Search Results - "Marek, Kinga"
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1
2,6-Di-tert-butylpyridine Sorption Approach to Quantify the External Acidity in Hierarchical Zeolites
Published in Journal of physical chemistry. C (12-06-2014)“…This work was aimed to evidence that substituted pyridine, 2,6-di-tert-butylpyridine, is a suitable probe for the quantitative investigation of the external…”
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2
Oxygen Splitting and Methane Oxidation over Fe-Mordenite: Insight by the Operando 2D COS UV–Vis–NIR–IR Approach
Published in Journal of physical chemistry. C (07-03-2024)“…Activation of molecular oxygen and subsequent oxidation of methane over Fe sites in mordenite zeolites with different content of framework Al atoms were…”
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3
Analysis of NH3‐TPD Profiles for CuSSZ‐13 SCR Catalyst of Controlled Al Distribution – Complexity Resolved by First Principles Thermodynamics of NH3 Desorption, IR and EPR Insight into Cu Speciation
Published in Chemistry : a European journal (06-12-2021)“…NH3 temperature‐programmed desorption (NH3‐TPD) is frequently used for probing the nature of the active sites in CuSSZ‐13 zeolite for selective catalytic…”
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4
Effect of zeolite topology on NH3-SCR activity and stability of Cu-exchanged zeolites
Published in Applied catalysis. B, Environmental (05-05-2021)“…[Display omitted] •Topology effects the redox-cycle of Cu2+↔Cu+ and thus the activity in NH3-SCR.•First spectroscopic evidence for the generation of…”
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5
High-Silica Layer-like Zeolites Y from Seeding-Free Synthesis and Their Catalytic Performance in Low-Density Polyethylene Cracking
Published in ACS applied materials & interfaces (09-02-2022)“…Layer-like FAU-type zeolite Y was synthesized by an organosilane-assisted low-temperature hydrothermal method and its catalytic activity was verified in the…”
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6
Molecular Understanding of the Catalytic Consequence of Ketene Intermediates under Confinement
Published in Journal of the American Chemical Society (22-09-2021)“…Neutral ketene is a crucial intermediate during zeolite carbonylation reactions. In this work, the roles of ketene and its derivates (viz., acylium ion and…”
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7
Accessibility of Acid Sites in Hierarchical Zeolites: Quantitative IR Studies of Pivalonitrile Adsorption
Published in Journal of physical chemistry. C (09-05-2013)“…Accessibility studies of acid sites in zeolites involving quantitative IR measurements with hindered pivalonitrile as probe molecule were performed. The…”
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8
Constrained and Open Mesoporosity in Polypropylene Cracking: Insight From Spectroscopic Investigations of Acidity, Diffusion, and Activity
Published in Langmuir (02-04-2024)“…The outcome of the demetalation process of zeolites depends on applied treatment conditions and can lead to the formation of either open or constrained…”
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9
Towards a greater olefin share in polypropylene cracking – Amorphous mesoporous aluminosilicate competes with zeolites
Published in Applied catalysis. B, Environmental (15-11-2021)“…[Display omitted] •The highest olefinicity products found for the HAlMCM-48.•The HAlMCM-48 as a successful additives of the FCC catalyst.•Low coke formation in…”
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10
Effect of Missing-Linker Defects and Ion Exchange on Stability and Proton Conduction of a Sulfonated Layered Zr-MOF
Published in ACS applied materials & interfaces (14-06-2023)“…Intentionally introduced defects into solid materials create opportunities to control and tune their diverse physicochemical properties. Despite the growing…”
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11
Operando Study Reveals the Superior Cracking Activity and Stability of Hierarchical ZSM‐5 Catalyst for the Cracking of Low‐Density Polyethylene
Published in ChemSusChem (07-02-2019)“…A new theoretical and practical framework has been developed through operando study of the zeolite catalytic cracking of low‐density polyethylene (as a model…”
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12
Hydrothermal stability and catalytic performance of desilicated highly siliceous zeolites ZSM-5
Published in Journal of catalysis (01-07-2016)“…[Display omitted] •Desilicated high silica zeolites presented good hydrothermal stability.•Preservation of mesoporosity after the steaming treatment.•Mesopores…”
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13
Pd-modified beta zeolite for modulated hydro-cracking of low-density polyethylene into a paraffinic-rich hydrocarbon fuel
Published in Applied catalysis. B, Environmental (15-11-2020)“…[Display omitted] •Pd-modified beta zeolite of the similar texture, structure and acidity as H-zeolite.•Saturated hydrocarbons produced using only…”
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14
Hierarchical zeolites TNU-9 and IM-5 as the catalysts for cracking processes
Published in Applied catalysis. B, Environmental (05-12-2023)“…The 10-ring zeolites TNU-9 and IM-5 were obtained by a desilication and evaluated in series of acid-catalysed cracking reactions. n-Decane and…”
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15
Charge-separation driven mechanism via acylium ion intermediate migration during catalytic carbonylation in mordenite zeolite
Published in Nature communications (19-11-2022)“…By employing ab initio molecular dynamic simulations, solid-state NMR spectroscopy, and two-dimensional correlation analysis of rapid scan Fourier transform…”
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16
IR studies of Fe modified ZSM-5 zeolites of diverse mesopore topologies in the terms of their catalytic performance in NH3-SCR and NH3-SCO processes
Published in Applied catalysis. B, Environmental (01-12-2015)“…[Display omitted] •Conventional microporous zeolite vs. hierarchical analogs.•Superior activity of mesostructured Fe-ZSM-5 in the NH3-SCR and NH3-SCO…”
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17
Influence of Framework n(Si)/n(Al) Ratio on the Nature of Cu Species in Cu‐ZSM‐5 for NH3‐SCR‐DeNOx
Published in ChemCatChem (20-09-2022)“…Nanosized Cu‐containing ZSM‐5 catalysts with different n(Si)/n(Al) ratio of 18.9–50.5 were prepared by ion‐exchange. The physico‐chemical characterization…”
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18
Mechanistic stages of the SCR reaction – Insights into the trade-off between NO reduction and NH3 oxidation over CuSSZ-13 catalysts via isotopic 15NH3 and 18O2 TPSR and steady state studies supported by IR 2D COS and DFT modeling
Published in Applied catalysis. B, Environmental (15-05-2023)“…Isotopic labeling investigations into SCR reaction were performed over CuSSZ-13 zeolites, obtained by one-pot synthesis or impregnation, and characterized by…”
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19
Adjustment of the ZSM-5 zeolite support towards the efficient hydrogen production by ethanol steam reforming on cobalt catalysts
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-07-2023)“…[Display omitted] •The effect of Al content on the activity of Co|zeolite catalyst in the ethanol steam reforming process.•The key role of the zeolite…”
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20
Vanadium-doped dendritic mesoporous silica for selective propane oxidation to valuable intermediates
Published in Catalysis today (01-01-2025)“…The catalytic performance of a series of dendritic mesoporous silica nanoparticles (DMSNs) containing vanadium, featuring a unique central-radial pore…”
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