Search Results - "Michalis A. Vasiliades"
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The Effect of CeO2 Preparation Method on the Carbon Pathways in the Dry Reforming of Methane on Ni/CeO2 Studied by Transient Techniques
Published in Catalysts (01-07-2019)“…The present work discusses the effect of CeO2 synthesis method (thermal decomposition (TD), precipitation (PT), hydrothermal (HT), and sol-gel (SG)) on the…”
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2
Remarkable N2-selectivity enhancement of practical NH3-SCR over Co0.5Mn1Fe0.25Al0.75Ox-LDO: The role of Co investigated by transient kinetic and DFT mechanistic studies
Published in Applied catalysis. B, Environmental (15-11-2020)“…[Display omitted] •Co0.5Mn1Fe0.25Al0.75Ox-LDO showed remarkable N2-selectivity enhancement.•Use of Co reduced significantly NH3 oxidation to N2O.•Electron…”
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3
Promotional effect of Ce doping in Cu4Al1Ox – LDO catalyst for low-T practical NH3-SCR: Steady-state and transient kinetics studies
Published in Applied catalysis. B, Environmental (15-10-2019)“…[Display omitted] •A novel NH3-SCR catalyst Ce2/Cu4Al1Ox was synthesized from Ce2/Cu4Al1-CO3 LDH precursors.•Ce2/Cu4Al1Ox shows significantly higher activity…”
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4
Unravelling the Mechanism of Intermediate‐Temperature CO2 Interaction with Molten‐NaNO3‐Salt‐Promoted MgO
Published in Advanced materials (Weinheim) (01-01-2022)“…The optimization of MgO‐based adsorbents as advanced CO2‐capture materials is predominantly focused on their molten‐salt modification, for which theoretical…”
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5
Design Aspects of Doped CeO2 for Low-Temperature Catalytic CO Oxidation: Transient Kinetics and DFT Approach
Published in ACS applied materials & interfaces (19-05-2021)“…CO elimination through oxidation over highly active and cost-effective catalysts is a way forward for many processes of industrial and environmental…”
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6
Molten Salt-Promoted MgO Adsorbents for CO2 Capture: Transient Kinetic Studies
Published in Environmental science & technology (20-04-2021)“…Optimization of MgO adsorbents is predominantly focused on the regulation of appropriate adsorption sites for CO2 associated with Mg2+-O2– sites of low…”
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7
The steam reforming of acetol on Ni/La2O3-Al2O3 studied by transient and isotopic methods
Published in Catalysis communications (01-06-2023)“…Operando-SSITKA (Mass spectrometry-DRIFTS) and other isotopic experiments were employed to investigate the steam reforming of acetol on 10-wt% Ni/La2O3-Al2O3…”
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8
Decoupling the Chemical and Mechanical Strain Effect on Steering the CO2 Activation over CeO2‑Based Oxides: An Experimental and DFT Approach
Published in ACS applied materials & interfaces (27-07-2022)“…Doped ceria-based metal oxides are widely used as supports and stand-alone catalysts in reactions where CO2 is involved. Thus, it is important to understand…”
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9
Valorization of agricultural wastes could improve soil fertility and mitigate soil direct N2O emissions
Published in Journal of environmental management (15-11-2019)“…The emerging need for sustainable management of the increasing quantities of urban and industrial organic wastes creates opportunities for the development of…”
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10
Evolution of Oxygen Vacancy Sites in Ceria-Based High-Entropy Oxides and Their Role in N2 Activation
Published in ACS applied materials & interfaces (29-04-2024)“…In this work, a relatively new class of materials, rare earth (RE) based high entropy oxides (HEO) are discussed in terms of the evolution of the oxygen vacant…”
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11
Evolution of Oxygen Vacancy Sites in Ceria-Based High-Entropy Oxides and Their Role in N 2 Activation
Published in ACS applied materials & interfaces (29-04-2024)“…In this work, a relatively new class of materials, rare earth (RE) based high entropy oxides (HEO) are discussed in terms of the evolution of the oxygen vacant…”
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12
Unravelling the Mechanism of Intermediate-Temperature CO 2 Interaction with Molten-NaNO 3 -Salt-Promoted MgO
Published in Advanced materials (Weinheim) (01-01-2022)“…The optimization of MgO-based adsorbents as advanced CO -capture materials is predominantly focused on their molten-salt modification, for which theoretical…”
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13
Carbon dioxide storage in olivine basalts: Effect of ball milling process
Published in Powder technology (01-03-2015)“…The goal of this study is to propose a cost-effective method for the optimization of the ex situ carbonation of basaltic rocks. The ball milling process was…”
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14
Molten Salt-Promoted MgO Adsorbents for CO 2 Capture: Transient Kinetic Studies
Published in Environmental science & technology (20-04-2021)“…Optimization of MgO adsorbents is predominantly focused on the regulation of appropriate adsorption sites for CO associated with Mg -O sites of low…”
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15
Elucidating the role of La3+/Sm3+ in the carbon paths of dry reforming of methane over Ni/Ce-La(Sm)-Cu-O using transient kinetics and isotopic techniques
Published in Applied catalysis. B, Environmental (01-05-2022)“…The different effects of the presence of La3+ and Sm3+ heteroatoms in the 5 wt% Ni/45Ce-45(Sm or La)-10Cu-O catalytic system on the carbon deposition and…”
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16
Decoupling the Chemical and Mechanical Strain Effect on Steering the CO 2 Activation over CeO 2 -Based Oxides: An Experimental and DFT Approach
Published in ACS applied materials & interfaces (27-07-2022)“…Doped ceria-based metal oxides are widely used as supports and stand-alone catalysts in reactions where CO is involved. Thus, it is important to understand how…”
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17
A Novel Analysis of Transient Isothermal 18O Isotopic Exchange on Commercial CexZr1−xO2-Based OSC Materials
Published in Topics in catalysis (01-01-2019)“…A novel methodology for the analysis of 18 O 2 -transient isothermal isotopic exchange (TIIE) response curves obtained over commercial mixed metal oxides upon…”
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18
Enhancing the rate of ex situ mineral carbonation in dunites via ball milling
Published in Advanced powder technology : the international journal of the Society of Powder Technology, Japan (01-03-2016)“…[Display omitted] •Dunitic materials with enhanced CO2 uptake were created via ball milling (BM).•The optimum conditions are 12h of BM with 50wt% ethanol as…”
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19
Design Aspects of Doped CeO 2 for Low-Temperature Catalytic CO Oxidation: Transient Kinetics and DFT Approach
Published in ACS applied materials & interfaces (19-05-2021)“…CO elimination through oxidation over highly active and cost-effective catalysts is a way forward for many processes of industrial and environmental…”
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Journal Article -
20
The Effect of CO Partial Pressure on Important Kinetic Parameters of Methanation Reaction on Co-Based FTS Catalyst Studied by SSITKA-MS and Operando DRIFTS-MS Techniques
Published in Catalysts (01-05-2020)“…A 20 wt% Co-0.05 wt% Pt/γ-Al2O3 catalyst was investigated to obtain a fundamental understanding of the effect of CO partial pressure (constant H2 partial…”
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