Search Results - "Manor, Brian C."

Cerium Photosensitizers: Structure–Function Relationships and Applications in Photocatalytic Aryl Coupling Reactions by Yin, Haolin, Carroll, Patrick J, Manor, Brian C, Anna, Jessica M, Schelter, Eric J

“…Two complete mixed-ligand series of luminescent CeIII complexes with the general formulas [(Me3Si)2NC­(N i Pr)2] x CeIII[N­(SiMe3)2]3–x (x = 0, 1-N; x = 1,…”
Get full text

Hydrogen Activation by Biomimetic [NiFe]-Hydrogenase Model Containing Protected Cyanide Cofactors by Manor, Brian C, Rauchfuss, Thomas B

“…Described are experiments demonstrating incorporation of cyanide cofactors and hydride substrate into [NiFe]-hydrogenase (H2ase) active site models. Complexes…”
Get full text

The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides by Yin, Haolin, Jin, Yi, Hertzog, Jerald E, Mullane, Kimberly C, Carroll, Patrick J, Manor, Brian C, Anna, Jessica M, Schelter, Eric J

“…The hexachlorocerate­(III) anion, [CeIIICl6]3–, was found to be a potent photoreductant in acetonitrile solution with an estimated excited-state reduction…”
Get full text

Understanding and Controlling the Emission Brightness and Color of Molecular Cerium Luminophores by Qiao, Yusen, Sergentu, Dumitru-Claudiu, Yin, Haolin, Zabula, Alexander V, Cheisson, Thibault, McSkimming, Alex, Manor, Brian C, Carroll, Patrick J, Anna, Jessica M, Autschbach, Jochen, Schelter, Eric J

“…Molecular cerium complexes are a new class of tunable and energy-efficient visible- and UV-luminophores. Understanding and controlling the emission brightness…”
Get full text

Palladium-Catalyzed Enantioselective Arylation of Aryl Sulfenate Anions: A Combined Experimental and Computational Study by Jia, Tiezheng, Zhang, Mengnan, McCollom, Samuel P, Bellomo, Ana, Montel, Sonia, Mao, Jianyou, Dreher, Spencer D, Welch, Christopher J, Regalado, Erik L, Williamson, R. Thomas, Manor, Brian C, Tomson, Neil C, Walsh, Patrick J

“…A novel approach to produce chiral diaryl sulfoxides from aryl benzyl sulfoxides and aryl bromides via an enantioselective arylation of aryl sulfenate anions…”
Get full text

A Planar Ti2P2 Core Assembled by Reductive Decarbonylation of −O−C≡P and P−P Radical Coupling by Grant, Lauren N., Pinter, Balazs, Manor, Brian C., Suter, Riccardo, Grützmacher, Hansjörg, Mindiola, Daniel J.

“…The complex [(nacnac)Ti(OAr)]2(μ2:η2,η2‐P2) (1) is formed via reductive decarbonylation of the phosphaethynolate ion −[OCP], which serves as a P atom source…”
Get full text

Ring‐Size‐Modulated Reactivity of Putative Dicobalt‐Bridging Nitrides: C−H Activation versus Phosphinimide Formation by Cui, Peng, Wang, Qiuran, McCollom, Samuel P., Manor, Brian C., Carroll, Patrick J., Tomson, Neil C.

“…Dicobalt complexes supported by flexible macrocyclic ligands were used to target the generation of the bridging nitrido species [(nPDI2)Co2(μ‐N)(PMe3)2]3+…”
Get full text

A Scandium‐Stabilized Diisophosphaethynolate Ligand: [OCPPCO]4 by Grant, Lauren N., Pinter, Balazs, Manor, Brian C., Grützmacher, Hansjörg, Mindiola, Daniel J.

“…The first example of the OCPPCO ligand, diisophosphaethynolate, is reported via reductive coupling of a Sc−OCP precursor. Upon reduction with KC8, isolation of…”
Get full text

Synthesis of an elusive, stable 2-azaallyl radical guided by electrochemical and reactivity studies of 2-azaallyl anions by Panetti, Grace B, Carroll, Patrick J, Gau, Michael R, Manor, Brian C, Schelter, Eric J, Walsh, Patrick J

“…The super electron donor (SED) ability of 2-azaallyl anions has recently been discovered and applied to diverse reactivity, including transition metal-free…”
Get full text

N−H Bond Formation at a Diiron Bridging Nitride by Zhang, Shaoguang, Cui, Peng, Liu, Tianchang, Wang, Qiuran, Longo, Thomas J., Thierer, Laura M., Manor, Brian C., Gau, Michael R., Carroll, Patrick J., Papaefthymiou, Georgia C., Tomson, Neil C.

“…Despite their connection to ammonia synthesis, little is known about the ability of iron‐bound, bridging nitrides to form N−H bonds. Herein we report a linear…”
Get full text

Metallophilic and Inter‐Ligand Interactions in Diargentous Compounds Bound by a Geometrically Flexible Macrocycle by Wang, Qiuran, Gau, Michael R., Manor, Brian C., Carroll, Patrick J., Tomson, Neil C.

“…Abstract A series of mono‐ and di‐nuclear Ag I complexes supported by a flexible macrocyclic ligand are reported. The geometric flexibility of the ligand was…”
Get full text

Phosphinoalkylidene and -alkylidyne Complexes of Titanium: Intermolecular C–H Bond Activation and Dehydrogenation Reactions by Kamitani, Masahiro, Pinter, Balazs, Searles, Keith, Crestani, Marco G, Hickey, Anne, Manor, Brian C, Carroll, Patrick J, Mindiola, Daniel J

“…The ethylene complex (PNP)­Ti­(η2-H2CCH2)­(CH2 t Bu) or (PNP)­TiCH t Bu­(CH2 t Bu) (PNP– = N­[2-P­(CHMe2)2-4-methylphenyl]2) reacts with H2CPPh3 to form the…”
Get full text

Reactivity Studies of a Zirconium Methylidene Complex: Group Transfer and Methylenation Reactions by Kurogi, Takashi, Kamitani, Masahiro, Manor, Brian C, Carroll, Patrick J, Mindiola, Daniel J

“…The zirconium methylidene complex (PNP)­ZrCH2(OAr) (1; PNP = N­[2-PiPr2-4-methylphenyl]2 –, Ar = 2,6-iPr2C6H3), prepared from photolysis of…”
Get full text

Phosphoryl-Ligand Adducts of Rare Earth-TriNOx Complexes: Systematic Studies and Implications for Separations Chemistry by Cheisson, Thibault, Cole, Bren E, Manor, Brian C, Carroll, Patrick J, Schelter, Eric J

“…Phosphoryl ligands of the general formula OPR3 (R = Me, OMe, Et, n Bu, Ph, i Pr, NMe2) were coordinated to [Nd­(TriNOx)] (TriNOx3– = ([(2- t…”
Get full text

Observation of the FeCN and FeCO Vibrations in the Active Site of [NiFe] Hydrogenase by Nuclear Resonance Vibrational Spectroscopy by Kamali, Saeed, Wang, Hongxin, Mitra, Devrani, Ogata, Hideaki, Lubitz, Wolfgang, Manor, Brian C., Rauchfuss, Thomas B., Byrne, Deborah, Bonnefoy, Violaine, Jenney Jr, Francis E., Adams, Michael W. W., Yoda, Yoshitaka, Alp, Ercan, Zhao, Jiyong, Cramer, Stephen P.

“…Nuclear inelastic scattering of 57Fe labeled [NiFe] hydrogenase is shown to give information on different states of the enzyme. It was thus possible to detect…”
Get full text

Ni(NIXANTPHOS)-Catalyzed Mono-Arylation of Toluenes with Aryl Chlorides and Bromides by Jiang, Hui, Sha, Sheng-Chun, Jeong, Soo A, Manor, Brian C, Walsh, Patrick J

“…A nickel-catalyzed cross-coupling of toluene derivatives with both aryl bromides and chlorides using a NIXANTPHOS-ligated nickel­(II) complex has been…”
Get full text

A Scandium‐Stabilized Diisophosphaethynolate Ligand: [OCPPCO]4 by Grant, Lauren N., Pinter, Balazs, Manor, Brian C., Grützmacher, Hansjörg, Mindiola, Daniel J.

“…The first example of the OCPPCO ligand, diisophosphaethynolate, is reported via reductive coupling of a Sc−OCP precursor. Upon reduction with KC8, isolation of…”
Get full text

Synthesis and Characterization of (pyNO−)2GaCl: A Redox-Active Gallium Complex by Kirsh, Jacob, Woodside, Audra, Manor, Brian, Carroll, Patrick, Rablen, Paul, Graves, Christopher

“…We report the synthesis of a gallium complex incorporating redox-active pyridyl nitroxide ligands. The (pyNO−)2GaCl complex was prepared in 85% yield via a…”
Get full text

Cerium(IV) Imido Complexes: Structural, Computational, and Reactivity Studies by Solola, Lukman A, Zabula, Alexander V, Dorfner, Walter L, Manor, Brian C, Carroll, Patrick J, Schelter, Eric J

“…A series of alkali metal capped cerium­(IV) imido complexes, [M­(solv) x ]­[CeN­(3,5-(CF3)2C6H3)­(TriNOx)] (M = Li, K, Rb, Cs; solv = TMEDA, THF, Et2O, or…”
Get full text

Electro‐kinetic Separation of Rare Earth Elements Using a Redox‐Active Ligand by Fang, Huayi, Cole, Bren E., Qiao, Yusen, Bogart, Justin A., Cheisson, Thibault, Manor, Brian C., Carroll, Patrick J., Schelter, Eric J.

“…Purification of rare earth elements is challenging due to their chemical similarities. All of the deployed separation methods rely on thermodynamic properties,…”
Get full text