Search Results - "Markus, Charles R"
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Mid-infrared cross-comb spectroscopy
Published in Nature communications (24-02-2023)“…Dual-comb spectroscopy has been proven beneficial in molecular characterization but remains challenging in the mid-infrared region due to difficulties in…”
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Well-Defined Cobalt(I) Dihydrogen Catalyst: Experimental Evidence for a Co(I)/Co(III) Redox Process in Olefin Hydrogenation
Published in Journal of the American Chemical Society (14-09-2016)“…The synthesis of a cobalt dihydrogen CoI-(H2) complex prepared from a CoI-(N2) precursor supported by a monoanionic pincer bis(carbene) ligand, MesCCC (MesCCC…”
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Chemical Kinetic Study of the Reaction of CH2OO with CH3O2
Published in The journal of physical chemistry letters (04-04-2024)“…Criegee intermediates play an important role in the oxidizing capacity of the Earth’s troposphere. Although extensive studies have been conducted on Criegee…”
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Vibrational Excitation Hindering an Ion-Molecule Reaction: The c−C3H2+ − H2 Collision Complex
Published in Physical review letters (12-06-2020)“…Experiments within a cryogenic 22-pole ion trap have revealed an interesting reaction dynamic phenomenon, where rovibrational excitation of an ionic molecule…”
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Chemical Kinetic Study of the Reaction of CH 2 OO with CH 3 O 2
Published in The journal of physical chemistry letters (04-04-2024)“…Criegee intermediates play an important role in the oxidizing capacity of the Earth's troposphere. Although extensive studies have been conducted on Criegee…”
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OH Roaming and Beyond in the Unimolecular Decay of the Methyl-Ethyl-Substituted Criegee Intermediate: Observations and Predictions
Published in Journal of the American Chemical Society (06-09-2023)“…Alkene ozonolysis generates short-lived Criegee intermediates that are a significant source of hydroxyl (OH) radicals. This study demonstrates that roaming of…”
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Bimolecular Reaction of Methyl-Ethyl-Substituted Criegee Intermediate with SO2
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-11-2023)“…Methyl-ethyl-substituted Criegee intermediate (MECI) is a four-carbon carbonyl oxide that is formed in the ozonolysis of some asymmetric alkenes. MECI is…”
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High-resolution infrared action spectroscopy of the fundamental vibrational band of CN
Published in Journal of molecular spectroscopy (01-11-2020)“…[Display omitted] •First high-resolution infrared study of CN+.•Study of two isotopic species, C14N+ and C15N+.•Derivation of an isotopically invariant…”
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Improving cavity-enhanced spectroscopy of molecular ions in the mid-infrared with up-conversion detection and Brewster-plate spoilers
Published in Optics express (20-02-2017)“…The performance of sensitive spectroscopic methods in the mid-IR is often limited by fringing due to parasitic etalons and the background noise in mid-infrared…”
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HIGH PRECISION ROVIBRATIONAL SPECTROSCOPY OF OH
Published in The Astrophysical journal (01-02-2016)“…ABSTRACT The molecular ion OH+ has long been known to be an important component of the interstellar medium. Its relative abundance can be used to indirectly…”
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Photochemistry of Ozone–Water Ices
Published in ACS earth and space chemistry (21-11-2019)“…Ozone is known to be present within the surface ice of Jupiter’s moon Ganymede as well as Saturn’s moons Dione and Rhea. Given the ubiquity of solar photons…”
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Reaction of methane and UV-activated perchlorate: Relevance to heterogeneous loss of methane in the atmosphere of Mars
Published in Icarus (New York, N.Y. 1962) (01-04-2022)“…The absence of significant detectable signatures of organic molecules in the atmosphere and on the surface of Mars is a major unsolved puzzle. One possible…”
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Sub-Doppler rovibrational spectroscopy of the ν1 fundamental band of D2H
Published in Journal of molecular spectroscopy (01-01-2019)“…[Display omitted] •We have measured 37 fundamental band rovibrational transitions of D2H+.•Transitions were determined with MHz-level uncertainty.•An improved…”
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Vibrational Excitation Hindering an Ion-Molecule Reaction: The c − C 3 H 2 + − H 2 Collision Complex
Published in Physical review letters (01-06-2020)Get full text
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High-resolution rovibrational spectroscopy of c-C3H2+: The ν7 C–H antisymmetric stretching band
Published in Journal of molecular structure (15-08-2020)“…The ν7 antisymmetric C–H stretching fundamental of c-C3H2+ has been characterized in a cryogenic 22-pole ion trap by a novel type of action spectroscopy, in…”
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Sub-Doppler rovibrational spectroscopy of the ν 1 fundamental band of D2H
Published in Journal of molecular spectroscopy (01-01-2019)Get full text
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The fundamental rotational transition of NO
Published in Journal of molecular spectroscopy (01-04-2021)“…[Display omitted] •The 22-pole trap machine COLTRAP investigates NO+ ions at low temperature.•The three lowest rotational transitions of 14NO+ are…”
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Extended sub-Doppler resolution spectroscopy of the ν3 band of methane
Published in Journal of quantitative spectroscopy & radiative transfer (01-08-2018)“…•Sub-Doppler mid-infrared spectroscopy of methane.•Measured 22 previously Doppler-broadened transitions in the ν3 band.•Uncertainties improved by at least an…”
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