Search Results - "Mayrhofer, Karl J. J."
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Importance and Challenges of Electrochemical in Situ Liquid Cell Electron Microscopy for Energy Conversion Research
Published in Accounts of chemical research (20-09-2016)“…The foreseeable worldwide energy and environmental challenges demand renewable alternative sources, energy conversion, and storage technologies. Therefore,…”
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Oxygen Electrochemistry as a Cornerstone for Sustainable Energy Conversion
Published in Angewandte Chemie International Edition (03-01-2014)“…Electrochemistry will play a vital role in creating sustainable energy solutions in the future, particularly for the conversion and storage of electrical into…”
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Molecular Insight in Structure and Activity of Highly Efficient, Low-Ir Ir–Ni Oxide Catalysts for Electrochemical Water Splitting (OER)
Published in Journal of the American Chemical Society (14-10-2015)“…Mixed bimetallic oxides offer great opportunities for a systematic tuning of electrocatalytic activity and stability. Here, we demonstrate the power of this…”
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Stability of Fe-N-C Catalysts in Acidic Medium Studied by Operando Spectroscopy
Published in Angewandte Chemie International Edition (19-10-2015)“…Fundamental understanding of non‐precious metal catalysts for the oxygen reduction reaction (ORR) is the nub for the successful replacement of noble Pt in fuel…”
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Engineering stable electrocatalysts by synergistic stabilization between carbide cores and Pt shells
Published in Nature materials (01-03-2020)“…Core–shell particles with earth-abundant cores represent an effective design strategy for improving the performance of noble metal catalysts, while…”
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Dissolution of Platinum: Limits for the Deployment of Electrochemical Energy Conversion?
Published in Angewandte Chemie International Edition (07-12-2012)“…Platinum stability: Dissolution of Pt, which is one major degradation mechanism in, for example, hydrogen/air fuel cells, was monitored under potentiodynamic…”
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The Particle Size Effect on the Oxygen Reduction Reaction Activity of Pt Catalysts: Influence of Electrolyte and Relation to Single Crystal Models
Published in Journal of the American Chemical Society (02-11-2011)“…The influence of particle size on the oxygen reduction reaction (ORR) activity of Pt was examined in three different electrolytes: two acidic solutions, with…”
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Toward Highly Stable Electrocatalysts via Nanoparticle Pore Confinement
Published in Journal of the American Chemical Society (19-12-2012)“…The durability of electrode materials is a limiting parameter for many electrochemical energy conversion systems. In particular, electrocatalysts for the…”
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Atomistic Insights into the Stability of Pt Single-Atom Electrocatalysts
Published in Journal of the American Chemical Society (09-09-2020)“…Single-atom catalysts (SACs) have quickly emerged as a new class of catalytic materials. When confronted with classical carbon-supported nanoparticulated…”
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The effect of particle proximity on the oxygen reduction rate of size-selected platinum clusters
Published in Nature materials (01-10-2013)“…The diminished surface-area-normalized catalytic activity of highly dispersed Pt nanoparticles compared with bulk Pt is particularly intricate, and not yet…”
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Adsorbate‐Induced Surface Segregation for Core–Shell Nanocatalysts
Published in Angewandte Chemie International Edition (01-01-2009)“…Coming to the surface: The surface composition of carbon‐supported Pt3Co catalyst particles changes upon a CO‐annealing treatment. Platinum atoms segregate to…”
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Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
Published in Nature materials (01-03-2007)“…One of the key objectives in fuel-cell technology is to improve and reduce Pt loading as the oxygen-reduction catalyst. Here, we show a fundamental…”
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13
CO2 Electroreduction on Silver Foams Modified by Ionic Liquids with Different Cation Side Chain Length
Published in ACS applied materials & interfaces (30-03-2022)“…Ionic liquids (ILs) are capable of tuning the kinetics of electroreduction processes by modifying a catalyst interface. In this work, a group of hydrophobic…”
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14
General Method for the Synthesis of Hollow Mesoporous Carbon Spheres with Tunable Textural Properties
Published in ACS applied materials & interfaces (17-06-2015)“…A versatile synthetic procedure to prepare hollow mesoporous carbon spheres (HMCS) is presented here. This approach is based on the deposition of a homogeneous…”
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Tuning the Electrocatalytic Performance of Ionic Liquid Modified Pt Catalysts for the Oxygen Reduction Reaction via Cationic Chain Engineering
Published in ACS catalysis (07-09-2018)“…Modifying Pt catalysts using hydrophobic ionic liquids (ILs) has been demonstrated to be a facile approach for boosting the performance of Pt catalysts for the…”
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The Common Intermediates of Oxygen Evolution and Dissolution Reactions during Water Electrolysis on Iridium
Published in Angewandte Chemie International Edition (23-02-2018)“…Understanding the pathways of catalyst degradation during the oxygen evolution reaction is a cornerstone in the development of efficient and stable…”
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Towards maximized utilization of iridium for the acidic oxygen evolution reaction
Published in Nano research (01-09-2019)“…The reduction in noble metal content for efficient oxygen evolution catalysis is a crucial aspect towards the large scale commercialisation of polymer…”
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Tuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst
Published in Nature communications (08-03-2016)“…Maximum atom efficiency as well as distinct chemoselectivity is expected for electrocatalysis on atomically dispersed (or single site) metal centres, but its…”
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Carbon Monoxide as a Promoter of Atomically Dispersed Platinum Catalyst in Electrochemical Hydrogen Evolution Reaction
Published in Journal of the American Chemical Society (28-11-2018)“…Carbon monoxide is widely known to poison Pt during heterogeneous catalysis owing to its strong donor–acceptor binding ability. Herein, we report a…”
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Online Monitoring of Transition-Metal Dissolution from a High-Ni-Content Cathode Material
Published in ACS applied materials & interfaces (21-07-2021)“…The dissolution of transition metals (TMs) from cathode materials and their deposition on the anode represents a serious degradation process and, with that, a…”
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