Search Results - "Maza, Ricardo J."
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Synthesis and Reactivity of 1,1‐Diborylalkanes towards C–C Bond Formation and Related Mechanisms
Published in Advanced synthesis & catalysis (03-04-2018)“…gem‐Diborylalkanes have emerged as efficient reagents for synthesizing organoboron compounds through selective C−C bond‐forming reactions. Activation of the…”
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Borata‐Alkene Species as Nucleophilic Reservoir
Published in Advanced synthesis & catalysis (27-04-2021)“…α‐Monoboryl anions show remarkable stability due to the valence deficiency of the adjacent three‐coordinate boron center and can be expressed as its resonance…”
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Transition-Metal-Free Allylic Borylation of 1,3-Dienes
Published in Organic letters (05-04-2019)“…This work explains the reactivity of diboron reagents with 1,3-dienes in a transition-metal-free context. The sole addition of Na2CO3 (30 mol %) to…”
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4
Mapping the Electronic Structure and the Reactivity Trends for Stabilized α‐Boryl Carbanions
Published in Chemistry : a European journal (25-08-2021)“…The chemistry of stabilized α‐boryl carbanions shows remarkable diversity, and can enable many different synthetic routes towards efficient C−C bond formation…”
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5
Site‐Selective (Z)‐α‐Borylalkenyl Copper Systems for Nucleophilic Stereodefined Allylic Coupling
Published in Angewandte Chemie International Edition (12-09-2022)“…1,1‐Diborylalkenes can be transformed into (Z)‐skipped dienes through CuI‐phosphine catalyzed allylic coupling reactions. The energetically preferred formation…”
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Boron‐Copper 1,3‐Rearrangement: the New Concept Behind the Boryl Migration from C(sp2) in Alkenyl Boranes to C(sp3)
Published in Angewandte Chemie International Edition (24-07-2023)“…Regioselective borylcupration of borylated skipped (Z)‐dienes generates diborylated alkylcopper species that are involved in an intramolecular stereospecific…”
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7
The seriatim Cu(I) activation of 1,1,1′,1′-tetrapinacolborylethane to prospective ring closing
Published in Tetrahedron chem (01-12-2023)“…The synthesis and characterization of 1,1,1′1′-tetrapinacolborylethane is conducted to study the functionalization of that densely borylated small molecules…”
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8
Site‐Selective (Z)‐α‐Borylalkenyl Copper Systems for Nucleophilic Stereodefined Allylic Coupling
Published in Angewandte Chemie (12-09-2022)“…1,1‐Diborylalkenes can be transformed into (Z)‐skipped dienes through CuI‐phosphine catalyzed allylic coupling reactions. The energetically preferred formation…”
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Journal Article -
9
Boron‐Copper 1,3‐Rearrangement: the New Concept Behind the Boryl Migration from C(sp2) in Alkenyl Boranes to C(sp3)
Published in Angewandte Chemie (24-07-2023)“…Regioselective borylcupration of borylated skipped (Z)‐dienes generates diborylated alkylcopper species that are involved in an intramolecular stereospecific…”
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