Search Results - "Mashkovsky, Igor S"
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Removal of VOCs by Ozone: n-Alkane Oxidation under Mild Conditions
Published in Catalysts (01-04-2021)“…Volatile organic compounds (VOCs) have a negative effect on both humans and the environment; therefore, it is crucial to minimize their emission. The…”
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Reversible Transformations of Palladium–Indium Intermetallic Nanoparticles upon Repetitive Redox Treatments in H2/O2
Published in Crystals (Basel) (01-09-2023)“…The transformations of chemical states and structures occurring in the PdIn/Al2O3 catalyst upon redox treatments in different gaseous atmospheres at different…”
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Single-Atom Alloy Pd1Ag10/CeO2–ZrO2 as a Promising Catalyst for Selective Alkyne Hydrogenation
Published in Inorganics (01-04-2023)“…The effect of support on the performance of Pd1Ag10/Al2O3 and Pd1Ag10/CeO2–ZrO2 catalysts in the selective hydrogenation of diphenylacetylene (DPA) was…”
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Local Structure of Pd1 Single Sites on the Surface of PdIn Intermetallic Nanoparticles: A Combined DFT and CO-DRIFTS Study
Published in Catalysts (01-11-2021)“…Local structure of Pd1 single sites on the surface of Pd1In1 intermetallic nanoparticles supported on α-Al2O3 was investigated by the combination of CO-DRIFTS…”
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Liquid-Phase Hydrogenation of 1-Phenyl-1-propyne on the Pd1Ag3/Al2O3 Single-Atom Alloy Catalyst: Kinetic Modeling and the Reaction Mechanism
Published in Nanomaterials (Basel, Switzerland) (03-12-2021)“…This research was focused on studying the performance of the Pd1Ag3/Al2O3 single-atom alloy (SAA) in the liquid-phase hydrogenation of di-substituted alkyne…”
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Highly-Ordered PdIn Intermetallic Nanostructures Obtained from Heterobimetallic Acetate Complex: Formation and Catalytic Properties in Diphenylacetylene Hydrogenation
Published in Nanomaterials (Basel, Switzerland) (28-09-2018)“…Formation of PdIn intermetallic nanoparticles supported on α-Al₂O₃ was investigated by X-ray powder diffraction (XRD), transmission electron microscopy (TEM),…”
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Particle size effect in liquid-phase hydrogenation of phenylacetylene over Pd catalysts: Experimental data and theoretical analysis
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-02-2019)“…[Display omitted] •Kinetics of phenylacetylene hydrogenation was studied.•Pd on alumina with different metal dispersion were investigated.•TOF increases with…”
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Selective Single‐Site Pd−In Hydrogenation Catalyst for Production of Enhanced Magnetic Resonance Signals using Parahydrogen
Published in Chemistry : a European journal (21-02-2018)“…Pd−In/Al2O3 single‐site catalyst was able to show high selectivity (up to 98 %) in the gas phase semihydrogenation of propyne. Formation of intermetallic Pd−In…”
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Novel Pd–Zn/C catalyst for selective alkyne hydrogenation: Evidence for the formation of Pd–Zn bimetallic alloy particles
Published in Mendeleev communications (01-11-2014)“…The formation of Pd–Zn alloy was revealed in a highly selective Pd–Zn/C catalyst for acetylene hydrogenation prepared via the heterobimetallic PdZn(OAc)4(OH2)…”
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Frontispiece: Selective Single‐Site Pd−In Hydrogenation Catalyst for Production of Enhanced Magnetic Resonance Signals using Parahydrogen
Published in Chemistry : a European journal (21-02-2018)“…Pd−In/Al2O3 single‐site catalyst was able to show high selectivity in the gas phase semihydrogenation of propyne. When parahydrogen was used 3400‐fold NMR…”
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Rh-Based Intermetallic Rh–In/SiO 2 Catalyst for Parahydrogen-Induced Polarization
Published in Journal of physical chemistry. C (18-04-2024)Get full text
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Rh-Based Intermetallic Rh–In/SiO2 Catalyst for Parahydrogen-Induced Polarization
Published in Journal of physical chemistry. C (18-04-2024)“…Heterogeneous catalysts are of considerable interest for their ability to produce gases with highly polarized nuclear spins by using parahydrogen. Rh catalysts…”
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Experimental and theoretical analysis of particle size effect in liquid-phase hydrogenation of diphenylacetylene
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-01-2021)“…[Display omitted] •Relationship between Pd particle size and DPA hydrogenation kinetics revealed.•Pd/Al2O3 catalysts with different average Pd particle sizes…”
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An egg-shell PdAg/α-Al2O3 single-atom alloy catalyst for selective acetylene hydrogenation
Published in Mendeleev communications (01-11-2023)Get full text
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Performance of PdAu/Al2O3 egg-shell catalyst with isolated Pd1 sites for selective hydrogenation of acetylene
Published in Mendeleev communications (01-09-2024)“…[Display omitted] A herein proposed PdAu/Al2O3 egg-shell catalyst for selective acetylene hydrogenation combines two factors to provide perfect performance:…”
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In situ FTIR study of surface site transformations in Pd3In/α-Al2O3 and Pd3Ag/α-Al2O3 induced by CO adsorption
Published in Mendeleev communications (01-11-2022)“…[Display omitted] In the course of the treatment of Pd3Ag/α-Al2O3 in 0.5%CO + He at 200 °C, intense transformation of single atom Pd1 surface sites isolated…”
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PdCu/Al2O3 catalyst for Sonogashira cross-coupling: effect of a Pd/Cu ratio on the catalytic performance
Published in Mendeleev communications (01-09-2018)“…[Display omitted] The catalytic performance of 3 wt% Pd–Cu/Al2O3 containing bimetallic alloy Pd–Cu nanoparticles strongly depends on the Pd/Cu ratio in the…”
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Organic and hybrid systems: from science to practice
Published in Mendeleev communications (01-09-2017)“…[Display omitted] Organic systems still dominate several traditional areas of chemical science and well-known applications, such as the synthesis of…”
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Intermetallic PdxIny/Al2O3 catalysts with isolated single-atom Pd sites for one-pot hydrogenation of diphenylacetylene into trans-stilbene
Published in Mendeleev communications (01-07-2020)“…[Display omitted] Novel one-pot synthesis of trans-stilbene comprises hydrogenation of diphenylacetylene into cis-stilbene followed by its hydroisomerization,…”
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