Search Results - "Mahle, John"
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Integration of Metal–Organic Frameworks on Protective Layers for Destruction of Nerve Agents under Relevant Conditions
Published in Journal of the American Chemical Society (26-12-2019)“…Metal–organic frameworks (MOFs) are promising candidates for the catalytic hydrolysis of nerve agents and their simulants. Though highly efficient, bulk water…”
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Extraordinary NO2 Removal by the Metal-Organic Framework UiO-66-NH2
Published in Angewandte Chemie International Edition (17-05-2016)“…Here we discuss the removal of nitrogen dioxide, an important toxic industrial chemical and pollutant, from air using the MOF UiO‐66‐NH2. The amine group is…”
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Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption
Published in Chemical science (Cambridge) (01-01-2016)“…Metal-organic frameworks (MOFs) in their free powder form have exhibited superior capacities for many gases when compared to other materials, due to their…”
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Immobilized Regenerable Active Chlorine within a Zirconium-Based MOF Textile Composite to Eliminate Biological and Chemical Threats
Published in Journal of the American Chemical Society (13-10-2021)“…The most recent global health crisis caused by the SARS-CoV-2 outbreak and the alarming use of chemical warfare agents highlight the necessity to produce…”
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Highly Mesoporous Zr-Based MOF-Fabric Composites: A Benign Approach for Expeditious Degradation of Chemical Warfare Agents and Simulants
Published in Small (Weinheim an der Bergstrasse, Germany) (23-09-2024)“…Recent research has demonstrated the degradation of organophosphonates through hydrolysis using microporous UiO-66-NH -fabric composites. Yet, challenges…”
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Toxin‐Blocking Textiles: Rapid, Benign, Roll‐to‐Roll Production of Robust MOF‐Fabric Composites for Organophosphate Separation and Hydrolysis
Published in ChemSusChem (20-01-2023)“…Current approaches to create zirconium‐based metal–organic framework (MOF) fabric composites for catalysis, water purification, wound healing, gas sorption,…”
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Bent‐But‐Not‐Broken: Reactive Metal‐Organic Framework Composites from Elastomeric Phase‐Inverted Polymers
Published in Advanced functional materials (01-12-2020)“…A phase inversion process is used to fabricate composite beads from the metal–organic framework (MOF) UiO‐66‐NH2 and the elastomeric block copolymer…”
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Fabrication of Multifunctional Electronic Textiles Using Oxidative Restructuring of Copper into a Cu-Based Metal–Organic Framework
Published in Journal of the American Chemical Society (28-12-2022)“…This paper describes a novel synthetic approach for the conversion of zero-valent copper metal into a conductive two-dimensional layered metal–organic…”
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Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal–Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard
Published in Chemistry : a European journal (01-01-2017)“…A fullerene‐based photosensitizer is incorporated postsynthetically into a Zr6‐based MOF, NU‐1000, for enhanced singlet oxygen production. The structural…”
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Solid-Phase Detoxification of Chemical Warfare Agents using Zirconium-Based Metal Organic Frameworks and the Moisture Effects: Analyze via Digestion
Published in ACS applied materials & interfaces (12-06-2019)“…Zirconium-based metal organic frameworks (Zr-MOFs) are highly chemically and thermally stable and have been of particular interest as reactive sorbents for…”
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Graphene Oxide and Metal–Organic Framework-Based Breathable Barrier Membranes for Toxic Vapors
Published in ACS applied materials & interfaces (13-07-2022)“…Garments protective against chemical warfare agents (CWAs) or accidently released toxic chemicals must block the transport of toxic gases/vapors for a…”
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Laponite-Incorporated UiO-66-NH2‑Polyethylene Oxide Composite Membranes for Protection against Chemical Warfare Agent Simulants
Published in ACS applied materials & interfaces (03-03-2021)“…A strategy is developed to enhance the barrier protection of polyethylene oxide (PEO)-metal–organic framework (MOF) composite films against chemical warfare…”
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Effect of Adsorbed Water and Surface Hydroxyls on the Hydrolysis of VX, GD, and HD on Titania Materials: The Development of Self-Decontaminating Paints
Published in Industrial & engineering chemistry research (07-03-2012)“…Titania materials such as anatase (TiO2), nanotubular titania (NTT), and nanocrystalline titania (nTiO2) exhibit extremely short half-lives for VX, provided…”
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Development of a Multiparticulate Metal-Organic Framework/Textile Fiber Swatch
Published in ACS applied materials & interfaces (20-08-2024)“…The versatility of metal-organic frameworks (MOFs) has led to groundbreaking applications in a wide variety of fields, especially in the areas of energy,…”
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Factors and Limitations of Green, Rapid Metal–Organic Framework-Fabric Synthesis and Effects on Dual Chemical Warfare Agent Protection
Published in Industrial & engineering chemistry research (09-08-2023)“…Metal–organic framework (MOF) fabric composites integrate important MOF chemistry with flexible, strong fabric substrates and are useful in many applications…”
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Stretchable and Multi-Metal–Organic Framework Fabrics Via High-Yield Rapid Sorption-Vapor Synthesis and Their Application in Chemical Warfare Agent Hydrolysis
Published in ACS applied materials & interfaces (07-07-2021)“…Protocols to create metal–organic framework (MOF)/polymer composites for separation, chemical capture, and catalytic applications currently rely on relatively…”
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110th Anniversary: Molecular Structure Effects on Mass Transfer of C10 Hydrocarbons in BPL Activated Carbon
Published in Industrial & engineering chemistry research (21-08-2019)“…Adsorbent filters often use activated carbons to remove a wide range of toxic chemicals from air. It is of interest to know if filter performance for these…”
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Multifunctional Purification and Sensing of Toxic Hydride Gases by CuBTC Metal–Organic Framework
Published in Industrial & engineering chemistry research (15-04-2015)“…In this report, we evaluate the metal–organic framework CuBTC as a real-world adsorbent for protection against three toxic hydride gases: ammonia, arsine, and…”
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Laponite-Incorporated UiO-66-NH 2 -Polyethylene Oxide Composite Membranes for Protection against Chemical Warfare Agent Simulants
Published in ACS applied materials & interfaces (03-03-2021)“…A strategy is developed to enhance the barrier protection of polyethylene oxide (PEO)-metal-organic framework (MOF) composite films against chemical warfare…”
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