Search Results - "Meyer‐Klaucke, Wolfram"
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Catching an Entatic State-A Pair of Copper Complexes
Published in Angewandte Chemie International Edition (03-01-2014)“…The structures of two types of guanidine–quinoline copper complexes have been investigated by single‐crystal X‐ray crystallography, K‐edge X‐ray absorption…”
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Architecture of a protein central to iron homeostasis: crystal structure and spectroscopic analysis of the ferric uptake regulator
Published in Molecular microbiology (01-02-2003)“…Summary Iron is an essential element for almost all organisms, although an overload of this element results in toxicity because of the formation of hydroxyl…”
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Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site
Published in Science (American Association for the Advancement of Science) (25-07-2008)“…Biological formation and consumption of molecular hydrogen (H₂) are catalyzed by hydrogenases, of which three phylogenetically unrelated types are known:…”
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X-ray absorption spectroscopic studies on model compounds for biological iodine and bromine
Published in Journal of synchrotron radiation (01-01-2005)“…X-ray absorption spectra of a number of organic iodine and bromine compounds of biological relevance, as well as of a series of iodine compounds with different…”
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A Halide-Induced Copper(I) Disulfide/Copper(II) Thiolate Interconversion
Published in Angewandte Chemie International Edition (13-02-2012)“…One to two and back again: A disulfide–thiolate interconversion process in a dinuclear copper complex is induced by chloride ions (see scheme). Within this…”
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Implications of Guanidine Substitution on Copper Complexes as Entatic-State Models
Published in European journal of inorganic chemistry (01-10-2016)“…The guanidine–quinoline ligand dimethylethyleneguanidinoquinoline (DMEGqu) is able to stabilise bis(chelate) copper complexes in an intermediate geometry…”
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Crystal Structures of [Fe]-Hydrogenase in Complex with Inhibitory Isocyanides: Implications for the H2-Activation Site
Published in Angewandte Chemie International Edition (09-09-2013)“…Inhibition mechanism: Isocyanides strongly inhibit [Fe]‐hydrogenase. X‐ray crystallography and X‐ray absorption spectroscopy revealed that the isocyanide binds…”
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8
HDAC6-p97/VCP controlled polyubiquitin chain turnover
Published in The EMBO journal (26-07-2006)“…HDAC6 is a unique cytoplasmic deacetylase capable of interacting with ubiquitin. Using a combination of biophysical, biochemical and biological approaches, we…”
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The crystal structure of C176A mutated [Fe]-hydrogenase suggests an acyl-iron ligation in the active site iron complex
Published in FEBS letters (04-02-2009)“…[Fe]-hydrogenase is one of three types of enzymes known to activate H 2. Crystal structure analysis recently revealed that its active site iron is ligated…”
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Iodide accumulation provides kelp with an inorganic antioxidant impacting atmospheric chemistry
Published in Proceedings of the National Academy of Sciences - PNAS (13-05-2008)“…Brown algae of the Laminariales (kelps) are the strongest accumulators of iodine among living organisms. They represent a major pump in the global…”
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Crystal Structure and Function of the Zinc Uptake Regulator FurB from Mycobacterium tuberculosis
Published in The Journal of biological chemistry (30-03-2007)“…Members of the ferric/zinc uptake regulator (Fur/Zur) family are the central metal-dependent regulator proteins in many Gram-negative and -positive bacteria…”
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The Iron-Sulfur Cluster-free Hydrogenase (Hmd) Is a Metalloenzyme with a Novel Iron Binding Motif
Published in The Journal of biological chemistry (13-10-2006)“…The iron-sulfur cluster-free hydrogenase (Hmd) from methanogenic archaea harbors an iron-containing cofactor of yet unknown structure. X-ray absorption…”
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Complexation and Toxicity of Copper in Higher Plants. II. Different Mechanisms for Copper versus Cadmium Detoxification in the Copper-Sensitive Cadmium/Zinc Hyperaccumulator Thlaspi Caerulescens (Ganges Ecotype)
Published in Plant physiology (Bethesda) (01-10-2009)“…The cadmium/zinc hyperaccumulator Thlaspi caerulescens is sensitive toward copper (Cu) toxicity, which is a problem for phytoremediation of soils with mixed…”
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Tissue- and Age-Dependent Differences in the Complexation of Cadmium and Zinc in the Cadmium/Zinc Hyperaccumulator Thlaspi caerulescens (Ganges Ecotype) Revealed by X-Ray Absorption Spectroscopy
Published in Plant physiology (Bethesda) (01-02-2004)“…Extended x-ray absorption fine structure measurements were performed on frozen hydrated samples of the cadmium (Cd)/zinc (Zn) hyperaccumulator Thlaspi…”
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A Functional Ni-Ni-[4Fe-4S] Cluster in the Monomeric Acetyl-CoA Synthase from Carboxydothermus hydrogenoformans
Published in Proceedings of the National Academy of Sciences - PNAS (13-01-2004)“…In anaerobic microorganisms employing the acetyl-CoA pathway, acetyl-CoA synthase (ACS) and CO dehydrogenase (CODH) form a complex (ACS/CODH) that catalyzes…”
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In vivo speciation studies and antioxidant properties of bromine in Laminaria digitata reinforce the significance of iodine accumulation for kelps
Published in Journal of experimental botany (01-07-2013)“…The metabolism of bromine in marine brown algae remains poorly understood. This contrasts with the recent finding that the accumulation of iodide in the brown…”
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Stabilisation of a Highly Reactive Bis(μ‐oxo)dicopper(III) Species at Room Temperature by Electronic and Steric Constraint of an Unconventional Nitrogen Donor Ligand
Published in Chemistry : a European journal (07-09-2009)“…Amazingly stable: The bis(guanidine) ligand N1,N3‐bis[bis(2,2,6,6‐tetramethylpiperidin‐1‐yl)methylen]propan‐1,3‐diamine stabilizes the first…”
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Different speciation for bromine in brown and red algae, revealed by in vivo X‐ray absorption spectroscopic studies
Published in Journal of phycology (01-08-2014)“…Members of various algal lineages are known to be strong producers of atmospherically relevant halogen emissions, that is a consequence of their capability to…”
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Implications of Guanidine Substitution on Copper Complexes as Entatic-State Models
Published in European journal of inorganic chemistry (01-10-2016)“…Invited for the cover of this issue is the group of Sonja Herres‐Pawlis from RWTH Aachen University, Germany. The cover image shows our entatic‐state model…”
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Front Cover: Implications of Guanidine Substitution on Copper Complexes as Entatic-State Models (Eur. J. Inorg. Chem. 29/2016)
Published in European journal of inorganic chemistry (01-10-2016)“…The cover picture shows a guanidine–quinoline–copper complex as a new entatic‐state model. Small changes in the ligand strongly affect the molecular structure,…”
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