Modeling Solvent Effects on Asphaltene Dimers

Modeling Solvent Effects on Asphaltene Dimers

Asphaltene deposition is a well-known problem in the petroleum industry. Nevertheless, there seems to be a lack of information on the processes involved in asphaltene association and its relationship to asphaltene solubility under certain conditions. Molecular mechanics and molecular dynamics have h...

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Bibliographic Details
Published in:Energy & fuels Vol. 19; no. 4; pp. 1245 - 1251
Main Authors: Carauta, Alexandre N. M, Seidl, Peter R, Chrisman, Erika C. A. N, Correia, Júlio C. G, Menechini, Príscila de O, Silva, Daniel M, Leal, Katia Z, de Menezes, Sonia M. C, de Souza, Wladimir F, Teixeira, Marco A. G
Format: Journal Article Conference Proceeding
Language:English
Published: Washington, DC American Chemical Society 01-07-2005
Subjects:
Applied sciences
Constitution and properties of crude oils, shale oils, natural gas and bitumens. Analysis and characteristics
Crude oil, natural gas and petroleum products
Energy
Exact sciences and technology
Fuels
Asphaltene
Solvent effect
Butane
Simulation
Toluene
Solubility
Molecular dynamics
Isobutane
Heptane
Modeling
Petroleum
Vacuum residue
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Summary:Asphaltene deposition is a well-known problem in the petroleum industry. Nevertheless, there seems to be a lack of information on the processes involved in asphaltene association and its relationship to asphaltene solubility under certain conditions. Molecular mechanics and molecular dynamics have had an important role in the investigation of these phenomena. To better understand the role of solvents in fractionating asphaltenes extracted from vacuum residues and evaluate their tendency to dissociate under different conditions, we modeled the effect of toluene, n-butane, isobutane, and n-heptane on an aggregate formed by two asphaltene molecules that would have a tendency to associate (not average structures commonly used in similar studies). Molecular dynamics simulations were performed on an asphaltene dimer after minimizing the conformation of each molecule and verifying the most stable position for docking. They reveal the extent to which these solvents are able to separate the aggregate at different temperatures after a given period of time. As expected, toluene is the most effective and n-heptane affects the aggregate the least, with n-butane and isobutane falling between these two bounds.
Bibliography:Presented at the 5th International Conference on Petroleum Phase Behavior and Fouling.
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istex:4729B3BBF4437FD06CCE1E2F070BB17131E3FD7F
ISSN:0887-0624
1520-5029
DOI:10.1021/ef049809d