Search Results - "Merino, Estíbaliz"
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Visible Light Mediated, Redox Neutral Remote 1,6-Difunctionalizations of Alkenes
Published in ACS catalysis (06-07-2018)“…A photoinduced cascade strategy is presented here for the remote functionalization of alkenes under redox neutral conditions. A broad portfolio of alkyl groups…”
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2
Asymmetric, visible light-mediated radical sulfinyl-Smiles rearrangement to access all-carbon quaternary stereocentres
Published in Nature chemistry (01-04-2021)“…The asymmetric construction of all-carbon quaternary centres within acyclic settings represents a long-standing challenge for synthetic chemists. Alongside…”
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3
Asymmetric Ni-Catalyzed Radical Relayed Reductive Coupling
Published in Journal of the American Chemical Society (05-08-2020)“…Alkene dicarbofunctionalizations enable the streamlined construction of aliphatic structures and have thus been the subject of intense research efforts…”
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4
Cyclization Cascades via N‑Amidyl Radicals toward Highly Functionalized Heterocyclic Scaffolds
Published in Journal of the American Chemical Society (21-01-2015)“…The addition of a variety of radicals to the double bond of N-(arylsulfonyl)acrylamides can trigger cyclization/aryl migration/desulfonylation cascades via…”
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5
Copper-Catalyzed Hydroamination of 2‑Alkynylazobenzenes: Synthesis of 3‑Alkenyl‑2H‑Indazoles
Published in Journal of organic chemistry (15-11-2024)“…A copper-catalyzed intramolecular synthesis of 3-alkenyl-2H-indazoles from 2-alkynylazobenzenes is described. The reaction proceeds in a single step via C–N…”
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6
Visible Light-Mediated Heterodifunctionalization of Alkynylazobenzenes for 2H‑Indazole Synthesis
Published in Organic letters (08-03-2024)“…We disclose the heterodifunctionalization of alkynylazobenzenes promoted exclusively by visible light in the absence of any transition metal and/or…”
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7
Synthesis of Structured Porous Polymers with Acid and Basic Sites and Their Catalytic Application in Cascade-Type Reactions
Published in Chemistry of materials (26-03-2013)“…We described the use of one porous polymeric aromatic framework (PPAF) with a 9,9′-spiro-bisfluorene unit as a support in heterogeneous catalysis. The material…”
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8
One-Pot (3 + 2) Cycloaddition–Isomerization–Oxidation of 2,2,2-Trifluorodiazoethane and Styryl Derivatives
Published in Journal of organic chemistry (04-08-2023)“…A facile access to 5-aryl-3-trifluoromethylpyrazoles has been developed by a one-pot (3 + 2) cycloaddition–isomerization–oxidation sequence employing…”
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9
Catalytic Asymmetric Domino Michael Addition−Alkylation Reaction: Enantioselective Synthesis of Dihydrofurans
Published in Organic letters (17-12-2010)“…A catalytic enantioselective synthesis of dihydrofurans has been developed. 1,3-Dicarbonyl derivatives react with (E)-β,β-bromonitrostyrenes in the presence of…”
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10
1,2,3-Benzotriazine Synthesis by Heterocyclization of p‑Tosylmethyl Isocyanide Derivatives
Published in Journal of organic chemistry (06-10-2023)“…An efficient methodology to form 4-alkoxy- and 4-aryloxybenzo[d][1,2,3]triazines via an intramolecular heterocyclization of…”
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11
Highly Efficient Green Solution Processable Organic Light-Emitting Diodes Based on a Phosphorescent κ3‑(N^C^C)Gold(III)-Alkynyl Complex
Published in Chemistry of materials (25-02-2020)“…Gold(III) complexes are emerging as promising phosphorescent emitters for high-efficiency organic light-emitting diodes (OLEDs). However, despite recent…”
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12
Mono-functionalization of porous aromatic frameworks to use as compatible heterogeneous catalysts in one-pot cascade reactions
Published in Applied catalysis. A, General (01-01-2014)“…Porous aromatic frameworks (PPAFs) prepared by microwave assisted synthesis can be easily functionalized to obtain solid acid (sulfonic acid) and base (primary…”
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13
Synthesis of azobenzenes: the coloured pieces of molecular materials
Published in Chemical Society reviews (01-01-2011)“…Azobenzenes are ubiquitous motifs very important in many areas of science. Azo compounds display crucial properties for important applications, mainly for the…”
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14
Hyper-Cross-Linked Porous Polymer Featuring B–N Covalent Bonds (HCP-BNs): A Stable and Efficient Metal-Free Heterogeneous Photocatalyst
Published in ACS macro letters (18-07-2023)“…The first example of a porous polymer containing B–N covalent bonds, prepared from a tetraphene B–N monomer and biphenyl as a comonomer, is reported. It was…”
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Postfunctionalized Porous Polymeric Aromatic Frameworks with an Organocatalyst and a Transition Metal Catalyst for Tandem Condensation–Hydrogenation Reactions
Published in ACS sustainable chemistry & engineering (07-03-2016)“…Novel heterogenized bifunctional catalysts were prepared combining a rhodium complex with a pyrrolidine on porous polymeric aromatic frameworks (PAFs) based on…”
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16
Addition of CF3 across unsaturated moieties: a powerful functionalization tool
Published in Chemical Society reviews (21-09-2014)“…In the last few years, the efficient introduction of trifluoromethyl groups in organic molecules has become a major research focus. This review highlights the…”
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Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/Desulfonylation and C(sp2)–N Bond Formation of Conjugated Tosyl Amides
Published in Journal of the American Chemical Society (02-10-2013)“…A novel copper-catalyzed one-pot trifluoromethylation/aryl migration/desulfonylation and C(sp2)–N bond formation with conjugated tosyl amides as starting…”
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Correction to “Cyclization Cascades via N‑Amidyl Radicals toward Highly Functionalized Heterocyclic Scaffolds”
Published in Journal of the American Chemical Society (06-05-2015)Get full text
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19
Arylphosphonylation and Arylazidation of Activated Alkenes
Published in Angewandte Chemie International Edition (12-05-2014)“…Two radical‐mediated processes of activated alkenes, namely arylphosphonylation and arylazidation, are described. The difunctionalization of alkenes by a…”
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20
Synergistic role for CO
Published in Nature catalysis (23-10-2024)“…Typically, active acyl intermediates are quenched with nucleophiles to complete carbonylation. Now, a visible-light-induced radical relay enables CO insertion…”
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