Search Results - "Melcher, Michaela"
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Iridium Catalyzed Carbocyclizations: Efficient (5+2) Cycloadditions of Vinylcyclopropanes and Alkynes
Published in Chemistry : a European journal (07-01-2015)“…Third‐row transition metal catalysts remain a largely untapped resource in cycloaddition reactions for the formation of medium‐sized rings. Herein, we report…”
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Control of Enantioselectivity in Rhodium(I) Catalysis by Planar Chiral Dibenzo[a,e]cyclooctatetraenes
Published in Chemistry : a European journal (16-02-2018)“…Planar chiral 5,11‐disubstiuted dibenzo[a,e]cyclo‐octatetraenes (dbCOTs) have been developed as the first useful chiral homologs to dbCOT‐ligands for…”
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Electro-mechanically switchable hydrocarbons based on [8]annulenes
Published in Nature communications (14-02-2022)“…Pure hydrocarbons with shape and conjugation properties that can be switched by external stimuli is an intriguing prospect in the design of new responsive…”
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Structure-activity relationship studies for the development of inhibitors of murine adipose triglyceride lipase (ATGL)
Published in Bioorganic & medicinal chemistry (15-08-2020)“…[Display omitted] High serum fatty acid (FA) levels are causally linked to the development of insulin resistance, which eventually progresses to type 2…”
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Cover Feature: Control of Enantioselectivity in Rhodium(I) Catalysis by Planar Chiral Dibenzo[a,e]cyclooctatetraenes (Chem. Eur. J. 10/2018)
Published in Chemistry : a European journal (16-02-2018)“…The chirality of 5,11‐disubstituted dibenzo[a,e]cyclooctatetraene ligands is represented by a two‐fold axis of symmetry in molecular monarch‐butterflies…”
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Structure–activity studies in the development of a hydrazone based inhibitor of adipose-triglyceride lipase (ATGL)
Published in Bioorganic & medicinal chemistry (15-06-2015)“…[Display omitted] Adipose triglyceride lipase (ATGL) catalyzes the degradation of cellular triacylglycerol stores and strongly determines the concentration of…”
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Chiral Discrimination in Rhodium(I) Catalysis by 2,5-Disubstituted 1,3 a ,4,6 a -Tetrahydropenatalene Ligands-More Than Just a Twist of the Olefins?
Published in ACS omega (31-03-2018)“…Chiral dienes are useful ligands in a number of asymmetric transition-metal-catalyzed reactions. Here, we evaluate the efficiency of 2,5-disubstituted 1,3 ,4,6…”
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Chiral Discrimination in Rhodium(I) Catalysis by 2,5-Disubstituted 1,3a,4,6a‑Tetrahydropenatalene LigandsMore Than Just a Twist of the Olefins?
Published in ACS omega (31-03-2018)“…Chiral dienes are useful ligands in a number of asymmetric transition-metal-catalyzed reactions. Here, we evaluate the efficiency of 2,5-disubstituted…”
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Dioxomolybdenum(VI) Complexes with Pyrazole Based Aryloxide Ligands: Synthesis, Characterization and Application in Epoxidation of Olefins
Published in Inorganic chemistry (16-07-2012)“…Synthesis, characterization, and epoxidation chemistry of four new dioxomolybdenum(VI) complexes [MoO2(L)2] (1–4) with aryloxide-pyrazole ligands L = L1–L4 is…”
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