Search Results - "Miedziak, Peter J"
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Selective Oxidation of Glycerol by Highly Active Bimetallic Catalysts at Ambient Temperature under Base-Free Conditions
Published in Angewandte Chemie International Edition (17-10-2011)“…Au–Pt alloy nanoparticles deposited on Mg(OH)2 (see STEM‐HAADF image) show high activity in the selective oxidation of polyols using molecular oxygen as…”
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The Effects of Dopants on the Cu–ZrO2 Catalyzed Hydrogenation of Levulinic Acid
Published in Journal of physical chemistry. C (04-04-2019)“…Catalytic hydrogenation of levulinic acid to form γ-valerolactone was studied over Cu–ZrO2 catalysts doped with metal oxides from the first-row transition…”
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3
Base-Free Oxidation of Glycerol Using Titania-Supported Trimetallic Au-Pd-Pt Nanoparticles
Published in ChemSusChem (01-05-2014)“…Base‐free selective oxidation of glycerol has been investigated using trimetallic Au–Pd–Pt nanoparticles supported on titania and their corresponding…”
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Solvent Effect and Reactivity Trend in the Aerobic Oxidation of 1,3-Propanediols over Gold Supported on Titania: NMR Diffusion and Relaxation Studies
Published in Chemistry : a European journal (26-08-2013)“…In recent work, it was reported that changes in solvent composition, precisely the addition of water, significantly inhibits the catalytic activity of Au/TiO2…”
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Oxidation of benzyl alcohol using supported gold–palladium nanoparticles
Published in Catalysis today (01-01-2011)“…A key discovery in the last two decades has been the realisation that gold, when prepared as supported nanoparticles, is exceptionally effective as an…”
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The selective oxidation of 1,2-propanediol to lactic acid using mild conditions and gold-based nanoparticulate catalysts
Published in Catalysis today (30-03-2013)“…[Display omitted] ► 1,2-Propanediol was oxidised to lactic acid with enhanced selectivity. ► AuPt/C catalysts are active at mild conditions. ► Amount of base…”
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Journal Article Conference Proceeding -
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Selective Oxidation of n-Butanol Using Gold-Palladium Supported Nanoparticles Under Base-Free Conditions
Published in ChemSusChem (01-02-2015)“…The base‐free selective catalytic oxidation of n‐butanol by O2 in an aqueous phase has been studied using Au‐Pd bimetallic nanoparticles supported on titania…”
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Au–Pd separation enhances bimetallic catalysis of alcohol oxidation
Published in Nature (London) (10-03-2022)“…In oxidation reactions catalysed by supported metal nanoparticles with oxygen as the terminal oxidant, the rate of the oxygen reduction can be a limiting…”
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Gold-Palladium Core-Shell Nanocrystals with Size and Shape Control Optimized for Catalytic Performance
Published in Angewandte Chemie International Edition (28-01-2013)“…Right to the core: The design of nanocatalysts with maximized catalytic performance relies on control of the size, shape, and composition. The shell thickness…”
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The Role of Mg(OH)2 in the So‐Called “Base‐Free” Oxidation of Glycerol with AuPd Catalysts
Published in Chemistry : a European journal (16-02-2018)“…Mg(OH)2‐ and Mg(OH)2‐containing materials can provide excellent performance as supports for AuPd nanoparticles for the oxidation of glycerol in the absence of…”
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Transfer hydrogenation of methyl levulinate with methanol to gamma valerolactone over Cu-ZrO2: A sustainable approach to liquid fuels
Published in Catalysis communications (01-04-2022)“…Cu-ZrO2 is demonstrated to be a highly effective catalyst for the transfer hydrogenation of methyl levulinate to γ-valerolactone, using methanol as the…”
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Solvent-free aerobic epoxidation of 1-decene using supported cobalt catalysts
Published in Catalysis today (01-08-2019)“…[Display omitted] •Supported cobalt catalysts for the aerobic epoxidation of 1-decene are reported.•Leaching could be minimised by change of the support…”
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Surface functionalized TiO2 supported Pd catalysts for solvent-free selective oxidation of benzyl alcohol
Published in Catalysis today (15-07-2015)“…•APTES-grafted TiO2 was used as Pd catalyst support in benzyl alcohol oxidation.•Monolayer attachment promoted small and uniform Pd nanoclusters.•Excess…”
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The Over-Riding Role of Autocatalysis in Allylic Oxidation
Published in Catalysis letters (01-04-2022)“…In this paper we aim to highlight the need to consider the possible role of autocatalysis in oxidation reactions when using molecular oxygen as the terminal…”
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Selective Hydrogenation of Levulinic Acid Using Ru/C Catalysts Prepared by Sol-Immobilisation
Published in Topics in catalysis (01-06-2018)“…A 1% Ru/C catalyst prepared by the sol immobilization method showed a high yield of γ-valerolactone from levulinic acid. We performed an optimization of the…”
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Cinnamyl Alcohol Oxidation Using Supported Bimetallic Au–Pd Nanoparticles: An Optimization of Metal Ratio and Investigation of the Deactivation Mechanism Under Autoxidation Conditions
Published in Topics in catalysis (01-03-2020)“…The aerobic oxidation of cinnamyl alcohol in toluene under autoxidation conditions has been studied using a range of 1 wt% Au–Pd/TiO 2 catalysts. The catalysts…”
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Three step synthesis of benzylacetone and 4-(4-methoxyphenyl)butan-2-one in flow using micropacked bed reactors
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-12-2019)“…[Display omitted] •Three catalytic reactors and a separator were combined in a telescoped flow system.•Telescoped flow synthesis allowed different operating…”
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Understanding the Solvent Effect on the Catalytic Oxidation of 1,4-Butanediol in Methanol over Au/TiO2 Catalyst: NMR Diffusion and Relaxation Studies
Published in Chemistry : a European journal (05-11-2012)“…The effect of water on the catalytic oxidation of 1,4‐butanediol in methanol over Au/TiO2 has been investigated by catalytic reaction studies and NMR diffusion…”
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Deactivation Behavior of Supported Gold Palladium Nanoalloy Catalysts during the Selective Oxidation of Benzyl Alcohol in a Micropacked Bed Reactor
Published in Industrial & engineering chemistry research (15-11-2017)“…Highly active, supported Au–Pd catalysts have been tested for catalyzing benzyl alcohol oxidation in a silicon-glass micropacked bed reactor. The effects of…”
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A micropacked-bed multi-reactor system with in situ raman analysis for catalyst evaluation
Published in Catalysis today (01-04-2017)“…[Display omitted] •Portable Raman spectrometer was utilised for evaluation of catalyst activity.•A single chip with four parallel micropacked-bed reactors was…”
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