Search Results - "McDaniel, Max P."
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Alternative View of Long Chain Branch Formation by Metallocene Catalysts
Published in Macromolecules (09-11-2010)“…The widely accepted mechanism of long chain branch (LCB) formation, i.e. random macromer incorporation, conflicts with many of the experimental trends observed…”
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A Review of the Phillips Supported Chromium Catalyst and Its Commercial Use for Ethylene Polymerization
Published in Advances in Catalysis (2010)“…The Phillips supported chromium catalyst is used to produce some 40–50% of the world's high-density polyethylene. The chemistry of this important catalyst is…”
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Book Chapter -
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Kinetics of Long-Chain Branch Formation in Polyethylene
Published in ACS catalysis (05-01-2018)“…Long-chain branch (LCB) formation was measured in polyethylene homopolymers and 1-hexene–ethylene copolymers made using a variety of metallocene and chromium…”
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4
Reinforcement of Cr/silica catalysts by secondary deposition of silicate oligomers
Published in Applied catalysis. A, General (25-03-2018)“…[Display omitted] •A new method of reinforcing the silica matrix of Cr/silica polymerization catalysts is introduced, and the effect on catalyst activity and…”
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Journal Article -
5
Products of the initial reduction of the Phillips catalyst by olefins
Published in Journal of catalysis (01-09-2019)“…[Display omitted] •Organic products of reduction of Cr(VI)/SiO2 with olefins identified.•Oxygenates such as aldehydes and carboxylates adhere strongly to…”
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Reduction of the Phillips catalyst by various olefins: Stoichiometry, thermochemistry, reaction products and polymerization activity
Published in Journal of catalysis (01-12-2016)“…[Display omitted] •Cr(VI)/SiO2 reduced by ethylene and hexenes.•Olefin oxidation products are retained on the surface of Cr/SiO2.•Thermal decomposition…”
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Ethylene polymerization by Cr(III) salts on acidic carriers
Published in Applied catalysis. A, General (25-10-2016)“…[Display omitted] •Cr(III) compounds can be activated for ethylene polymerization by acidic carriers.•Such Cr(III) catalysts do not pass through the…”
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Journal Article -
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Influence of porosity on PE molecular weight from the Phillips Cr/silica catalyst
Published in Journal of catalysis (2009)“…The porosity of Phillips Cr/silica catalysts plays a major role in determining the molecular weight (MW) and molecular weight distribution obtained during…”
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Journal Article -
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Long-chain branching in PE from Cr/aluminophosphate catalysts
Published in Applied catalysis. A, General (20-11-2010)“…[Display omitted] ▶ Phosphate-treated Cr/alumina catalysts produce HDPE in which the long chain branching is concentrated into the low MW. ▶ This finding…”
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Journal Article -
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Silica supported single-walled carbon nanotubes as a modifier in polyethylene composites
Published in Journal of applied polymer science (15-01-2009)“…Composites have been made from single-wall carbon nanotubes in a polyethylene (PE) matrix, in which different methods of preparation were used to disperse the…”
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A comparative study of multimodal vs. bimodal polyethylene pipe resins for PE-100 applications
Published in Polymer engineering and science (01-09-2005)“…In this paper several high density polyethylene pipe resins are compared to polyethylene resins made in the Phillips Loop‐Slurry Process (single‐reactor),…”
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Short chain branching profiles in polyethylene from the Phillips Cr/silica catalyst
Published in Journal of polymer science. Part A, Polymer chemistry (01-08-2007)“…SEC and on‐line Fourier transform infrared spectroscopy analysis have been combined to study branching profiles from the Phillips Cr/silica catalyst. For the…”
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Journal Article -
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Initiation of the Phillips Cr(VI) Catalyst by Alkenes
Published in ACS catalysis (18-10-2024)“…As part of a continuing effort to better understand the initiation (i.e., the reduction and self-alkylation) of the Phillips commercial Cr(VI)/silica…”
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Controlling polymer properties with the Phillips chromium catalysts
Published in Industrial & engineering chemistry research (01-09-1988)Get full text
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Infrared spectrometric determination of catalysts used in the production of high-density polyethylene
Published in Analytical chemistry (Washington) (01-12-1981)Get full text
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5599887 Chromium catalyst compositions and ethylene polymerization processes therewith
Published in Journal of molecular catalysis. A, Chemical (01-11-1997)Get full text
Journal Article