-Crossover-Eigenschaften
Published in Angewandte Chemie (24-04-2017)“…Metallosupramolekulare ChemieA. Lutzen und Mitarbeiter beschreiben in ihrer Zuschrift auf S.5012 die Synthese und Eigenschaften eines achtkernigen…”
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Journal Article -
19
Ein achtkerniger metallosupramolekularer Wurfel mit Spin-Crossover-Eigenschaften
Published in Angewandte Chemie (24-04-2017)“…Nach dem Ansatz der Subkomponenten-Selbstorganisation lassen sich aus 5,10,15,20-Tetrakis(4-aminophenyl)porphyrin oder dessen Zink(II)-Komplex,…”
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20
The Geometric and Electronic Structure of [(cyclam-acetato)Fe(N)]+: A Genuine Iron(V) Species with a Ground-State Spin S=1/2
Published in Angewandte Chemie (06-05-2005)“…Hochvalente Low‐Spin‐Eisenzentren: Eine hochvalente Eisen‐Nitrido‐Spezies mit einem FeV‐Zentrum entsteht bei der Photolyse von [(cyclam‐ac)FeIIIN3]+. Anhand…”
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