Search Results - "Mertens, Florian O.R.L."

Investigation of n-alkane adsorption on HKUST-1 and determination of intrinsic interfacial energy contributions by Münch, Alexander S., Mertens, Florian O.R.L.

“…The performance of metal-organic frameworks in gas chromatographic separation investigations has been widely study in recent years. However, to use…”
Get full text

High-Separation Performance of Chromatographic Capillaries Coated with MOF-5 by the Controlled SBU Approach by Münch, Alexander S., Seidel, Jürgen, Obst, Anja, Weber, Edwin, Mertens, Florian O. R. L.

“…Recently developed MOF surface‐coating techniques, the controlled SBU approach (CSA) for the generation of MOF‐5, and the use of self‐assembled monolayers have…”
Get full text

Formate Ester Is Not a Decisive Intermediate in the Low-Temperature Synthesis of Methanol from Carbon Dioxide Dissolved in Diethylaminoethanol by Hemmann, Felix, Frölich, Stefan, Lißner, Andreas, Mertens, Florian O. R. L

“…Alcohols are often discussed as suitable solvents for the low-temperature methanol synthesis. In particular, 2-(diethylamino)­ethanol is seen as a promising…”
Get full text

Room temperature preparation method for thin MOF-5 films on metal and fused silica surfaces using the controlled SBU approach by Münch, Alexander S., Lohse, Maria S., Hausdorf, Steffen, Schreiber, Gerhard, Zacher, Denise, Fischer, Roland A., Mertens, Florian O.R.L.

“…Recently developed procedures for the coating of surfaces with metal-organic frameworks using cyclic preparation schemes in which different reactants are…”
Get full text

A Self-Contained Regeneration Scheme for Spent Ammonia Borane Based on the Catalytic Hydrodechlorination of BCl3 by Reller, Christian, Mertens, Florian O. R. L.

“…Recycling: A self‐contained procedure for the recycling of BNH‐waste, based on the three major steps: polymer break‐up, amine supported catalytic…”
Get full text

Methanol from CO2 by Organo-Cocatalysis: CO2 Capture and Hydrogenation in One Process Step by Reller, Christian, Pöge, Matthias, Lißner, Andreas, Mertens, Florian O. R. L

“…Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The…”
Get full text

A procedure for the regeneration of ammonia borane from BNH-waste products by Hausdorf, Steffen, Baitalow, Felix, Wolf, Gert, Mertens, Florian O.R.L.

“…Ammonia borane BH 3 NH 3 has attracted considerable interest in the last years as a hydrogen source material due to its high hydrogen content of 19.6 wt%. The…”
Get full text

Main-Group and Transition-Element IRMOF Homologues by Hausdorf, Steffen, Baitalow, Felix, Böhle, Tony, Rafaja, David, Mertens, Florian O. R. L

“…A simple two-component procedure was developed to synthesize not only classical zinc-based IRMOFs represented by MOF-5 but also the cobalt and beryllium…”
Get full text

Proton and Water Activity-Controlled Structure Formation in Zinc Carboxylate-Based Metal Organic Frameworks by Hausdorf, Steffen, Wagler, Jörg, Moβig, Regina, Mertens, Florian O. R. L

“…The contributions of terephthalic acid and Zn2+-coordinated water in N,N-diethylformamide (DEF) to the overall proton activity in the synthesis of MOF-5…”
Get full text

Hydrodechlorination of Et3NBCl3 Catalyzed by Amorphous Nickel Boride - A Mechanistic Approach by Reller, Christian, Mertens, Florian O. R. L.

“…The catalytic hydrodechlorination of BCl3 with molecular hydrogen in the presence of tertiary amines is a viable strategy for the energy‐efficient generation…”
Get full text

Synthesis, spectroscopic characterization and structural investigation of a new symmetrically trisubstituted benzene derivative: 3,3′,3′′-(Benzene-1,3,5-triyl)tripropiolic acid by Münch, Alexander S., Katzsch, Felix, Weber, Edwin, Mertens, Florian O.R.L.

“…[Display omitted] •A new extended analogue of trimesic acid has been prepared.•The structure of the compound is determined by single crystal X-ray…”
Get full text

Copper(II) benzoate dimers coordinated by different linear alcohols – A systematic study of crystal structures by Katzsch, Felix, Münch, Alexander S., Mertens, Florian O.R.L., Weber, Edwin

“…[Display omitted] •Three new alcohol coordinated copper(II) benzoate paddle wheels have been prepared.•The structures of the compounds are determined by single…”
Get full text

Gaseous Species as Reaction Tracers in the Solvothermal Synthesis of the Zinc Oxide Terephthalate MOF-5 by Hausdorf, Steffen, Baitalow, Felix, Seidel, Jürgen, Mertens, Florian O. R. L

“…Gaseous species emitted during the zinc oxide/zinc hydroxide 1,4-benzenedicarboxylate metal organic framework synthesis (MOF-5, MOF-69c) have been used to…”
Get full text

Spectroscopic, thermal and single crystal structure investigations of 2-bromotrimesic acid and its trimethyl ester analogue by Münch, Alexander S., Katzsch, Felix, Gruber, Tobias, Mertens, Florian O.R.L.

“…[Display omitted] •Bromotrimesic acid (1) and bromotrimesic trimethyl ester (2) were synthesised.•Single crystal structures were determined to study…”
Get full text

Synthesis of the Bifunctional Ligand N,Nʹ-[1,4- Phenylenebis(iminocarbonyl)]di(L-phenylalanine) and Crystal Structure of Its Supramolecular Coordination Polymer with Lead(II) by Stapf, Manuel, Böhle, Tony, Seichter, Wilhelm, Mertens, Florian O. R. L., Weber, Edwin

“…The new linker-type ligand 1, featuring two L-phenylalanine-terminated urea moieties attached to the para positions of a central phenylene unit has been…”
Get full text

5,5′-(Ethyne-1,2-diyl)diisophthalic acid dimethyl sulfoxide tetrasolvate by Münch, Alexander S., Katzsch, Felix, Weber, Edwin, Mertens, Florian O. R. L.

“…In the title compound, C18H10O8·4C2H6OS, the mid-point of the triple bond of the main molecule is located on a special position, i.e. about an inversion…”
Get full text

Poly[(μ4-2,5-dimethoxybenzene-1,4-dicarboxylato)manganese(II)] and its zinc(II) analogue: three-dimensional coordination polymers containing unusually coordinated metal centres by Böhle, Tony, Eissmann, Frank, Weber, Edwin, Mertens, Florian O. R. L.

“…The title compounds, [Mn(C10H8O6)]n and [Zn(C10H8O6)]n, are isomorphous coordination polymers prepared from 2,5‐dimethoxyterephthalic acid (H2dmt) and the…”
Get full text

Hexakis(N,N-dimethyl-formamide-κO)cobalt(II) bis-(perchlorate) by Eissmann, Frank, Böhle, Tony, Mertens, Florian O R L, Weber, Edwin

“…The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the…”
Get full text