Search Results - "Mews, Rüdiger"
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CH3N=SF2=NCH3: Structural, Conformational, and Configurational Properties in the Gaseous and in the Condensed Phases
Published in European journal of inorganic chemistry (01-10-2014)“…CH3–N=SF2=N–CH3 (1) was obtained in 88 % yield from the reaction of a bis(silylated) amine RN(Si–Me3)2 with a sulfur tetrafluoride imide R′N=SF4 (R = R′ =…”
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Interaction of 1,2,5-Chalcogenadiazole Derivatives with Thiophenolate: Hypercoordination with Formation of Interchalcogen Bond versus Reduction to Radical Anion
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-05-2011)“…According to the DFT calculations, [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazole (4), [1,2,5]selenadiazolo[3,4-c][1,2,5]thiadiazole (5),…”
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Trithiatetrazocine Cations, [RCN4S3]+; Planar Sulfur−Nitrogen 10π Aromatics
Published in Inorganic chemistry (17-11-2008)“…The reaction of bicyclic sulfur−nitrogen heterocyles RCN5S3 (R = F3C, Ph, Me2N, 2-FC6H4, 2,6-F2C6H3) with [Hg(SO2)2][AsF6]2 in liquid SO2 yielded the…”
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Tris(dimethylamino)oxosulfonium Difluorotrimethylsilicate, (Me2N)3SO+Me3SiF2 - (TAOS Fluoride)
Published in Inorganic chemistry (09-09-2002)“…In the OSF4/Me2NSiMe3 system besides the long known Me2NS(O)F3 only the trisubstituted derivative is isolated as (Me2N)3SO+Me3SiF2 - (3). Similar to…”
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Fluorothiazynes, 50 years old and still exciting: electrophilic attack at the thiazyl nitrogen of NSF2NS(O)F2
Published in Journal of fluorine chemistry (01-11-2004)Get full text
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CH 3 N=SF 2 =NCH 3 : Structural, Conformational, and Configurational Properties in the Gaseous and in the Condensed Phases
Published in European journal of inorganic chemistry (01-10-2014)“…CH 3 –N=SF 2 =N–CH 3 ( 1 ) was obtained in 88 % yield from the reaction of a bis(silylated) amine RN(Si–Me 3 ) 2 with a sulfur tetrafluoride imide R′N=SF 4 (R…”
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CF3CF2NS(F)CF3: Vibrational spectra and conformational properties
Published in Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (05-05-2014)“…•CF3CF2NS(F)CF3 exists in the gas phase as a mixture of anticlinal and syn forms.•Theoretical calculations predict the anticlinal form as the global…”
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Structure of the SO2F- Anion, a Problem Case1
Published in Inorganic chemistry (12-03-2001)“…Recently, room-temperature crystal structures of SO2F- in its K+ and Rb+ salts were published in Z. Anorg. Allg. Chem. 1999, 625, 385 and claimed to represent…”
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Tellurium-Nitrogen π-Heterocyclic Chemistry - Synthesis, Structure, and Reactivity Toward Halides and Pyridine of 3,4-Dicyano-1,2,5-telluradiazole
Published in European journal of inorganic chemistry (01-08-2012)“…The reaction of 2,3‐diaminomaleonitrile with TeX4 (X = Cl, Br) in the presence of pyridine (Py) and/or triethylamine (Et3N) provided…”
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CF₃CF₂N=S(F)CF₃: vibrational spectra and conformational properties
Published in Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (05-05-2014)“…The structural, conformational, and configurational properties of 1,1,1-trifluoro-N-(1,1,2,2,2-pentafluoroethyl) methanesulfinimidoyl fluoride, CF3CF2N=S(F)CF3…”
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Lithium Fluoroarylamidinates: Syntheses, Structures, and Reactions
Published in Inorganic chemistry (22-04-2002)“…Lithium fluoroarylamidinates [(ArFC(NSiMe3)2Li) n ·xD] (ArF = 4-CF3C6H4, n = 2, D = OEt2, x = 1 (2a); n = 1, D = TMEDA, x = 1 (4a); ArF = 2-FC6H4, n = 2, D =…”
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Complexes of the Bicyclic Multifunctional Sulfur‐Nitrogen Ligand F 3 CCN 5 S 3 with Co 2+ , Zn 2+ , Cu 2+ , and Cd
Published in European journal of inorganic chemistry (01-09-2005)“…The ability of the sulfur‐nitrogen‐carbon bicycle F 3 CCN 5 S 3 to act as a donor towards transition metal cations has been investigated. F 3 CCN 5 S 3 forms…”
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Di- and Trifluorobenzenes in Reactions with Me2EM (E = P, N; M = SiMe3, SnMe3, Li) Reagents: Evidence for a Concerted Mechanism of Aromatic Nucleophilic Substitution
Published in European Journal of Organic Chemistry (01-02-2010)“…Dimethyl(trimethylsilyl)phosphane (Me3SiPMe2) has been successfully used for the substitution of fluorine variously in 1,3‐ (1) or 1,2‐difluorobenzene (2) or…”
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Book Review Journal Article -
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Some chemistry of tris(pyrazolyl)methylthiolate derivatives
Published in Acta chimica Slovenica (2013)“…An efficient synthetic method for the preparation of TAS tris(pyrazolyl)methylthiolate (3) is reported. Nucleophilic exchange reactions with 3 gave…”
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Pentafluoroethyliminosulfur difluoride, CF3CF2NSF2: Vibrational spectra and quantum chemical calculations
Published in Journal of molecular structure (01-08-2010)Get full text
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Coordination chemistry in and of sulfur dioxide
Published in Coordination chemistry reviews (01-02-2000)“…The review describes the syntheses of metal salts with weakly interacting anions (AlCl 4 −, AsF 6 −, SbF 6 −) in the poorly coordinating solvent SO 2. The…”
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Di‐ and Trifluorobenzenes in Reactions with Me 2 EM (E = P, N; M = SiMe 3 , SnMe 3 , Li) Reagents: Evidence for a Concerted Mechanism of Aromatic Nucleophilic Substitution
Published in European journal of organic chemistry (01-02-2010)“…Dimethyl(trimethylsilyl)phosphane (Me 3 SiPMe 2 ) has been successfully used for the substitution of fluorine variously in 1,3‐ ( 1 ) or 1,2‐difluorobenzene (…”
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Pentafluoroethyliminosulfur difluoride, CF 3CF 2N SF 2: Vibrational spectra and quantum chemical calculations
Published in Journal of molecular structure (2010)“…The vibrational spectra of pentafluoroethyliminosulfur difluoride, CF 3CF 2N SF 2, were recorded in the gas phase with IR spectroscopy and in the liquid state…”
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