Search Results - "Marek, Ilan"

Asymmetric Preparation of Polysubstituted Cyclopropanes Based on Direct Functionalization of Achiral Three-Membered Carbocycles by Dian, Longyang, Marek, Ilan

“…In addition to the appealing synthetic transformations that cyclopropanes present, they are also part of larger molecular structures that possess a wide range…”
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Synthesis of Enantioenriched Vicinal Tertiary and Quaternary Carbon Stereogenic Centers within an Acyclic Chain by Pierrot, David, Marek, Ilan

“…Overcoming the inherent difficulty to prepare quaternary carbon stereogenic centers, the diastereo‐ and enantioselective preparation of acyclic carbon…”
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Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis by Massad, Itai, Marek, Ilan

“…The positional isomerization of alkenes is a well-known process mediated by various transition metal complexes. Nevertheless, systems which isomerize alkenes…”
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Nucleophilic Substitution at Quaternary Carbon Stereocenters by Lanke, Veeranjaneyulu, Marek, Ilan

“…Cyclopropyl carbinol derivatives undergo a regio- and stereoselective nucleophilic substitution at the quaternary carbon center, with pure inversion of…”
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Rhodium‐Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three‐Membered Carbocycles by Dian, Longyang, Marek, Ilan

“…A variety of highly diastereo‐ and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium‐catalyzed arylation reaction of…”
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Stereospecific nucleophilic substitution at tertiary and quaternary stereocentres by Lanke, Veeranjaneyulu, Marek, Ilan

“…Nucleophilic substitution reactions have always been considered as one of the most powerful reactions for the creation of carbon-carbon or carbon-heteroatom…”
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Selectivity in Metal-Catalyzed CarbonCarbon Bond Cleavage of Alkylidenecyclopropanes by Masarwa, Ahmad, Marek, Ilan

“…When more complex system leads to simpler reactivity profile; the ring‐opening of strained three‐membered rings such as methylene‐ and alkylidenecyclopropanes…”
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A unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-opening by Singh, Sukhdev, Bruffaerts, Jeffrey, Vasseur, Alexandre, Marek, Ilan

“…Combining functionalization at a distant position from a reactive site with the creation of several consecutive stereogenic centres, including the formation of…”
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Alkene Isomerization Revitalizes the Coates–Claisen Rearrangement by Massad, Itai, Marek, Ilan

“…The [3,3]‐sigmatropic rearrangement of allylic vinyl acetals, first investigated by Coates nearly four decades ago, is set apart from other variants of the…”
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Merging C–H and C–C bond cleavage in organic synthesis by Nairoukh, Zackaria, Cormier, Morgan, Marek, Ilan

“…Metal-catalysed functionalization of a carbon–hydrogen bond can occur selectively even in the presence of ostensibly more reactive functional groups. Such…”
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Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes through C-H Cleavage by Schinkel, Marvin, Marek, Ilan, Ackermann, Lutz

“…Catalytic: Ruthenium(II)biscarboxylate complexes enabled highly effective hydroarylations of unactivated alkenes through CH bond activation. This method has a…”
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Walking Metals for Remote Functionalization by Sommer, Heiko, Juliá-Hernández, Francisco, Martin, Ruben, Marek, Ilan

“…The distant and selective activation of unreactive C–H and C–C bonds remains one of the biggest challenges in organic chemistry. In recent years, the…”
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Stereoselective Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers by Iridium‐Catalyzed Alkene Isomerization by Massad, Itai, Sommer, Heiko, Marek, Ilan

“…An in situ generated cationic Ir‐catalyst isomerizes simple allylic silyl ethers into valuable, fully substituted aldehyde‐derived silyl enol ethers…”
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Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en Route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanes by Müller, Daniel S, Marek, Ilan

“…The enantioselective synthesis of cyclopropylzinc reagents has been achieved via a copper-catalyzed carbozincation of 3,3-disubstituted cyclopropenes with…”
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Merging allylic carbon–hydrogen and selective carbon–carbon bond activation by Masarwa, Ahmad, Didier, Dorian, Zabrodski, Tamar, Schinkel, Marvin, Ackermann, Lutz, Marek, Ilan

“…A method of selectively activating both allylic carbon–hydrogen bonds and carbon–carbon bonds can furnish sophisticated molecular scaffolds with all-carbon…”
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A Shift in Retrosynthetic Paradigm by Marek, Ilan

“…The current state‐of‐the‐art synthesis for the formation of enantiomerically enriched all‐carbon quaternary stereocenters in acyclic system relies on the…”
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Asymmetric Copper‐Catalyzed Carbomagnesiation of Cyclopropenes by Dian, Longyang, Müller, Daniel S., Marek, Ilan

“…The highly diastereo‐ and enantioselective formation of polysubstituted cyclopropanes was easily achieved through the asymmetric copper‐catalyzed…”
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Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates by Starkov, Pavel, Moore, Jared T, Duquette, Douglas C, Stoltz, Brian M, Marek, Ilan

“…We report a divergent and modular protocol for the preparation of acyclic molecular frameworks containing newly created quaternary carbon stereocenters…”
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Remote functionalization through alkene isomerization by Vasseur, Alexandre, Bruffaerts, Jeffrey, Marek, Ilan

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Highly E‑Selective, Stereoconvergent Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling of Alkenyl Ethers by Ho, Guo-Ming, Sommer, Heiko, Marek, Ilan

“…An improved method for the nickel-catalyzed Suzuki–Miyaura cross-coupling of alkenyl ethers is reported. This stereoconvergent protocol allows for the…”
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