Search Results - "Manmode, Sujit"
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Glycosyl Dioxalenium Ions as Reactive Intermediates of Automated Electrochemical Assembly
Published in European journal of organic chemistry (19-05-2022)“…Stability of electrochemically generated glycosyl dioxalenium ions, which are reactive intermediates of electrochemical glycosylation, is influenced by…”
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Electrochemical Methods as Enabling Tools for Glycosylation
Published in Asian journal of organic chemistry (01-09-2018)“…Electrochemical methods have been widely used for organic synthesis including glycosylation. Electrochemical oxidation via single electron transfer (SET) is a…”
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Rational optimization of the mannoside building block for automated electrochemical assembly of the core trisaccharide of GPI anchor oligosaccharides
Published in Carbohydrate research (10-10-2017)“…We have developed a carbohydrate building block of mannosides based on DFT calculations, electrochemical analysis, and automated solution-phase synthesis. The…”
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[Au]/[Ag]-catalysed expedient synthesis of branched heneicosafuranosyl arabinogalactan motif of Mycobacterium tuberculosis cell wall
Published in Nature communications (25-01-2017)“…Emergence of multidrug-resistant and extreme-drug-resistant strains of Mycobacterium tuberculosis (MTb) can cause serious socioeconomic burdens…”
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Total synthesis of TMG-chitotriomycin based on an automated electrochemical assembly of a disaccharide building block
Published in Beilstein journal of organic chemistry (16-05-2017)“…The total synthesis of TMG-chitotriomycin using an automated electrochemical synthesizer for the assembly of carbohydrate building blocks is demonstrated. We…”
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Electrochemical Glycosylation as an Enabling Tool for the Stereoselective Synthesis of Cyclic Oligosaccharides
Published in ChemistryOpen (Weinheim) (01-07-2019)“…Electrochemical glycosylation of a linear oligosaccharide with a protecting‐group‐free primary hydroxyl group afforded cyclic oligo‐saccharides, up to…”
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A Versatile Synthesis of Pentacosafuranoside Subunit Reminiscent of Mycobacterial Arabinogalactan Employing One Strategic Glycosidation Protocol
Published in Chemistry : a European journal (24-01-2018)“…Oligosaccharides are involved in a myriad of biological phenomena. Many glycobiological experiments can be undertaken if homogenous and well‐defined…”
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Propargyl 1,2-Orthoesters for a Catalytic and Stereoselective Synthesis of Pyrimidine Nucleosides
Published in Journal of organic chemistry (06-02-2015)“…Pyrimidine nucleosides are synthesized by using propargyl 1,2-orthoesters and Au(III) salt as a catalyst. Strategically positioned 1,2-orthoesters are found to…”
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Expedient Synthesis of a Linear Nonadecaarabinofuranoside of the Mycobacterium tuberculosis Cellular Envelope
Published in European journal of organic chemistry (01-09-2017)“…The synthesis of oligosaccharides is demanding as it requires multiple steps and long reaction sequences. The choice of glycosylation method and protecting…”
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Thioarylation of 6‐Amino‐2,3,6‐trideoxy‐d‐manno‐oct‐2‐ulosonic Acid (IminoKdo): Access to 3,6‐Disubstituted Picolinates and Mechanistic Insights
Published in Chemistry : a European journal (26-02-2024)“…In this work, we present a metal‐free coupling protocol for the regio‐ and stereoselective C3‐thioarylation of 6‐amino‐2,3,6‐trideoxy‐d‐manno‐oct‐2‐ulosonic…”
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Electrochemical synthesis of the protected cyclic (1,3;1,6)-β-glucan dodecasaccharide
Published in Faraday discussions (31-10-2023)“…Automated electrochemical assembly is an electrochemical method to synthesise middle-sized molecules, including linear oligosaccharides, and some linear…”
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Automated Electrochemical Assembly of the β‐(1,3)‐β‐(1,6)‐Glucan Hexasaccharide Using Thioglucoside Building Blocks
Published in Asian journal of organic chemistry (01-09-2018)“…This study deals with the design, synthesis, and rational optimization of carbohydrate building blocks of glucosides for automated electrochemical assembly of…”
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Propargyl 1,2-orthoesters for stereoselective synthesis of thioglycosides and 1-thiotrehaloses
Published in Carbohydrate research (19-11-2015)“…•Various thiosaccharides and 1-thiotrehaloses were synthesized.•Salient features of gold-catalyzed glycosidation were applied.•Alkynyl 1,2-orthoesters as…”
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