Trialkylalanes in palladium-catalyzed chemo- and regioselective alkylations

Trialkylalanes in palladium-catalyzed chemo- and regioselective alkylations

Carbosubstitution in halogenoazines with alkyl groups is readily effected under the influence of Pd-catalysis with alanes as the donor of the alkyl group. Regioselective Pd-catalyzed carbosubstitution in azines with trialkylalanes as alkylating agent.

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Bibliographic Details
Published in:Tetrahedron letters Vol. 37; no. 8; pp. 1309 - 1312
Main Authors: Mangalagiu, Inoel, Benneche, Tore, Undheim, Kjell
Format: Journal Article
Language:English
Published: Elsevier Ltd 19-02-1996
Online Access:Get full text
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Description
Summary:Carbosubstitution in halogenoazines with alkyl groups is readily effected under the influence of Pd-catalysis with alanes as the donor of the alkyl group. Regioselective Pd-catalyzed carbosubstitution in azines with trialkylalanes as alkylating agent.
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(95)02381-X