Search Results - "Mark R. Ringenberg"
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Redox-Active Ligands in Catalysis
Published in Angewandte Chemie International Edition (08-10-2012)“…Nature’s use of redox‐active moieties combined with 3d transition‐metal ions is a powerful strategy to promote multi‐electron catalytic reactions. The ability…”
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Exchange coupling and single molecule magnetism in redox-active tetraoxolene-bridged dilanthanide complexes
Published in Chemical science (Cambridge) (2018)“…Tetraoxolene radical-bridged lanthanide SMM systems were prepared for the first time by reduction of the respective neutral compounds. Magnetic measurements…”
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Mesoionic Imines (MIIs): Strong Donors and Versatile Ligands for Transition Metals and Main Group Substrates
Published in Angewandte Chemie International Edition (20-06-2022)“…We report the synthesis and the reactivity of 1,2,3‐triazolin‐5‐imine type mesoionic imines (MIIs). The MIIs are accessible by a base‐mediated cycloaddition…”
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Merging the best of two worlds: artificial metalloenzymes for enantioselective catalysis
Published in Chemical communications (Cambridge, England) (01-01-2011)“…Artificial metalloenzymes result from combining a catalytically active organometallic moiety with a macromolecular host. The resulting hybrid catalysts combine…”
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Redox Induced Configurational Isomerization of Bisphosphine–Tricarbonyliron(I) Complexes and the Difference a Ferrocene Makes
Published in Inorganic chemistry (03-07-2017)“…The tricarbonyliron (TCFe) complexes Fe(CO)3(dppf) and Fe(CO)3(dppp), where dppf = 1,1′-bis(diphenylphosphino)ferrocene and dppp =…”
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Cooperativity‐Driven Reactivity of a Dinuclear Copper Dimethylglyoxime Complex
Published in Chemistry : a European journal (18-04-2023)“…In this report, we present the dinuclear copper(II) dimethylglyoxime (H2dmg) complex [Cu2(H2dmg)(Hdmg)(dmg)]+ (1), which, in contrast to its mononuclear…”
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Polyfunctional Imidazolium Aryloxide Betaine/Lewis Acid Catalysts as Tools for the Asymmetric Synthesis of Disfavored Diastereomers
Published in Journal of the American Chemical Society (31-07-2019)“…Enzymes are Nature’s polyfunctional catalysts tailor-made for specific biochemical synthetic transformations, which often proceed with almost perfect…”
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Control of Molecular Packing in Crystal and Electron Communication of Two Ferrocenyl Moieties across Chiral Isomannide or Isosorbide Bridge
Published in Crystals (Basel) (01-03-2023)“…Intramolecular electronic communication between electrochemically active groups connected by a bridging moiety can be modified through small changes in the…”
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Redox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand
Published in Journal of the American Chemical Society (23-01-2008)“…Organometallic complexes containing non-innocent ligands of the type Cp*Ir( t BAFPh)(1), where H2 t BAFPh is…”
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Beyond Common Metal-Metal Bonds, κ 3 -Bis(donor)ferrocenyl→Transition-Metal Interactions
Published in Chemistry : a European journal (18-02-2019)“…Ligands with 1,1'-bis(donor)ferrocene motif are capable of a wide range of binding modes, including the trans chelation mode in which there is a Fe-M…”
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Beyond Common Metal–Metal Bonds, κ3‐Bis(donor)ferrocenyl→Transition‐Metal Interactions
Published in Chemistry : a European journal (18-02-2019)“…Ligands with 1,1′‐bis(donor)ferrocene motif are capable of a wide range of binding modes, including the trans chelation mode in which there is a Fe−M…”
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Organobimetallic Nickel‐Iron Complexes, Valence Tautomer or Charge Localized Ferrocene Ligands Upon Oxidation
Published in European journal of inorganic chemistry (16-02-2022)“…[[CpNi(dRpf)]+ (dRpf=1,1’‐bis(di‐R‐phosphino)ferrocene, R=phenyl (dppf) [1]+, iso‐propyl (dippf) [2]+, and cyclohexyl (dcpf) [3]+),…”
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[(η6-p-Cymene)[3-(pyrid-2-yl)-1,2,4,5-tetrazine]chlororuthenium(II)]+, Redox Noninnocence and Dienophile Addition to Coordinated Tetrazine
Published in Inorganic chemistry (03-05-2021)“…The bidentate ligand 3-(pyrid-2-yl)-1,2,4,5-tetrazine (TzPy) coordinated in the complex [CyRuCl(TzPy)]PF6 ([1]+; Cy = η6-p-cymene) shows noninnocent behavior…”
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Anodic Mechanism of 1,1′‐Bis(diphenylphosphino)ferrocenedicarbonylnickel Determined by Low‐Temperature Spectroelectrochemistry
Published in European journal of inorganic chemistry (26-05-2019)“…[Ni(CO)2(dppf)] [1] {dppf = 1,1′‐bis(diphenylphosphino)ferrocene} was made by reductive carbonylation of [NiCl2(dppf)] with [Fe(CO)5], similar to our recent…”
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Reductive Carbonylation of [NiCl2(dippf)] (dippf = 1,1′-Bis(diisopropylphosphino)ferrocene) with Fe(CO)5 and (Spectro)electrochemistry of the Resulting [Ni(CO)2(dippf)]
Published in Organometallics (28-01-2019)“…[Ni(CO)2(dippf)] [1] (dippf = 1,1′-bis(diisopropylphosphino)ferrocene) was synthesized from [NiCl2(dippf)] and [Fe(CO)5] at elevated temperature/pressure…”
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Electrochemical Reduction Mechanism of [(η5‑C5H5)Fe(dppf)(CO)]+ (dppf = 1,1′-Bis(diphenylphosphino)ferrocene)
Published in Organometallics (22-03-2021)“…The complex [CpFe(dppf)(CO)][B(ArF)4] [1][B(ArF)4] (Cp = cyclopentadienyl, dppf = 1,1′-bis(diphenylphosphino)ferrocene, and [B(ArF)4]− =…”
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Artificial metalloenzymes for olefin metathesis based on the biotin-(strept)avidin technology
Published in Chemical communications (Cambridge, England) (28-11-2011)“…Incorporation of a biotinylated Hoveyda-Grubbs catalyst within (strept)avidin affords artificial metalloenzymes for the ring-closing metathesis of N-tosyl…”
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(Benz-)imidazolin-2-ylidene-benzimidazolatonickel(II) Chelates: Syntheses, Structures, and Tuning of Noninnocent Chelate Ligand Behavior
Published in Inorganic chemistry (02-12-2019)“…The deprotonation of 1-(1H-benzimidazol-2-yl)-3-methylbenzimidazolium hexafluorophosphate (2 MeH2[PF6]) and 1-(1H-benzimidazol-2-yl)-3-isopropylbenzimidazolium…”
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How Solid Surfaces Control Stability and Interactions of Supported Cationic Cu I (dppf) Complexes─A Solid-State NMR Study
Published in Inorganic chemistry (15-05-2023)“…Organometallic complexes are frequently deposited on solid surfaces, but little is known about how the resulting complex-solid interactions alter their…”
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(Spectro)Electrochemistry of 3‐(Pyrid‐2‐yl)‐s‐Tetrazine‐ and 1,2‐ (Dihydro)pyridazine Tricarbonylrhenium(I)chloride
Published in European journal of inorganic chemistry (08-04-2022)“…The electrochemistry and spectroelectrochemistry (SEC) of the three [ReCl(CO)3(N N)], N N=3‐(pyrid‐2‐yl)‐1,2,4,5‐tetrazine [1],…”
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