Search Results - "Mathieson, S."
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Digitization of multistep organic synthesis in reactionware for on-demand pharmaceuticals
Published in Science (American Association for the Advancement of Science) (19-01-2018)“…Chemical manufacturing is often done at large facilities that require a sizable capital investment and then produce key compounds for a finite period. We…”
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Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions
Published in Nature chemistry (04-09-2011)“…Oxo-transfer chemistry mediated by iron underpins many biological processes and today is emerging as synthetically very important for the catalytic oxidation…”
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Self-Sorting of Heteroanions in the Assembly of Cross-Shaped Polyoxometalate Clusters
Published in Journal of the American Chemical Society (21-02-2018)“…Heteroanion (HA) moieties have a key role in templating of heteropolyoxometalate (HPA) architectures, but clusters templated by two different templates are…”
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A Versatile Tripodal Cu(I) Reagent for C–N Bond Construction via Nitrene-Transfer Chemistry: Catalytic Perspectives and Mechanistic Insights on C–H Aminations/Amidinations and Olefin Aziridinations
Published in Journal of the American Chemical Society (13-08-2014)“…A CuI catalyst (1), supported by a framework of strongly basic guanidinato moieties, mediates nitrene-transfer from PhINR sources to a wide variety of…”
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What proportion of patients with chronic noncancer pain are prescribed an opioid medicine? Systematic review and meta‐regression of observational studies
Published in Journal of internal medicine (01-05-2020)“…Guidelines now discourage opioid analgesics for chronic noncancer pain because the benefits frequently do not outweigh the harms. We aimed to determine the…”
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Satellite-based measurements of surface deformation reveal fluid flow associated with the geological storage of carbon dioxide
Published in Geophysical research letters (01-02-2010)“…Interferometric Synthetic Aperture Radar (InSAR) data, gathered over the In Salah CO2 storage project in Algeria, provide an early indication that…”
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Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes
Published in Inorganic chemistry (02-01-2012)“…A series of dinuclear triple-stranded complexes, [Fe2L3⊃X]X6 [X = BF4 – (1), ClO4 – (2)], [Fe2L3⊃SO4]2(SO4)5 (3), [Fe2L3⊃Br](BPh4)6 (4), Fe2L3(NO3)Br6 (5),…”
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classification of spin frustration in molecular magnets from a physical study of large odd-numbered-metal, odd electron rings
Published in Proceedings of the National Academy of Sciences - PNAS (20-11-2012)“…The term “frustration” in the context of magnetism was originally used by P. W. Anderson and quickly adopted for application to the description of spin glasses…”
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Adherence to a Mediterranean diet and Alzheimer’s disease risk in an Australian population
Published in Translational psychiatry (02-10-2012)“…The Mediterranean diet (MeDi), due to its correlation with a low morbidity and mortality for many chronic diseases, has been widely recognised as a healthy…”
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10
In-depth performance analysis of an EEG based neonatal seizure detection algorithm
Published in Clinical neurophysiology (01-05-2016)“…Highlights • A novel method for in-depth analysis of neonatal seizure detection algorithms is proposed. • The analysis estimated how seizure features are…”
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Does vibration training reduce the fall risk profile of frail older people admitted to a rehabilitation facility? A randomised controlled trial
Published in Disability and rehabilitation (21-05-2016)“…Purpose: To determine the effect of Vibration Training (VT) on functional ability and falls risk among a group of frail older people admitted to an inpatient…”
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Following the Reaction of Heteroanions inside a {W18O56} Polyoxometalate Nanocage by NMR Spectroscopy and Mass Spectrometry
Published in Angewandte Chemie International Edition (26-06-2015)“…By incorporating phosphorus(III)‐based anions into a polyoxometalate cage, a new type of tungsten‐based unconventional Dawson‐like cluster,…”
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Mapping the Sequential Self-Assembly of Heterometallic Clusters: From a Helix to a Grid
Published in Angewandte Chemie International Edition (16-05-2011)“…Two iron/cobalt mixed‐valence clusters were synthesized using multidentate polypyridyl ligands (see picture: FeII orange, FeIII yellow, CoII blue, O red). A…”
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Continuous parallel ESI-MS analysis of reactions carried out in a bespoke 3D printed device
Published in Beilstein journal of nanotechnology (29-04-2013)“…Herein, we present an approach for the rapid, straightforward and economical preparation of a tailored reactor device using three-dimensional (3D) printing,…”
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The Effect of the Spacer of Bis(biurea) Ligands on the Structure of A2L3-type (A=anion) Phosphate Complexes
Published in Chemistry : a European journal (02-02-2015)“…By tuning the length and rigidity of the spacer of bis(biurea) ligands L, three structural motifs of the A2L3 complexes (A represents anion, here…”
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P788: Electro-clinical characteristics of epileptic seizures in preterm infants
Published in Clinical neurophysiology (01-06-2014)Get full text
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Nanoscale Control of Polyoxometalate Assembly: A {Mn8W4} Cluster within a {W36Si4Mn10} Cluster Showing a New Type of Isomerism
Published in Chemistry : a European journal (25-02-2013)“…Two near isomeric clusters containing a novel {Mn8W4} Keggin cluster within a [W36Mn10Si4O136(OH)4(H2O)8]24− cluster are reported: K10Li14…”
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223 Clinical Utility of an Automated Neonatal Seizure Detection Algorithm
Published in Archives of disease in childhood (01-10-2012)“…Background/Aims EEG is the gold standard for the identification of neonatal seizures as the vast majority of electrographic seizures do not have a clinical…”
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A systematic review of the measurement properties and usage of the Physiotherapy Evidence Database (PEDRO) scale
Published in Physiotherapy (01-05-2015)Get full text
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Fish assemblages of European tidal marshes: a comparison based on species, families and functional guilds
Published in Marine ecology. Progress series (Halstenbek) (05-10-2000)“…In considering the use of estuarine habitats by fish assemblages, alternative views of the assemblage are increasingly being explored, based on functional…”
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