Search Results - "McKenna, Gregory B."
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50th Anniversary Perspective: Challenges in the Dynamics and Kinetics of Glass-Forming Polymers
Published in Macromolecules (12-09-2017)“…The phenomenology of the glass transition and the associated behavior in the near liquid and glassy states are detailed, including the cooling rate dependence…”
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Nanoconfinement Effects on the Glass Transition and Crystallization Behaviors of Nifedipine
Published in Molecular pharmaceutics (04-02-2019)“…The impact of nanoconfinement on the crystallization and glass transition behaviors of nifedipine (NIF) has been investigated using differential scanning…”
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Isothermal Crystallization and Time–Temperature Transformation of Amorphous Nifedipine: A Case of Polymorphism Formation and Conversion
Published in Molecular pharmaceutics (05-07-2021)“…Crystallization of active pharmaceutical ingredients (APIs) from the supercooled liquid state is an important issue in determining the stability of amorphous…”
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Correlation between dynamic fragility and glass transition temperature for different classes of glass forming liquids
Published in Journal of non-crystalline solids (15-08-2006)“…Here we compile literature data for dynamic fragility m for six types of glass forming liquids: polymers, small molecule organics, hydrogen bonding organics,…”
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Viscoelastic and Glass Transition Properties of Ultrathin Polystyrene Films by Dewetting from Liquid Glycerol
Published in Macromolecules (26-03-2013)“…We have used the liquid dewetting method originally proposed by Bodiguel and Fretigny (Eur. Phys. J. E: Soft Matter Biol. Phys. 2006, 19(2), 185–193) to study…”
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Linear Rheological Response of a Series of Densely Branched Brush Polymers
Published in Macromolecules (13-09-2011)“…We have examined the linear rheological responses of a series of well-defined, dense, regularly branched brush polymers. These narrow molecular weight…”
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Substrate Effects on Glass Transition and Free Surface Viscoelasticity of Ultrathin Polystyrene Films
Published in Macromolecules (23-12-2014)“…We describe results from experiments in which spontaneous embedment of 20 nm silica particles was used to probe under-layer effects on the free surface…”
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Challenging the Kauzmann paradox using an ultra-stable perfluoropolymer glass with a fictive temperature below the dynamic VFT temperature
Published in Scientific reports (14-03-2023)“…Ultra-stable fluoropolymer glasses were created using vacuum pyrolysis deposition that show large fictive temperature T f reductions relative to the glass…”
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Effect of molecular architecture on ring polymer dynamics in semidilute linear polymer solutions
Published in Nature communications (15-04-2019)“…Understanding the dynamics of ring polymers is a particularly challenging yet interesting problem in soft materials. Despite recent progress, a complete…”
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Correlation between Molecular Mobility and Physical Stability in Pharmaceutical Glasses
Published in Molecular pharmaceutics (04-04-2016)“…We investigated a possible correlation between molecular mobility and physical stability in glassy celecoxib and indomethacin and identified the specific…”
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Re-visiting the “consequences of grafting density on the linear viscoelastic behavior of graft polymers”
Published in Polymer (Guilford) (09-01-2020)“…In a recent work published by Haugan et al. (ACS Macro Lett., 2018, 7, 525–530.), the linear viscoelastic behaviors of a series of random graft polymers as a…”
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Rheology of Entangled Solutions of Ring–Linear DNA Blends
Published in Macromolecules (22-02-2022)“…Bulk rheology measurements on concentrated monodisperse ring–linear DNA mixtures are reported for the first time. The entanglement behavior of the ring–linear…”
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High strain rate mechanical properties of a cross-linked epoxy across the glass transition
Published in Polymer (Guilford) (13-12-2013)“…Molecular dynamics simulations were used to study the high strain rate mechanical properties of a cross-linked epoxy system comprised of diglycidyl ether of…”
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Forced assembly by multilayer coextrusion to create oriented graphene reinforced polymer nanocomposites
Published in Polymer (Guilford) (14-01-2014)“…A potential advantage of platelet-like nanofillers as nanocomposite reinforcements is the possibility of achieving two-dimensional stiffening through planar…”
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Glass transition temperature of thin polycarbonate films measured by flash differential scanning calorimetry
Published in Journal of polymer science. Part B, Polymer physics (15-11-2014)“…ABSTRACT Flash differential scanning calorimetry was used to study the glass transition temperature Tg of polycarbonate ultrathin films. The investigation was…”
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When Ends Meet: Circular DNA Stretches Differently in Elongational Flows
Published in Macromolecules (25-08-2015)“…Chain topology has a profound impact on the flow behavior of single macromolecules. For circular polymers, the absence of free ends results in a unique chain…”
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Linear Rheology of a Series of Second-Generation Dendronized Wedge Polymers
Published in Macromolecules (12-03-2019)“…A series of second-generation dendronized wedge polymers were synthesized by ring-opening metathesis polymerization, and the linear viscoelastic response over…”
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Viscoelastic modeling of nanoindentation experiments: A multicurve method
Published in Journal of polymer science. Part B, Polymer physics (01-05-2014)“…ABSTRACT Nanoindentation is an increasingly used method of extracting surface mechanical properties of viscoelastic materials, especially polymers. Recently,…”
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Exceptional Property Changes in Ultrathin Films of Polycarbonate: Glass Temperature, Rubbery Stiffening, and Flow
Published in Macromolecules (13-03-2012)“…The TTU nanobubble inflation method has been used to determine the creep compliance of ultrathin films of polycarbonate over a thickness range of 3–22 nm and a…”
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Comparison of surface mechanical properties among linear and star polystyrenes: Surface softening and stiffening at different temperatures
Published in Polymer (Guilford) (04-10-2013)“…In a previous study, we reported both surface softening and stiffening for poly(α-methylstyrene) (PαMS) over a temperature range from room temperature to 21 °C…”
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