Search Results - "Massou, Stéphane"

Evidence for genuine hydrogen bonding in gold(I) complexes by Rigoulet, Mathilde, Massou, Stéphane, Carrizo, E. Daiann Sosa, Mallet-Ladeira, Sonia, Amgoune, Abderrahmane, Miqueuc, Karinne, Bourissou, Didier

“…The ability of gold to act as proton acceptor and participate in hydrogen bonding remains an open question. Here, we report the synthesis and characterization…”
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Cyclic (Amino)(Phosphonium Bora‐Ylide)Silanone: A Remarkable Room‐Temperature‐Persistent Silanone by Rosas‐Sánchez, Alfredo, Alvarado‐Beltran, Isabel, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Massou, Stéphane, Hashizume, Daisuke, Branchadell, Vicenç, Kato, Tsuyoshi

“…A silanone substituted by bulky amino and phosphonium bora‐ylide substituents has been isolated in crystalline form. Thanks to the exceptionally strong…”
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Catalytic Dehydrogenation of (Di)Amine-Boranes with a Geometrically Constrained Phosphine-Borane Lewis Pair by Boudjelel, Maxime, Sosa Carrizo, E. Daiann, Mallet−Ladeira, Sonia, Massou, Stéphane, Miqueu, Karinne, Bouhadir, Ghenwa, Bourissou, Didier

“…The o-phenylene bridged phosphine-borane iPr2P­(o-C6H4)­B­(Fxyl)2 2 was prepared. Despite ring strain, it adopts a closed form, as substantiated by NMR, XRD,…”
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Room‐Temperature Functionalization of N2 to Borylamine at a Molybdenum Complex by Espada, Maria F., Bennaamane, Soukaina, Liao, Qian, Saffon‐Merceron, Nathalie, Massou, Stéphane, Clot, Eric, Nebra, Noel, Fustier‐Boutignon, Marie, Mézailles, Nicolas

“…Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)MoIV–nitrido complex generated by N2 splitting is reported. The imido–hydride and…”
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Gelation Mechanism Revealed in Organometallic Gels: Prevalence of van der Waals Interactions on Oligomerization by Coordination Chemistry by Wang, Yinping, Coppel, Yannick, Fitremann, Juliette, Massou, Stéphane, Mingotaud, Christophe, Kahn, Myrtil L.

“…Shaping of nanomaterials is a necessary step for their inclusion in electronic devices and batteries. For this purpose, the formulation of a moldable material…”
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Exceptionally Strong Electron‐Donating Ability of Bora‐Ylide Substituent vis‐à‐vis Silylene and Silylium Ion by Rosas‐Sánchez, Alfredo, Alvarado‐Beltran, Isabel, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Massou, Stéphane, Branchadell, Vicenç, Kato, Tsuyoshi

“…Electropositive boron‐based substituent (phosphonium bora‐ylide) with an exceptionally strong π‐ and σ‐electron donating character dramatically increases the…”
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Mechanochemical Synthesis and Biological Evaluation of Novel Isoniazid Derivatives with Potent Antitubercular Activity by Oliveira, Paulo F M, Guidetti, Brigitte, Chamayou, Alain, André-Barrès, Christiane, Madacki, Jan, Korduláková, Jana, Mori, Giorgia, Orena, Beatrice Silvia, Chiarelli, Laurent Roberto, Pasca, Maria Rosalia, Lherbet, Christian, Carayon, Chantal, Massou, Stéphane, Baron, Michel, Baltas, Michel

“…A series of isoniazid derivatives bearing a phenolic or heteroaromatic coupled frame were obtained by mechanochemical means. Their pH stability and their…”
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Isotopic Studies of Metabolic Systems by Mass Spectrometry: Using Pascal’s Triangle To Produce Biological Standards with Fully Controlled Labeling Patterns by Millard, Pierre, Massou, Stéphane, Portais, Jean-Charles, Létisse, Fabien

“…Mass spectrometry (MS) is widely used for isotopic studies of metabolism in which detailed information about biochemical processes is obtained from the…”
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A Stable N‐Hetero‐Rh‐Metallacyclic Silylene by Takahashi, Shintaro, Bellan, Ekaterina, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Massou, Stéphane, Nakata, Norio, Hashizume, Daisuke, Branchadell, Vicenç, Kato, Tsuyoshi

“…A cyclic (amino)metal‐substituted dicoordinated silylene derivative has been synthesized and fully characterized. Of particular interest is that the…”
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Sampling of intracellular metabolites for stationary and non-stationary C-13 metabolic flux analysis in [i]Escherichia coli[/i] by Millard, Pierre, Massou, Stéphane, Wittmann, Christoph, Portais, Jean-Charles, Letisse, Fabien

“…The analysis of metabolic intermediates is a rich source of isotopic information for C-13 metabolic flux analysis (C-13-MFA) and extends the range of its…”
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Room-Temperature Functionalization of N 2 to Borylamine at a Molybdenum Complex by Espada, Maria F, Bennaamane, Soukaina, Liao, Qian, Saffon-Merceron, Nathalie, Massou, Stéphane, Clot, Eric, Nebra, Noel, Fustier-Boutignon, Marie, Mézailles, Nicolas

“…Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)Mo -nitrido complex generated by N splitting is reported. The imido-hydride and…”
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Synthesis of a Stable N‐Hetero ‐ Rh I ‐Metallacyclic Silanone by Takahashi, Shintaro, Nakaya, Kazuki, Frutos, María, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Massou, Stéphane, Nakata, Norio, Hashizume, Daisuke, Branchadell, Vicenç, Kato, Tsuyoshi

“…Abstract A novel N‐hetero‐Rh I ‐metallacyclic silanone 2 has been synthesized. The silanone 2 , showing an extremely large dimerization energy (Δ G =+86.2 kcal…”
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Ultrafast Quantitative 2D NMR: An Efficient Tool for the Measurement of Specific Isotopic Enrichments in Complex Biological Mixtures by Giraudeau, Patrick, Massou, Stéphane, Robin, Yoann, Cahoreau, Edern, Portais, Jean-Charles, Akoka, Serge

“…Two-dimensional nuclear magnetic resonance (2D NMR) is a promising tool for studying metabolic fluxes by measuring 13C-enrichments in complex mixtures of…”
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Synthesis of a Stable N‐Hetero‐RhI‐Metallacyclic Silanone by Takahashi, Shintaro, Nakaya, Kazuki, Frutos, María, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Massou, Stéphane, Nakata, Norio, Hashizume, Daisuke, Branchadell, Vicenç, Kato, Tsuyoshi

“…A novel N‐hetero‐RhI‐metallacyclic silanone 2 has been synthesized. The silanone 2, showing an extremely large dimerization energy (ΔG=+86.2 kcal mol−1),…”
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A novel platform for automated high-throughput fluxome profiling of metabolic variants by Heux, Stéphanie, Poinot, Juliette, Massou, Stéphane, Sokol, Serguei, Portais, Jean-Charles

“…Advances in metabolic engineering are enabling the creation of a large number of cell factories. However, high-throughput platforms do not yet exist for…”
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The Ethylmalonyl-CoA Pathway Is Used in Place of the Glyoxylate Cycle by Methylobacterium extorquens AM1 during Growth on Acetate by Schneider, Kathrin, Peyraud, Rémi, Kiefer, Patrick, Christen, Philipp, Delmotte, Nathanaël, Massou, Stéphane, Portais, Jean-Charles, Vorholt, Julia A.

“…Acetyl-CoA assimilation was extensively studied in organisms harboring the glyoxylate cycle. In this study, we analyzed the metabolism of the facultative…”
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Cyclometalated gold(iii) complexes: noticeable differences between (N,C) and (P,C) ligands in migratory insertion by Serra, Jordi, Font, Pau, Sosa Carrizo, E Daiann, Mallet-Ladeira, Sonia, Massou, Stéphane, Parella, Teodor, Miqueu, Karinne, Amgoune, Abderrahmane, Ribas, Xavi, Bourissou, Didier

“…Gold(iii) complexes are garnering increasing interest for opto-electronic, therapeutic and catalytic applications. But so far, very little is known about the…”
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Fast Spatially Encoded 3D NMR Strategies for C-13-Based Metabolic Flux Analysis by Boisseau, Renaud, Charrier, Benoit, Massou, Stéphane, Portais, Jean-Charles, Akoka, Serge, Giraudeau, Patrick

“…The measurement of site-specific C-13 enrichments in complex mixtures of C-13-labeled metabolites is a powerful tool for metabolic flux analysis. One of the…”
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Genome-scale reconstruction and system level investigation of the metabolic network of Methylobacterium extorquens AM1 by Peyraud, Rémi, Schneider, Kathrin, Kiefer, Patrick, Massou, Stéphane, Vorholt, Julia A, Portais, Jean-Charles

“…Methylotrophic microorganisms are playing a key role in biogeochemical processes - especially the global carbon cycle - and have gained interest for…”
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A new and specific mode of stabilization of metallic nanoparticles by Favier, Isabelle, Massou, Stéphane, Teuma, Emmanuelle, Philippot, Karine, Chaudret, Bruno, Gómez, Montserrat

“…We report in this paper the stabilization of ruthenium nanoparticles using a very simple ligand (4-(3-phenylpropyl)pyridine), through strong pi-coordination of…”
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