Search Results - "Miaskiewicz, Solène"
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1
Potassium Carbonate to Unlock a GaCl3‑Catalyzed C–H Propargylation of Arenes
Published in ACS catalysis (07-01-2022)“…A gallium-catalyzed C–H propargylation of electron-rich arenes using bromoallenes is described. The development of this reaction was first hampered by a side…”
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2
Gold(I)-Catalyzed Cyclization/Nucleophilic Substitution of 1‑(N‑Sulfonylazetidin-2-yl) Ynones into N‑Sulfonylpyrrolin-4-ones
Published in Organic letters (19-02-2016)“…Polysubstituted pyrrolin-4-ones have been efficiently synthesized from readily available 1-(N-sulfonylazetidin-2-yl) ynones via gold(I)-catalyzed…”
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3
Gold(I)-Catalyzed N-Desulfonylative Amination versus N-to-O 1,5-Sulfonyl Migration: A Versatile Approach to 1-Azabicycloalkanes
Published in Angewandte Chemie International Edition (25-07-2016)“…Valuable 1‐azabicycloalkane derivatives have been synthesized through a novel gold(I)‐catalyzed desulfonylative cyclization strategy. An ammoniumation reaction…”
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4
Coinage Metals-Catalyzed Cascade Reactions of Aryl Alkynylaziridines: Silver(I)-Single vs Gold(I)-Double Cyclizations
Published in Journal of organic chemistry (04-05-2012)“…Alkynylaziridines carrying an aryl group could be efficiently converted into aminoallenylidene isochromans, isoquinolines, or tetrahydronaphtalenes with…”
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5
Gold(I)-catalyzed formation of furans from γ-acyloxyalkynyl ketones
Published in Beilstein journal of organic chemistry (30-08-2013)“…Various γ-acyloxyalkynyl ketones were efficiently converted into highly substituted furans with 2.5 mol % of triflimide (triphenylphosphine)gold(I) as a…”
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6
Gold(I)-Catalyzed N-Desulfonylative Amination versus N-to-O 1,5-Sulfonyl Migration: A Versatile Approach to 1-Azabicycloalkanes
Published in Angewandte Chemie (25-07-2016)“…Valuable 1‐azabicycloalkane derivatives have been synthesized through a novel gold(I)‐catalyzed desulfonylative cyclization strategy. An ammoniumation reaction…”
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Journal Article -
7
Transition structures for the oxy-ene reaction
Published in Chemical communications (Cambridge, England) (12-04-2022)“…An overlooked pericyclic reaction between allyl alcohols and alkenes to form carbonyl compounds is analyzed. It combines the characteristic features of the…”
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8
A 1,3,2‐Diazaphospholene‐Catalyzed Reductive Claisen Rearrangement
Published in Angewandte Chemie International Edition (24-06-2019)“…1,3,2‐Diazaphospholenes (DAPs) are an emerging class of organic hydrides. In this work, we exploited them as efficient catalysts for very mild reductive…”
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9
Chiral 1,3,2‐Diazaphospholenes as Catalytic Molecular Hydrides for Enantioselective Conjugate Reductions
Published in Angewandte Chemie International Edition (03-04-2018)“…Secondary 1,3,2‐diazaphospholenes have a polarized P−H bond and are emerging as molecular hydrides. Herein, a class of chiral, conformationally restricted…”
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10
A gold(i)-catalysed approach towards harmalidine an elusive alkaloid from Peganum harmala
Published in RSC advances (16-09-2022)“…Upon gold catalysis, the 2,3-dihydropyrrolo[1,2- ]indole motif, encountered in few but interesting bioactive natural products, was efficiently obtained from…”
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11
Synthesis of 2-carboxylated aza-ring derivatives through α-monohalogenation/ring-contraction of N-sulfonyl lactams
Published in Tetrahedron (24-08-2017)“…2-Carboxylated aza-rings have been synthesized in two steps through a highly selective monohalogenation of N-sulfonylated lactams of various ring sizes (from…”
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12
Potassium Carbonate to Unlock a GaCl 3 -Catalyzed C–H Propargylation of Arenes
Published in ACS catalysis (07-01-2022)“…A gallium-catalyzed C-H propargylation of arenes using bromoallenes is described. The development of this new reaction was first hampered by a side…”
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Journal Article -
13
A gold()-catalysed approach towards harmalidine an elusive alkaloid from
Published in RSC advances (21-09-2022)“…Upon gold catalysis, the 2,3-dihydropyrrolo[1,2- a ]indole motif, encountered in few but interesting bioactive natural products, was efficiently obtained from…”
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Journal Article -
14
A 1,3,2‐Diazaphospholene‐Catalyzed Reductive Claisen Rearrangement
Published in Angewandte Chemie (24-06-2019)“…1,3,2‐Diazaphospholenes (DAPs) are an emerging class of organic hydrides. In this work, we exploited them as efficient catalysts for very mild reductive…”
Get full text
Journal Article -
15
Chiral 1,3,2‐Diazaphospholenes as Catalytic Molecular Hydrides for Enantioselective Conjugate Reductions
Published in Angewandte Chemie (03-04-2018)“…Secondary 1,3,2‐diazaphospholenes have a polarized P−H bond and are emerging as molecular hydrides. Herein, a class of chiral, conformationally restricted…”
Get full text
Journal Article