Search Results - "Mézailles, N"

Metal-Dependent Interplay between Crystallization and Phosphorus Diffusion during the Synthesis of Metal Phosphide Nanoparticles by Carenco, S, Hu, Y, Florea, I, Ersen, O, Boissière, C, Mézailles, N, Sanchez, C

“…The interplay between crystallization and phosphorus diffusion in the versatile synthesis of metal phosphide nanoparticles from well-defined metal…”
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Improving the Li-Electrochemical Properties of Monodisperse Ni2P Nanoparticles by Self-Generated Carbon Coating by Carenco, S, Surcin, C, Morcrette, M, Larcher, D, Mézailles, N, Boissière, C, Sanchez, C

“…Carbon coating of electrode materials is nowadays a major tool to improve the electronic percolation of the electrode. In this study, a self-generated carbon…”
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Formation of a Phosphorus−Phosphorus Bond by Successive One-Electron Reductions of a Two-Phosphinines-Containing Macrocycle:  Crystal Structures, EPR, and DFT Investigations by Cataldo, Laurent, Choua, Sylvie, Berclaz, Théo, Geoffroy, Michel, Mézailles, Nicolas, Ricard, Louis, Mathey, François, Floch, Pascal Le

“…Chemical and electrochemical reductions of the macrocycle 1 lead to the formation of a radical monoanion anion [1]•- whose structure has been studied by EPR in…”
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One-Electron Reduction Product of a Biphosphinine Derivative and of Its Ni(0) Complex:  Crystal Structure, EPR/ENDOR, and DFT Investigations on (tmbp)•- and [Ni(tmbp)2] by Choua, Sylvie, Sidorenkova, Helena, Berclaz, Théo, Geoffroy, Michel, Rosa, Patrick, Mézailles, Nicolas, Ricard, Louis, Mathey, François, Le Floch, Pascal

“…The radical anion (tmbp) • -, where tmbp = 4,4‘,5,5‘-tetramethyl-2,2‘-biphosphinine, was generated by reduction of tmbp on a potassium mirror. EPR/ENDOR…”
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Gold(I) and Gold(0) Complexes of Phosphinine-Based Macrocycles by Mézailles, Nicolas, Avarvari, Narcis, Maigrot, Nicole, Ricard, Louis, Mathey, François, Le Floch, Pascal, Cataldo, Laurent, Berclaz, Théo, Geoffroy, Michel

“…A “CO‐like matrix”, showing coordination analogous to that of carbonyl groups, is provided by silacalix[4]phosphinine macrocycles. Reaction with AuI leads to…”
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The tmbp Dianion in the Contact Ion Pair [(tmbp)Na2(dme)1.5]n and in the Solvent-Separated Ion Pair [tmbp][(2.2.1)Li]2 by Rosa, Patrick, Mézailles, Nicolas, Ricard, Louis, Mathey, François, Le Floch, Pascal

“…A surprising polymeric structure (see picture) results from the two‐electron reduction of a 2,2′‐biphosphinine with sodium/naphthalene in dimethoxyethane. When…”
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Improving the Li-Electrochemical Properties of Monodisperse Ni 2 P Nanoparticles by Self-Generated Carbon Coating by Carenco, S., Surcin, C., Morcrette, M., Larcher, D., Mézailles, N., Boissière, C., Sanchez, C.

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Mixed Phosphinine-Ether Macrocycles by Mézailles, Nicolas, Maigrot, Nicole, Hamon, Sylvain, Ricard, Louis, Mathey, François, Le Floch

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Phosphine Gold(I) Bis-(trifluoromethanesulfonyl)imidate Complexes as New Highly Efficient and Air-Stable Catalysts for the Cycloisomerization of Enynes by Mézailles, Nicolas, Ricard, Louis, Gagosz, Fabien

“…A study concerning the synthesis of new phosphine gold(I) complexes using the bis(trifluoromethanesulfonyl)imidate moiety as a weakly coordinating counteranion…”
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First X-ray Crystal Study and DFT Calculations of Anionic λ4-Phosphinines by Moores, Audrey, Ricard, Louis, Le Floch, Pascal, Mézailles, Nicolas

“…Anionic λ4-phosphinines 3 and 4 were synthesized via the reaction of the corresponding λ3-phosphinines 1 and 2 with MeLi. The X-ray structure of [3][Li(thf)2]…”
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Controlled Design of Size-Tunable Monodisperse Nickel Nanoparticles by Carenco, Sophie, Boissière, Cédric, Nicole, Lionel, Sanchez, Clément, Le Floch, Pascal, Mézailles, Nicolas

“…We present here a complete study on a synthesis of nickel nanoparticles involving the reaction of [Ni(acac)2] with oleylamine (OA) and trioctylphosphine (TOP)…”
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The Effect of a Fourth Binding Site on the Stabilization of Cationic SPS Pincer Palladium Complexes: Experimental, DFT, and Mass Spectrometric Studies by Blug, Matthias, Doux, Marjolaine, Le Goff, Xavier, Maître, Philippe, Ribot, François, Le Floch, Pascal, Mézailles, Nicolas

“…A potentially tetradentate ligand was synthesized by the addition of α-Li-picoline to the 2,6-bis(diphenylphosphine sulfide)-3,5-diphenylphosphinine (SPS)…”
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Synthesis and Molecular Structure of a Palladium Complex Containing a λ5-Phosphinine-Based SPS Pincer Ligand by Doux, Marjolaine, Bouet, Claire, Mézailles, Nicolas, Ricard, Louis, Le Floch, Pascal

“…2,6-Bis(diphenylphosphino)-3,5-diphenylphosphinine (1) reacts with elemental sulfur to yield the corresponding 2,6-bis(diphenylphosphine…”
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Synthesis and Reactivity of the First η6-Rhodium(I) and η6-Iridium(I) Complexes of 2,6-Bis(trimethylsilyl)phosphinines by Doux, Marjolaine, Ricard, Louis, Mathey, François, Floch, Pascal Le, Mézailles, Nicolas

“…It has been shown that 2 equiv. of 2,3,5,6‐tetraphenylphosphinine (2) react with [Rh(COD)2][BF4] to yield the bis(η1‐phosphinine)RhI complex 6, whose X‐ray…”
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η2-Palladium and Platinum(II) Complexes of a λ4-Phosphinine Anion:  Syntheses, X-ray Crystal Structures, and DFT Calculations by Moores, Audrey, Mézailles, Nicolas, Ricard, Louis, Jean, Yves, le Floch, Pascal

“…A 1-methyl-2,6-bis(trimethylsilyl)-3,5-diphenylphosphinine anion (2) reacts with [MCl2(PPh3)2] (M = Pd, Pt) to afford the corresponding η2-palladium (3) and…”
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A Bis(thiophosphinoyl)methanediide Palladium Complex: Coordinated Dianion or Nucleophilic Carbene Complex? by Cantat, Thibault, Mézailles, Nicolas, Ricard, Louis, Jean, Yves, Le Floch, Pascal

“…A question of identity: A palladium complex featuring a carbenic S,C,S‐based pincer ligand is reported (see scheme). DFT calculations show that, unlike…”
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New mono- and bis-carbene samarium complexes: synthesis, X-ray crystal structures and reactivity by Cantat, Thibault, Jaroschik, Florian, Nief, François, Ricard, Louis, Mézailles, Nicolas, Le Floch, Pascal

“…New samarium carbene complexes have been synthesized and characterized by X-ray diffraction analysis; the carbenic nature was assessed by reactivity studies…”
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Thulium Alkylidene Complexes:  Synthesis, X-ray Structures, and Reactivity by Cantat, Thibault, Jaroschik, Florian, Ricard, Louis, Le Floch, Pascal, Nief, François, Mézailles, Nicolas

“…The first thulium alkylidene complexes (2 and 5) were synthesized using a stable dianionic ligand as carbene precursor and were characterized by X-ray…”
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Synthesis and Reactivity Towards Cationic Group 11 Metal Centers of an Extended Silacalix-[3]-phosphinine Macrocycle by Moores, Audrey, Mézailles, Nicolas, Maigrot, Nicole, Ricard, Louis, Mathey, François, Floch, Pascal le

“…A synthetic route to a new type of phosphinine‐based macrocycle has been developed. This approach involves the reaction of a phosphinine bearing two pendant…”
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Electron Transfer between Two Silyl-Substituted Phenylene Rings:  EPR/ENDOR Spectra, DFT Calculations, and Crystal Structure of the One-Electron Reduction Compound of a Di(m-silylphenylenedisiloxane) by Dutan, Cosmina, Choua, Sylvie, Berclaz, Théo, Geoffroy, Michel, Mézailles, Nicolas, Moores, Audrey, Ricard, Louis, Le Floch, Pascal

“…Reduction of a solution of octamethylcyclo-di(m-silylphenylenedisiloxane) 4 in THF on a potassium mirror leads to EPR/ENDOR spectra characterized by a large…”
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