Search Results - "Maitro, Guillaume"
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Enantioselective Synthesis of Aryl Sulfoxides via Palladium-Catalyzed Arylation of Sulfenate Anions
Published in Organic letters (20-12-2007)“…Arylation of various sulfenate anions generated from β-sulfinyl esters by retro-Michael reaction in the presence of palladium(0) and enantiopure ligands gave…”
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Journal Article -
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Preparation of Allyl Sulfoxides by Palladium-Catalyzed Allylic Alkylation of Sulfenate Anions
Published in Journal of organic chemistry (15-09-2006)“…Palladium-catalyzed allylic alkylation of sulfenate anions, generated from β-sulfinylesters by retro-Michael reaction, can take place under biphasic…”
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New Enantiopure Bis(thioether) and Bis(sulfoxide) Ligands from Benzothiophene
Published in European Journal of Organic Chemistry (01-02-2005)“…The C2‐symmetric compound 2,3,2,3‐tetrahydro‐2,2‐bi(benzo[b]thiophenyl) and three diastereomeric bis(oxide) derivatives can be synthesized in a few steps from…”
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Book Review Journal Article -
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Aryl Sulfoxides via Palladium-Catalyzed Arylation of Sulfenate Anions
Published in Organic letters (21-12-2006)“…Palladium-catalyzed arylation of sulfenate anions generated from β-sulfinyl esters can take place under biphasic conditions. This hitherto unknown reaction…”
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Journal Article -
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Design and Preclinical Development of TransCon PTH, an Investigational Sustained‐Release PTH Replacement Therapy for Hypoparathyroidism
Published in Journal of bone and mineral research (01-11-2019)“…ABSTRACT Hypoparathyroidism (HP) is a condition of parathyroid hormone (PTH) deficiency leading to abnormal calcium and phosphate metabolism. The mainstay of…”
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An escapade in the world of sulfenate anions: generation, reactivity and applications in domino processes
Published in Tetrahedron: asymmetry (17-05-2010)“…An escapade in the world of sulfenate anions is described and shows that these nucleophiles, despite being described as unstable species, are mild and…”
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Palladium-catalyzed intramolecular allylic alkylation of α-sulfinyl carbanions: a new asymmetric route to enantiopure γ-lactams
Published in Tetrahedron letters (17-03-2010)“…A simple and efficient protocol for the intramolecular palladium-catalyzed allylic alkylation of α-sulfinyl carbanions is reported. The use of unsaturated…”
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Oxidative Addition of Ligand-Chelated Palladium(0) to Aryl Halides: Comparison between 1,2-Bisthioethers and 1,2-Bisphosphines
Published in Organometallics (15-01-2007)“…The kinetics of the oxidative addition of bidentate ligand-chelated Pd0 complexes to phenyl iodide and bromide has been studied via cyclic voltammetry. The…”
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