Search Results - "Matsuzaka, Hiroyuki"

Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination by Kameo, Hajime, Yamamoto, Jun, Asada, Ayaka, Nakazawa, Hiroshi, Matsuzaka, Hiroyuki, Bourissou, Didier

“…Metal–Lewis acid cooperation provides new opportunities in catalysis. In this work, we report a new type of palladium–borane cooperation involving anionic Pd0…”
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Linear Hydrocarbon Chain Growth from a Molecular Diruthenium Carbide Platform by Ohata, Jun, Teramoto, Akira, Fujita, Hiroaki, Takemoto, Shin, Matsuzaka, Hiroyuki

“…The formation of linear hydrocarbon chains by sequential coupling of C1 units on the metal surface is the central part of the Fischer–Tropsch (F-T) synthesis…”
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Tin–Ruthenium Cooperative Catalyst for Disproportionation of Formic Acid to Methanol by Fujita, Hiroaki, Takemoto, Shin, Matsuzaka, Hiroyuki

“…The disproportionation of formic acid to methanol and CO2 offers a renewable route to methanol avoiding the use of high-pressure H2. Previous studies have…”
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Synthesis, Structure, and Bonding Properties of Hypercoordinate Triorganotin Compounds Featuring Three O→Sn Interactions by Kameo, Hajime, Izumi, Daisuke, Matsuzaka, Hiroyuki

“…Here, heptacoordinate and hexacoordinate triorganotin compounds [o‐{(Ph2)(O)P}C6H4]3SnX (X=F (2 a), Cl (2 b), Me (2 f)) featuring three O→Sn interactions were…”
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Recent advances in the chemistry of ruthenium carbido complexes by Takemoto, Shin, Matsuzaka, Hiroyuki

“…► Progress of ruthenium carbido coordination chemistry in 2000–2010. ► Low-coordinate carbido derivatives with Ru–C multiple bonds. ► High-nuclearity clusters…”
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Experimental and Theoretical Investigation of an SN2‑type Pathway for Borate–Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes by Kameo, Hajime, Baba, Yuki, Sakaki, Shigeyoshi, Tanaka, Yudai, Matsuzaka, Hiroyuki

“…B–F σ-bond activation of a fluoroborate has been experimentally achieved through reactions with electron-rich iridium­(I) and palladium(0) complexes. The…”
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Fluorosilane Activation by Pd/Ni→Si–F→Lewis Acid Interaction: An Entry to Catalytic Sila-Negishi Coupling by Kameo, Hajime, Yamamoto, Hiroki, Ikeda, Koki, Isasa, Tomohito, Sakaki, Shigeyoshi, Matsuzaka, Hiroyuki, García-Rodeja, Yago, Miqueu, Karinne, Bourissou, Didier

“…A new mode of bond activation involving M→Z interactions is disclosed. Coordination to transition metals as σ-acceptor ligands was found to enable the…”
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Synthesis of Helicenes Utilizing Palladium-Catalyzed Double C−H Arylation Reaction by Kamikawa, Ken, Takemoto, Ippei, Takemoto, Shin, Matsuzaka, Hiroyuki

“…[5]- and [6]helicenes were synthesized in moderate to good yields from Z,Z-bis(bromostilbene)s by palladium-catalyzed double C−H arylation reaction. This…”
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Synthesis and reactivity of dinuclear CpRu tert-butylamido and cyclometallated Bis(trimethylsilyl)amido complexes by Takemoto, Shin, Oshimo, Masaki, Matsuzaka, Hiroyuki

“…Treatment of [Cp*Ru(μ3-Cl)]4 with 4 equiv of LiNHtBu in THF produces the dimeric tert-butylamido complex [Cp*Ru(μ-NHtBu)]2 (1b) in 85% yield. Complex 1b reacts…”
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Synthesis and N–H Reductive Elimination Study of Dinuclear Ruthenium Imido Dihydride Complexes by Takemoto, Shin, Yamazaki, Yusuke, Yamano, Takahiro, Mashima, Daichi, Matsuzaka, Hiroyuki

“…Diruthenium imido dihydride complexes [(Cp*Ru)2(μ-NAr)­(μ-H)2] (Ar = Ph (2a), p-MeOC6H4 (2b), p-ClC6H4 (2c), 2,6-Me2C6H3 (2d); Cp* = η5-C5Me5) have been…”
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A Bimetallic Ru2Pt Complex Containing a Trigonal-Planar μ3-Carbido Ligand: Formation, Structure, and Reactivity Relevant to the Fischer−Tropsch Process by Takemoto, Shin, Morita, Hidenobu, Karitani, Kenji, Fujiwara, Hideki, Matsuzaka, Hiroyuki

“…The bimetallic Ru2Pt complex [(Cp*Ru)2(μ2-NHPh)(μ2-H)(μ3-C)PtMe(PMe3)2][OTf] (3; Cp* = η5-C5Me5) containing a planar three-coordinate carbido ligand has been…”
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Synthesis and Reactivity of Coordinatively Unsaturated Dinuclear Ruthenium Bridging Imido Complexes by Takemoto, Shin, Kobayashi, Tomoharu, Ito, Takahiro, Inui, Akira, Karitani, Kenji, Katagiri, Sayuri, Masuhara, Yusaku, Matsuzaka, Hiroyuki

“…[Cp*Ru(μ-NHPh)]2 (Cp* = η5-C5Me5) reacted with CO, t-BuNC, Ph2SCH2, or Me3SiCCH to give the dinuclear ruthenium bridging imido complexes…”
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Stereoselective Synthesis of Axially Chiral N−C Bonds in N-Aryl Indoles by Kamikawa, Ken, Kinoshita, Shunsuke, Matsuzaka, Hiroyuki, Uemura, Motokazu

“…N-Aryl indoles with axially chiral N−C bonds were synthesized by stereoselective nucleophilic aromatic substitution reactions of planar chiral arene chromium…”
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Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination by Kameo, Hajime, Yamamoto, Jun, Asada, Ayaka, Nakazawa, Hiroshi, Matsuzaka, Hiroyuki, Bourissou, Didier

“…Metal–Lewis acid cooperation provides new opportunities in catalysis. In this work, we report a new type of palladium–borane cooperation involving anionic Pd0…”
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Dinuclear CpCo Amido and Alkoxo Complexes: Synthesis, Structures, and Reactivity by Takemoto, Shin, Honma, Takashi, Matsuzaka, Hiroyuki

“…New amido- and alkoxo-bridged dinuclear cobalt complexes [Cp*Co(μ-X)]2 (X = NHTol (2), NHBoc (3), OBn (4); Cp* = η5-C5Me5; Tol = p-tolyl; Boc = t-BuOCO; Bn =…”
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P−H Bond Addition to a Dinuclear Ruthenium Imido Complex: Synthesis and Reactivity of an Amido Phosphido Complex by Takemoto, Shin, Kimura, Yu, Kamikawa, Ken, Matsuzaka, Hiroyuki

“…Treatment of the imido complex [(Cp*Ru)2(μ2-NPh)(μ2-CO)] (3; Cp* = η5-C5Me5) with phenylphosphine resulted in the P−H bond addition across the Ru−N bonds to…”
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Synthesis and Reactivity of a Dithiolate-Bridged Ruthenium−Rhodium Heterobimetallic Dihydride Complex by Takemoto, Shin, Shimadzu, Daisuke, Kamikawa, Ken, Matsuzaka, Hiroyuki, Nomura, Ryoki

“…The new dithiolate-bridged Ru−Rh heterobimetallic dihydride complex [Cp*Rh(μ2-1,2-S2C6H4)(μ2-H)RuH(PPh3)2] (2) has been prepared, and its reactions with CO and…”
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Diiron Amido−Imido Complex [(CpFe)2(μ2-NHPh)(μ2-NPh)]:  Synthesis and a Net Hydrogen Atom Abstraction Reaction To Form a Bis(imido) Complex by Takemoto, Shin, Ogura, Shin-ichiro, Yo, Ho, Hosokoshi, Yuko, Kamikawa, Ken, Matsuzaka, Hiroyuki

“…A reaction between [Cp*FeCl] x and LiNHPh (1 equiv to Fe) produces a new paramagnetic Fe(II)−Fe(III) μ2-amido−μ2-imido complex [(Cp*Fe)2(μ2-NHPh)(μ2-NPh)] (1),…”
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Recent topics on catalytic transformations of aromatic molecules via η6-arene transition metal complexes by Takemoto, Shin, Matsuzaka, Hiroyuki

“…[Display omitted] •Catalytic transformations of aromatic molecules via η6-arene complexes are reviewed.•Catalytic aryl-heteroatom bond activation and…”
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Recent topics on catalytic transformations of aromatic molecules via η 6 -arene transition metal complexes by Takemoto, Shin, Matsuzaka, Hiroyuki

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