Search Results - "Meddour, Abdelkrim"
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Enantioselective Intramolecular Hydroamination Catalyzed by Lanthanide Ate Complexes Coordinated by N-Substituted (R)-1,1‘-Binaphthyl-2,2‘-diamido Ligands
Published in Journal of organic chemistry (17-03-2006)“…Ytterbium and lutetium ionic complexes derived from enantiopure substituted (R)-binaphthylamine ligands, of the general formula [Li(THF) n…”
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2H and 13C NMR‐Based Enantiodetection Using Polyacetylene versus Polypeptide Aligning Media: Versatile and Complementary Tools for Chemists
Published in ChemPlusChem (Weinheim, Germany) (01-02-2019)“…In this work, the practical/analytical potential of an L‐valine‐derived polyacetylene (PLA) lyotropic liquid crystal (LLC) is examined to spectrally…”
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Samarium Iodobinaphtholate: An Efficient Catalyst for Enantioselective Aza-Michael Additions of O-Benzylhydroxylamine to N-Alkenoyloxazolidinones
Published in European Journal of Organic Chemistry (01-05-2011)“…Samarium diiodide is an efficient catalyst for the aza‐Michael addition of O‐benzylhydroxylamine to α,β‐unsaturated N‐acyloxazolidinones leading to mixtures of…”
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Book Review Journal Article -
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Enantiodivergence in alkylation of 1-(6-methoxynaphth-2-yl)ethyl acetate by potassium dimethyl malonate catalyzed by chiral palladium-DUPHOS complex
Published in Tetrahedron: asymmetry (01-07-2010)“…Alkylation of racemic 1-(6-methoxynaphth-2-yl)ethyl acetate by potassium dimethyl malonate catalyzed by a chiral palladium-DUPHOS complex afforded the…”
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Enantioselective Intramolecular Hydroamination of Secondary Amines Catalyzed by Easily Accessible Ate and Neutral Rare-Earth Complexes
Published in ChemCatChem (10-01-2011)“…The magnificent neutral: Secondary amines are cyclized into the corresponding scalemic pyrrolidines and piperidines with in situ‐prepared chiral alkylamido ate…”
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On the Elucidation of the Mechanism of Vinca Alkaloid Fluorination in Superacidic Medium
Published in Organic letters (05-08-2011)“…Detailed investigations on one of the key steps of the superacidic fluorination of Vinca alkaloids that is the origin of C20′ activation are reported. While…”
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2H QUOSY 2D‐NMR Experiments in Weakly Aligning Systems: From the Conventional to the Ultrafast Approach
Published in Chemphyschem (17-07-2020)“…We describe three anisotropic ultrafast (UF) QUadrupolar Ordered SpectroscopY (QUOSY) 2D‐NMR experiments (referred to as ADUF 2D NMR spectroscopy) designed for…”
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2 H QUOSY 2D‐NMR Experiments in Weakly Aligning Systems: From the Conventional to the Ultrafast Approach
Published in Chemphyschem (17-07-2020)“…Abstract We describe three anisotropic ultrafast (UF) QUadrupolar Ordered SpectroscopY (QUOSY) 2D‐NMR experiments (referred to as ADUF 2D NMR spectroscopy)…”
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2H QUOSY 2D-NMR Experiments in Weakly Aligning Systems: From the Conventional to the UF Approach
Published in Chemphyschem (01-07-2020)“…We describe three anisotropic ultrafast (UF) QUOSY 2D-NMR experiments (referred to as ADUF 2D NMR spectroscopy) designed for recording the 2H homonuclear 2D…”
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Multinuclear NMR in polypeptide liquid crystals: Three fertile decades of methodological developments and analytical challenges
Published in Progress in nuclear magnetic resonance spectroscopy (01-02-2020)“…[Display omitted] •Progress of NMR in polypeptide-based media during three decades is reviewed.•Anisotropic NMR interactions (RCSA, RDC, RQC) depend on…”
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Crystal Structures of μ2-Fluoro- and μ2-Salicylaldoximato-Bridged μ3-Oxo-tris(dimethyltin(IV)) Bis(salicylaldoximate)
Published in Organometallics (21-12-1998)“…Crystallographic data for [(Me2Sn)2(Me2SnO)(Nu)(HONZO)(ONZO)] where HONZOH is ortho-HONCH−C6H4−OH, salicylaldoxime, have been obtained for Nu = ONZOH (2) and…”
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Synthesis and Solution State Characterization by Gradient-Enhanced 2D Multinuclear NMR Spectroscopy of a Fluorine-Bridged Dimethyltin(IV) Salicylaldoximate Derivative
Published in Inorganic chemistry (03-12-1997)“…The reaction of [(Me2Sn)2(Me2SnO)(ONZOH)(HONZO)(ONZO)] (HONZOH = o-HONCHC6H4OH, salicylaldoxime) with ammonium fluoride yields a fluorotris(dimethyltin)…”
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Front Cover: 2H and 13C NMR‐Based Enantiodetection Using Polyacetylene versus Polypeptide Aligning Media: Versatile and Complementary Tools for Chemists (ChemPlusChem 2/2019)
Published in ChemPlusChem (Weinheim, Germany) (01-02-2019)“…The front cover shows the L‐valine‐derived polyacetylene (PLA) lyotropic liquid crystal (LLC) can be used in 2H and 13C NMR experiments to discriminate…”
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2H and 13C NMR‐Based Enantiodetection Using Polyacetylene versus Polypeptide Aligning Media: Versatile and Complementary Tools for Chemists
Published in ChemPlusChem (Weinheim, Germany) (01-02-2019)“…Invited for this month's cover are the collaborating groups of Dr. Philippe Lesot (DR CNRS) at Université Paris‐Sud/Université Paris‐Saclay, France, and…”
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2 H and 13 C NMR-Based Enantiodetection Using Polyacetylene versus Polypeptide Aligning Media: Versatile and Complementary Tools for Chemists
Published in ChemPlusChem (Weinheim, Germany) (01-02-2019)“…Invited for this month's cover are the collaborating groups of Dr. Philippe Lesot (DR CNRS) at Université Paris-Sud/Université Paris-Saclay, France, and…”
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Journal Article -
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2 H and 13 C NMR-Based Enantiodetection Using Polyacetylene versus Polypeptide Aligning Media: Versatile and Complementary Tools for Chemists
Published in ChemPlusChem (Weinheim, Germany) (01-02-2019)“…In this work, the practical/analytical potential of an L-valine-derived polyacetylene (PLA) lyotropic liquid crystal (LLC) is examined to spectrally…”
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The use of exchangeable nuclei to observe enantiomers through deuterium NMR in chiral liquid crystalline solvents
Published in Magnetic resonance in chemistry (01-12-2012)“…It is demonstrated that 2H NMR in chiral liquid crystalline solvents can be used to measure enantiomeric excesses using exchangeable deuterons in alcohols…”
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X-ray Diffraction and 2D Gradient-Assisted 1H−119Sn HMQC NMR Studies of Structures Obtained from Nucleophilic Substitutions on Dimethyltin(IV) Salicylaldoximates
Published in Organometallics (30-09-1997)“…The reactivity of the trinuclear tin cluster [(Me2Sn)2(Me2SnO)(OCH3)(HONZO)(ONZO)] (3a; HONZOH = o-HONCH-C6H4-OH, salicylaldoxime) toward proton-donating…”
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Enzymatic Fluorination in Streptomyces cattleya Takes Place with an Inversion of Configuration Consistent with an SN2 Reaction Mechanism
Published in Chembiochem : a European journal of chemical biology (03-05-2004)“…The stereochemical course of the recently isolated fluorination enzyme from Streptomyces cattleya has been evaluated. The enzyme mediates a reaction between…”
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