Search Results - "Malwitz, Mark A"
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Role of Anions and Mixtures of Anions on the Thermochromism, Vapochromism, and Polymorph Formation of Luminescent Crystals of a Single Cation, [(C6H11NC)2Au]
Published in Journal of the American Chemical Society (25-03-2020)“…Noncoordinating anions, which generally play a subordinate role in coordination chemistry, alter the structure, the luminescence, as well as the thermochromic…”
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2
Crystallization and Interconversions of Vapor-Sensitive, Luminescent Polymorphs of [(C6H11NC)2AuI](AsF6) and [(C6H11NC)2AuI](PF6)
Published in Journal of the American Chemical Society (04-07-2012)“…The remarkable, vapor-induced transformation of the yellow polymorphs of [(C6H11NC)2AuI](AsF6) and [(C6H11NC)2AuI](PF6) into the colorless forms are reported…”
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3
Pyridine Substituted N-Heterocyclic Carbene Ligands as Supports for Au(I)−Ag(I) Interactions: Formation of a Chiral Coordination Polymer
Published in Inorganic chemistry (06-09-2004)“…Reaction of 1,3-bis(2-pyridinylmethyl)-1H-imidazolium tetrafluoroborate, [H(pyCH2)2im]BF4, with silver oxide in dichloromethane readily yields…”
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4
Short Metal−Metal Separations in a Highly Luminescent Trimetallic Ag(I) Complex Stabilized by Bridging NHC Ligands
Published in Inorganic chemistry (08-09-2003)“…Reaction of 1,3-bis(2-pyridinylmethyl)-1H-imidazolium salt, [H(pyCH2)2im]X (X = BF4 - or Cl-), with silver oxide in acetonitrile readily yields yellow-brown…”
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5
Mixed-Metal Metallocryptands. Short Metal−Metal Separations Strengthened by a Dipolar Interaction
Published in Journal of the American Chemical Society (02-06-2004)“…The deep-red, air-stable mixed-metal metallocryptands, [AuPdTl(P2phen)3](PF6)2, 1·(PF6)2, and [AuPtTl(P2phen)3](PF6)2, 2·(PF6)2, are easily prepared in good…”
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Pd(0) and Pt(0) Metallocryptands Encapsulating a Spinning Mercurous Dimer
Published in Inorganic chemistry (16-12-2002)“…The deep-red, air-stable complexes [Pt2Hg2(P2phen)3](PF6)2, 1, or [Pd2Hg2(P2phen)3](PF6)2, 2, (P2phen is 2,9-bis(diphenylphosphino)-1,10-phenanthroline) are…”
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Three- and Four-Coordinate Gold(I) Complexes of 3,6-Bis(diphenylphosphino)pyridazine: Monomers, Polymers, and a Metallocryptand Cage
Published in Inorganic chemistry (24-03-2003)“…The slightly yellow polymeric complexes {Au2Cl2(P2pz)3} n , 1·6CHCl 3 , (P2pz is 3,6-bis(diphenylphosphino)pyridazine) and {[Au2(P2pz)3](PF6)2} n , 2, are…”
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Copper Complexes with N-Alkylated NS2-Macrocyclic Ligands: Synthesis, Characterization, and Capabilities as Aziridination Precatalysts
Published in Organometallics (25-10-2004)“…The syntheses of two new ligands containing macrocyclic [10]-aneNS2 (1-aza-4,8-dithiacyclodecane) units are reported, including the N-methylated analogue (L…”
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9
Metallocryptands: Host Complexes for Probing Closed-Shell Metal-Metal Interactions
Published in Comments on modern chemistry. Part A, Comments on inorganic chemistry (01-01-2003)“…Metallocryptands are inorganic host complexes that contain a central metal ion, around which are arranged three multi-denate ligands capped by a trigonally…”
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10
A Reversible Polymorphic Phase Change Which Affects the Luminescence and Aurophilic Interactions in the Gold(I) Cluster Complex, [μ3-S(AuCNC7H13)3](SbF6)
Published in Journal of the American Chemical Society (10-08-2005)“…Crystallographic examination of [μ3-S(AuCNC7H13)3](SbF6) shows that it undergoes a reversible phase change from orthorhombic to monoclinic upon cooling. At 190…”
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Copper Complexes with N-Alkylated NS 2 -Macrocyclic Ligands: Synthesis, Characterization, and Capabilities as Aziridination Precatalysts
Published in Organometallics (25-10-2004)Get full text
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