Search Results - "Maguire, Oliver R"

A physicochemical orthophosphate cycle via a kinetically stable thermodynamically activated intermediate enables mild prebiotic phosphorylations by Maguire, Oliver R., Smokers, Iris B. A., Huck, Wilhelm T. S.

“…The incorporation of orthophosphate from scarce geochemical sources into the organic compounds essential for life under mild conditions is a fundamental…”
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Dynamic Environments as a Tool to Preserve Desired Output in a Chemical Reaction Network by Maguire, Oliver R., Wong, Albert S. Y., Baltussen, Mathieu G., Duppen, Peer, Pogodaev, Aleksandr A., Huck, Wilhelm T. S.

“…Current efforts to design functional molecular systems have overlooked the importance of coupling out‐of‐equilibrium behaviour with changes in the environment…”
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The Many‐Chemicals Problem of Systems Chemistry by Maguire, Oliver R.

“…An E. coli cell contains ~2500 different chemicals which combine into an ordered biochemical reaction network out of which emerges a living system. A chemist…”
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A Prebiotic Precursor to Life’s Phosphate Transfer System with an ATP Analog and Histidyl Peptide Organocatalysts by Maguire, Oliver R., Smokers, Iris B. A., Oosterom, Bob G., Zheliezniak, Alla, Huck, Wilhelm T. S.

“…Biochemistry is dependent upon enzyme catalysts accelerating key reactions. At the origin of life, prebiotic chemistry must have incorporated catalytic…”
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A catalytically active oscillator made from small organic molecules by ter Harmsel, Matthijs, Maguire, Oliver R., Runikhina, Sofiya A., Wong, Albert S. Y., Huck, Wilhelm T. S., Harutyunyan, Syuzanna R.

“…Oscillatory systems regulate many biological processes, including key cellular functions such as metabolism and cell division, as well as larger-scale…”
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Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect by Collett, Christopher J., Massey, Richard S., Taylor, James E., Maguire, Oliver R., O'Donoghue, AnnMarie C., Smith, Andrew D.

“…Rate and equilibrium constants for the reaction between N‐aryl triazolium N‐heterocyclic carbene (NHC) precatalysts and substituted benzaldehyde derivatives to…”
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Unusually high α-proton acidity of prolyl residues in cyclic peptides by Maguire, Oliver R, Taylor, Bethany, Higgins, Eleanor M, Rees, Matthew, Cobb, Steven L, Simpkins, Nigel S, Hayes, Christopher J, O'Donoghue, AnnMarie C

“…The acidity of the α-proton in peptides has an essential role in numerous biochemical reactions and underpins their stereochemical integrity, which is critical…”
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Syntheses and Electronic Structure of Bimetallic Complexes Containing a Flexible Redox-Active Bridging Ligand by Lindsay, Stacey, Lo, Siu K, Maguire, Oliver R, Bill, Eckhard, Probert, Michael R, Sproules, Stephen, Hess, Corinna R

“…The new ligand L 1 , 1-N,1-N-bis(pyridine-2-ylmethyl)-3-N-(pyridine-2-ylmethylidene)benzene-1,3-diamine, was synthesized as a platform for the study of…”
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Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect by Collett, Christopher J., Massey, Richard S., Taylor, James E., Maguire, Oliver R., O'Donoghue, AnnMarie C., Smith, Andrew D.

“…Rate and equilibrium constants for the reaction between N‐aryl triazolium N‐heterocyclic carbene (NHC) precatalysts and substituted benzaldehyde derivatives to…”
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