Search Results - "Matviitsuk, Anastassia"
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1
Enantio‐ and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes
Published in Angewandte Chemie International Edition (02-09-2019)“…A catalytic, enantio‐, and diastereoselective formation of sulfenyl acetals bearing multiple stereogenic centers is reported. Alkenyl aldehydes undergo a…”
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2
Enantio‐ and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes
Published in Angewandte Chemie (02-09-2019)“…A catalytic, enantio‐, and diastereoselective formation of sulfenyl acetals bearing multiple stereogenic centers is reported. Alkenyl aldehydes undergo a…”
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3
Catalytic, Enantioselective Sulfenofunctionalization of Alkenes: Development and Recent Advances
Published in Angewandte Chemie International Edition (02-11-2020)“…The last decade has witnessed a burgeoning of new methods for the enantioselective vicinal difunctionalization of alkenes initiated by electrophilic sulfenyl…”
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4
Organocatalyzed Knoevenagel-addition—simple access to carbon chain-elongated branched carbohydrates
Published in Tetrahedron (27-05-2013)“…Chain elongations of unprotected carbohydrates via a Knoevenagel-addition are described. The reactions were carried out in the presence of catalytic amounts of…”
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5
Skeletal Editing Approach to Bridge-Functionalized Bicyclo[1.1.1]pentanes from Azabicyclo[2.1.1]hexanes
Published in Journal of the American Chemical Society (24-05-2023)“…Azabicyclo[2.1.1]hexanes (aza-BCHs) and bicyclo[1.1.1]pentanes (BCPs) have emerged as attractive classes of sp 3-rich cores for replacing flat, aromatic…”
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6
Four into One: Organocatalyzed Stereoselective Conjugate Addition of Unprotected and Unactivated Carbohydrates
Published in Organic letters (17-10-2014)“…This paper proposes a new and stereoselective access to glycosides. This operationally simple approach achieved via base-catalyzed conjugate additions of…”
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7
Enantioselective Inter- and Intramolecular Sulfenofunctionalization of Unactivated Cyclic and (Z)‑Alkenes
Published in ACS catalysis (17-06-2022)“…A method for the enantioselective, Lewis base-catalyzed sulfenofunctionalization of cyclic and (Z)-alkenes is reported. The intermediate thiiranium ion…”
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8
Synthesis of Highly Functionalized 4-Iodo-7-azaindazoles via Condensation/Diels-Alder/Retro-Diels-Alder Cyclization of Iodoalkynones and 2-Hydrazineylpyrimidines
Published in Organic letters (08-12-2023)“…A method for the preparation of highly functionalized 4-iodo-7-azaindazoles is reported. These valuable heterocycles are synthesized via condensation of…”
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9
Aryloxide-Facilitated Catalyst Turnover in Enantioselective [alpha],[beta]-Unsaturated Acyl Ammonium Catalysis
Published in Angewandte Chemie International Edition (25-09-2017)“…A new general concept for [alpha],[beta]-unsaturated acyl ammonium catalysis is reported that uses p-nitrophenoxide release from an [alpha],[beta]-unsaturated…”
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10
Skeletal Editing Approach to Bridge-Functionalized Bicyclo1.1.1pentanes from Azabicyclo2.1.1hexanes
Published in Journal of the American Chemical Society (24-05-2023)“…Azabicyclo[2.1.1]hexanes (aza-BCHs) and bicyclo[1.1.1]pentanes (BCPs) have emerged as attractive classes of sp3-rich cores for replacing flat, aromatic groups…”
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11
Aryloxide‐Facilitated Catalyst Turnover in Enantioselective α,β‐Unsaturated Acyl Ammonium Catalysis
Published in Angewandte Chemie International Edition (25-09-2017)“…A new general concept for α,β‐unsaturated acyl ammonium catalysis is reported that uses p‐nitrophenoxide release from an α,β‐unsaturated p‐nitrophenyl ester…”
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12
Unanticipated Silyl Transfer in Enantioselective α,β-Unsaturated Acyl Ammonium Catalysis Using Silyl Nitronates
Published in Organic letters (03-01-2020)“…The use of silyl nitronates is reported for the isothiourea-catalyzed synthesis of γ-nitro-substituted silyl esters containing up to two contiguous…”
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13
Enantioselective Stereodivergent Nucleophile-Dependent Isothiourea-Catalysed Domino Reactions
Published in Chemistry : a European journal (05-12-2016)“…α,β‐Unsaturated acyl ammoniums generated from the reaction of α,β‐unsaturated 2,4,6‐trichlorophenol (TCP) esters bearing a pendent enone with an isothiourea…”
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14
Organocatalyzed Knoevenagel-additionasimple access to carbon chain-elongated branched carbohydrates
Published in Tetrahedron (01-05-2013)“…Chain elongations of unprotected carbohydrates via a Knoevenagel-addition are described. The reactions were carried out in the presence of catalytic amounts of…”
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15
Katalytische enantioselektive Sulfenofunktionalisierung von Alkenen: Entwicklung und aktuelle Fortschritte
Published in Angewandte Chemie (02-11-2020)“…In den letzten Jahren wurden vielzählige Methoden für die enantioselektive vicinale Difunktionalisierung von Alkenen durch elektrophilen…”
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16
Aryloxide‐Facilitated Catalyst Turnover in Enantioselective α,β‐Unsaturated Acyl Ammonium Catalysis
Published in Angewandte Chemie (25-09-2017)“…A new general concept for α,β‐unsaturated acyl ammonium catalysis is reported that uses p‐nitrophenoxide release from an α,β‐unsaturated p‐nitrophenyl ester…”
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Journal Article -
17
Aryloxide-Facilitated Catalyst Turnover in Enantioselective [alpha],[beta]-Unsaturated Acyl Ammonium Catalysis
Published in Angewandte Chemie (25-09-2017)“…A new general concept for [alpha],[beta]-unsaturated acyl ammonium catalysis is reported that uses p-nitrophenoxide release from an [alpha],[beta]-unsaturated…”
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18
Katalytische enantioselektive Sulfenofunktionalisierung von Alkenen: Entwicklung und aktuelle Fortschritte
Published in Angewandte Chemie (02-11-2020)“…Abstract In den letzten Jahren wurden vielzählige Methoden für die enantioselektive vicinale Difunktionalisierung von Alkenen durch elektrophilen…”
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