Search Results - "Mahabiersing, Taasje"
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Soluble Redox-Active Polymetallic Chains [{Ru0(CO)(L)(bpy)} m ] n (bpy = 2,2′-bipyridine, L = PrCN, Cl−; m = 0, −1): Electrosynthesis and Characterization
Published in Inorganic chemistry (07-09-2009)“…Electrochemical and spectroelectrochemical techniques were employed to study in detail the formation and so far unreported spectroscopic properties of soluble…”
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Electronic Properties of 4,4‘,5,5‘-Tetramethyl-2,2‘-biphosphinine (tmbp) in the Redox Series fac-[Mn(Br)(CO)3(tmbp)], [Mn(CO)3(tmbp)]2, and [Mn(CO)3(tmbp)]-: Crystallographic, Spectroelectrochemical, and DFT Computational Study
Published in Inorganic chemistry (14-07-2003)“…Stepwise electrochemical reduction of the complex fac-[Mn(Br)(CO)3(tmbp)] (tmbp = 4,4‘,5,5‘-tetramethyl-2,2‘-biphosphinine) produces the dimer [Mn(CO)3(tmbp)]2…”
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Redox-Active Polymers Based on Nonbridged Metal−Metal Bonds. Electrochemical Formation of [Os(bpy)(CO)(L)] n (bpy = 2,2‘-bipyridine; L = CO, MeCN) and of Their Reduced Forms: A Spectroelectrochemical Study
Published in Inorganic chemistry (01-11-2004)“…IR, UV−vis, and EPR spectroelectrochemistry at variable temperatures and in different solvents were applied to investigate in situ the formation of…”
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A Novel Organometallic Polymer of Osmium(0), [Os(2,2′-bipyridine)(CO)2]n: Its Electrosynthesis and Electrocatalytic Properties Towards CO2 Reduction
Published in European journal of inorganic chemistry (01-03-2001)“…A new kind of organometallic polymer of osmium(0) [Os0(bpy)(CO)2]n (bpy = 2,2′‐bipyridine) has been prepared as a thin film on an electrode surface by…”
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Redox-active polymers based on nonbridged metal-metal bonds. Electrochemical formation of [Os(bpy)(CO)(L)](n) (bpy = 2,2'-bipyridine; L = CO, MeCN) and of their reduced forms: a spectroelectrochemical study
Published in Inorganic chemistry (01-11-2004)“…IR, UV-vis, and EPR spectroelectrochemistry at variable temperatures and in different solvents were applied to investigate in situ the formation of…”
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Syntheses, X-ray Structures, Photochemistry, Redox Properties, and DFT Calculations of Interconvertible fac- and mer-[Mn(SPS)(CO)3] Isomers Containing a Flexible SPS-Based Pincer Ligand
Published in Inorganic chemistry (12-12-2005)“…The lithium salt of the anionic SPS pincer ligand composed of a central hypervalent lambda4-phosphinine ring bearing two ortho-positioned diphenylphosphine…”
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Syntheses, X-ray Structures, Photochemistry, Redox Properties, and DFT Calculations of Interconvertible f ac- and m er-[Mn(SPS)(CO)3] Isomers Containing a Flexible SPS-Based Pincer Ligand
Published in Inorganic chemistry (12-12-2005)“…The lithium salt of the anionic SPS pincer ligand composed of a central hypervalent λ4-phosphinine ring bearing two ortho-positioned diphenylphosphine sulfide…”
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Syntheses, X-ray structures, Photochemistry, Redox Properties and DFT Calculations of Inter-Convertible fac- and mer- [Mn(SPS)(CO)3] Isomers containing a flexible SPS-based pincer ligand
Published in Inorganic chemistry (2005)“…The lithium salt of the anionic SPS pincer ligand composed of a central hypervalent 4-phosphinine ring bearing two ortho-positioned diphenylphosphine sulfide…”
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Synthesis, Spectroscopy and Spectroelectrochemistry of Chlorocarbonyl {1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene-κ2-N,N'}rhodium(I)
Published in Collection of Czechoslovak chemical communications (01-01-2003)“…Reaction of the dinuclear complex [{Rh(CO) 2 } 2 (μ-Cl) 2 ] with an α-diimine ligand, 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene ( i Pr 2 Ph-bian),…”
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Soluble redox-active polymetallic chains [{Ru0(CO)(L)(bpy)}m](n) (bpy = 2,2'-bipyridine, L = PrCN, Cl-; m = 0, -1): electrosynthesis and characterization
Published in Inorganic chemistry (07-09-2009)“…Electrochemical and spectroelectrochemical techniques were employed to study in detail the formation and so far unreported spectroscopic properties of soluble…”
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Electrochemical and Catalytic Properties of Novel Manganese(III) Complexes with Substituted 2-(2′-Hydroxyphenyl)oxazoline Ligands − X-ray Structures of Tris[5-methyl-2-(2′-oxazolinyl)phenolato]manganese(III) and Tris[5-chloro-2-(2′-oxazolinyl)phenolato]manganese(III)
Published in European journal of inorganic chemistry (01-02-2002)“…A series of manganese complexes of the type MnL3 were synthesised and characterised, with HL being (substituted) 2‐(2′‐hydroxyphenyl)oxazoline ligands. The…”
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Novel Complexes trans(Cl)-[Os(bpy)(CO)(CH3CN)Cl2]n (n = 0, +1; bpy = 2,2′-Bipyridine): Photo- and Electrochemical Syntheses and Comparative Study of Their Bonding and Redox Properties
Published in European journal of inorganic chemistry (01-11-2002)“…Photoirradiation of the complex trans(Cl)‐[Os(bpy)(CO)2Cl2] in acetonitrile with λ ⩾ 320 nm light gives rise to substitution of a CO ligand, with the formation…”
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Air-Tight Three-Electrode Design of Coaxial Electrochemical-EPR Cell for Redox Studies at Low Temperatures
Published in Collection of Czechoslovak chemical communications (2001)“…The weak point of the original Allendoerfer electrochemical-EPR cell has been the reference electrode, placed outside the space-limited electrolysis cavity or…”
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Electrochemical and Photochemical Conversion of [Ru 3 Ir(μ 3 -H)(CO) 13 ] into [Ru 3 Ir(μ-H) 3 (CO) 12 ]
Published in Journal of cluster science (01-03-2004)“…Electrochemical and photochemical properties of the tetrahedral cluster [Ru3Ir(μ3-H)(CO)13] were studied in order to prove whether the previously established…”
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Synthesis and characterization of two isomers of decacarbonyl (1,4-dialkyl-1,4-diaza-1,3-butadiene)triosmium: Os3(CO)10(R-DAB). Fluxional behavior of Os3(CO)10(i-Pr-Pr-DAB(4e)) and of the 50e cluster Os3(CO)10(c-Pr-DAB(6e)) containing a 4e donor .rho.,.rho.-N,N' and a 6e donor .rho.-N, .mu.2-N', .eta.2-C:N' bonded R-DAB ligand, respectively
Published in Organometallics (01-10-1988)Get full text
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