Search Results - "Mallmann, Aimery de"
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Particle size effect in the low temperature reforming of methane by carbon dioxide on silica-supported Ni nanoparticles
Published in Journal of catalysis (01-01-2013)“…Particle size does not affect the intrinsic activity of silica-supported nickel nanoparticles in dry reforming at 500°C. [Display omitted] ► Different silica…”
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Nickel–Silicide Colloid Prepared under Mild Conditions as a Versatile Ni Precursor for More Efficient CO2 Reforming of CH4 Catalysts
Published in Journal of the American Chemical Society (26-12-2012)“…Preparing highly active and stable non-noble-metal-based dry reforming catalysts remains a challenge today. In this context, supported nickel nanoparticles…”
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NH3-Selective Catalytic Reduction of NOx to N2 over Ceria Supported WOx Based Catalysts: Influence of Tungsten Content
Published in Catalysts (01-08-2021)“…A series of HPW/CeO2 catalysts generated from 12-tungstophosphoric acid, H3PW12O40 (HPW), supported on ceria and presenting different tungsten loadings (2,…”
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Catalytic Reduction of NOx With NH3 Over CeO2 and SiO2 Supported Tungstophosphoric Acid: Promoting Effects of Ceria Support and Cobalt Proton Substitute
Published in Catalysis letters (01-07-2022)“…Grafted tungstophosphoric acid (H 3 PW 12 O 40 / HPW) is applied as a catalyst in the selective catalytic reduction of NO x with NH 3 (NH 3 -SCR). The HPW/CeO…”
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Selective Catalytic Reduction of CO2 to CO by a Single-Site Heterobimetallic Iron–Potassium Complex Supported on Alumina
Published in ACS catalysis (16-02-2024)“…CO2 has attracted much attention as a C1 feedstock for synthetic fuels via its selective catalytic hydrogenation to liquid hydrocarbons. One strategy is the…”
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Supported PdZn nanoparticles for selective CO2 conversion, through the grafting of a heterobimetallic complex on CeZrOx
Published in Applied catalysis. A, General (05-04-2022)“…Controlling the stoichiometry of supported bimetallic nanoparticles is essential in many catalytic reactions, notably selective CO2 hydrogenation. Thus, a new…”
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Oxide-Supported Titanium Catalysts: Structure–Activity Relationship in Heterogeneous Catalysis, with the Choice of Support as a Key Step
Published in Organometallics (28-12-2020)“…The reactions of tetrakis(neopentyl)titanium, TiNp4 (1), with the surface of three solid oxides, silica, silica–alumina, and alumina, all partially…”
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Well-Defined Molybdenum Oxo Alkyl Complex Supported on Silica by Surface Organometallic Chemistry: A Highly Active Olefin Metathesis Precatalyst
Published in Journal of the American Chemical Society (15-02-2017)“…The well-defined silica-supported molybdenum oxo alkyl species (SiO−)MoO(CH2 t Bu)3 was selectively prepared by grafting of MoO(CH2 t Bu)3Cl onto partially…”
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Direct conversion of trans-2-butene into a mixture of monomers with different composition over vanadium supported catalysts
Published in Catalysis communications (01-09-2022)“…Terpolymerization of 1,3-butadiene, ethylene and propylene became an important process to access EPDM rubbers materials with unique properties. Having a…”
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Ethenolysis of Renewable Methyl Oleate Catalyzed by Readily Accessible Supported Group VI Oxo Catalysts
Published in Organometallics (13-04-2020)“…The conversion of methyl oleate by cross-metathesis with ethylene using readily accessible supported group VI oxo species was addressed. TON up to 500 and 5000…”
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Selective Grafting of Ga(i-Bu)3 on the Silanols of Mesoporous H‑ZSM‑5 by Surface Organometallic Chemistry
Published in Journal of physical chemistry. C (25-11-2015)“…The reaction of triisobutylgallium toward meso-H-ZSM-5250, prepared by desilication of H-ZSM-5, has been studied by IR, high field solid-state NMR, and EXAFS…”
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Solvent-Free Ring-Opening Metathesis Polymerization of Norbornene over Silica-Supported Tungsten-Oxo Perhydrocarbyl Catalysts
Published in Macromolecular rapid communications. (01-11-2016)“…Ring opening metathesis polymerization (ROMP) of bicyclo[2.2.1]hept‐2‐ene (norbornene) is carried out over silica‐supported catalysts based on tungsten…”
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Macromol. Rapid Commun. 22/2016
Published in Macromolecular rapid communications. (01-11-2016)“…Back Cover: Solventless ring opening polymerization of norbornene over a well‐defined supported tungsten oxo catalysts, the model of industrial catalyst, is…”
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Bifunctional Catalysts Based on Tungsten Hydrides Supported on Silicated Alumina for the Direct Production of 2,3‐Dimethylbutenes and Neohexene from Isobutene
Published in ChemCatChem (22-06-2017)“…Well‐defined bifunctional supported catalysts that comprise tungsten hydride moieties and Brønsted acid sites were prepared successfully. The catalysts showed…”
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Small Changes Have Consequences: Lessons from Tetrabenzyltitanium and -zirconium Surface Organometallic Chemistry
Published in Chemistry : a European journal (14-01-2013)“…Homoleptic benzyl derivatives of titanium and zirconium have been grafted onto silica that was dehydroxylated at 200 and 700 °C, thereby affording bi‐grafted…”
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Enforcing Z-selectivity in olefin metathesis through use of catalysts grafted on well-defined phenolic hybrid material
Published in Catalysis today (15-10-2014)“…[Display omitted] •New olefin metathesis catalysts were prepared by replacing surface silanol by phenol.•SOMC of a W-perhydrocarbyl on supported phenol.•SOMC…”
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Journal Article Conference Proceeding -
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Preparation and characterization of metallacalixarenes anchored to a mesoporous silica SBA-15 LP as potential catalysts
Published in Microporous and mesoporous materials (01-04-2014)“…•Calixarene [[4H]-(OH)3(H)] was used as a spacer between the SBA-15 surface and grafted complexes.•Al(iBu)3·(Et2O) was used as a linker between the SBA-15…”
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Detailed Structural Investigation of the Grafting of [Ta(CHtBu)(CH2 tBu)3] and [CpTaMe4] on Silica Partially Dehydroxylated at 700 °C and the Activity of the Grafted Complexes toward Alkane Metathesis
Published in Journal of the American Chemical Society (20-10-2004)“…The reaction of [Ta(CHtBu)(CH2 tBu)3] or [Cp*Ta(CH3)4] with a silica partially dehydroxylated at 700 °C gives the corresponding monosiloxy surface complexes…”
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Grafting Reaction of Platinum Organometallic Complexes on Silica-Supported or Unsupported Heteropolyacids
Published in Organometallics (11-04-2011)“…Silica-supported Keggin-type heteropolyacids react with platinum(II) complexes displaying a Pt-CH3 group, leading to the evolution of methane and the formation…”
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Reactivity of Tetraneopentylhafnium, Hf(CH2 tBu)4, with Silica Surfaces
Published in Organometallics (03-07-2006)“…The reaction of Hf(CH2 tBu)4 with a silica surface treated at 800 °C affords a unique surface organometallic species in only one surface environment,…”
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