Search Results - "Maeda, Yonezo"
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Spectroscopic Characterization of a Hydroperoxo-Heme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex
Published in Angewandte Chemie (International ed.) (23-11-2009)“…Modeling job: Protonation of a closed seven‐coordinate side‐on heme peroxide can switch its spin state from high‐ to low‐spin and convert the η2 binding…”
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Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes: Models for Peroxo Intermediates of Non-Heme Diiron Proteins
Published in Journal of the American Chemical Society (26-01-2005)“…(μ-Hydroxo or oxo)(μ-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(μ-OH or μ-O)(μ-O2)(L)2] n…”
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Isolation and Crystal Structure of a Peroxo-Bridged Heme-Copper Complex
Published in Angewandte Chemie International Edition (23-06-2003)“…A stable bridge: A peroxo‐bridged Fe–O2–Cu complex (see picture) was synthesized and isolated as crystals. The X‐ray structure analysis revealed that the…”
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Gradual Two-step Spin Crossover Behavior of Binuclear Iron(III) Complex Bridged by trans-1,2-Bis(4-pyridyl)ethylene
Published in Chemistry letters (05-10-2005)“…A binuclear iron(III) complex bridged by trans-1,2-bis(4-pyridyl)ethylene, [LFeIII(vibpy)FeIIIL](BPh4)2, showed a gradual two-step spin crossover behavior,…”
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Crystal Structure and Magnetic Property of Two Novel 1-D Cobalt(II) Assemblies
Published in Chemistry letters (01-01-2007)“…Two novel one-dimensional (1-D) cobalt(II) self-assemblies, [Co(pyterpy)(NCS)2] (1) and [Co(pyterpy)(SO4)]·(CH3OH)(C2H5OH)(H2O) (2) (pyterpy =…”
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Novel Structural and Magnetic Properties of a 1-D Iron(II)−Manganese(II) LIESST Compound Bridged by Cyanide
Published in Inorganic chemistry (17-10-2005)“…The 1-D compound [Fe(L)(CN)2][Mn(hfac)2] (1), which adopts the −NC−Fe−CN−Mn− heterometallic structure, has been shown to exhibit light-induced excited…”
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Characterization of a Fluoride-bridged Mixed-valent Tetrairon(II,II,III,III) Complex
Published in Chemistry letters (05-01-2009)“…A di-μ-fluoride mixed-valent tetrairon(II,II,III,III) complex, [{Fe2(L)(dnba)}2(μ-F)2](BF4)2, was synthesized and characterized by X-ray structural analysis,…”
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A New Mononuclear Iron(III) Complex Containing a Peroxocarbonate Ligand
Published in Angewandte Chemie International Edition (02-04-2002)“…Stabilization of a peroxocarbonate ligand by formation of a five‐membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction…”
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Preparation of a Carboxylate-binding Mononuclear Iron(II) (−)-Sparteine Complex with Structural Distortion and Its Reaction with Oxidants
Published in Chemistry letters (05-01-2007)“…A novel iron complex with a distorted coordination geometry, [FeII((−)-sp)(OBz)2] (1) ((−)-sp = (−)-sparteine, OBz = benzoate anion), was prepared and…”
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Spin crossover iron(III) complexes
Published in Coordination chemistry reviews (01-11-2007)“…Metal complexes, of which metal ions have d 4–d 7 electrons, may exhibit spin conversion by external stimuli, and they are called spin crossover (SCO)…”
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[CoII(phimpy)2](ClO4)2 and [CoII(ipimpy)2](ClO4)2: New Cobalt(II) Spin Crossover Compounds, and the Role of the Ligand Flexibility in Spin Transition Behavior
Published in Chemistry letters (05-10-2003)“…New spin-crossover compounds, [Co(phimpy)2](ClO4)2 (1) and [Co(ipimpy)2](ClO4)2 (2) (phimpy = 2,6-bis(N-phenylformimidoyl)pyridine and ipimpy =…”
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Hysteresis Loops in Dielectric Properties of the Thermochromic Copper(II) Compounds
Published in Chemistry letters (01-10-2006)“…The dielectric changes of thermochromic compounds, [Cu(dieten)2]X2 (X = BF4 and ClO4, dieten = N,N-diethylethylenediamine), have been induced by the…”
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Study of Intermolecular Interaction for the Spin-Crossover Iron(II) Compounds
Published in Bulletin of the Chemical Society of Japan (01-06-2003)“…The thermal spin transitions of iron(II) spin-crossover compounds [Fe(PM-iPA)2(NCS)2] (1) and [Fe(PM-iPA)2(NCSe)2] (2) (PM-iPA =…”
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Valence States and Structure of Mixed-Valence Dinuclear Iron(II,III) Complexes [Fe2(2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-methylphenol)(L)2](BF4)2
Published in Bulletin of the Chemical Society of Japan (01-11-2002)“…Mixed-valence dinuclear iron(II,III) complexes, [FeIIFeIII(bpmp)(L)2](BF4)2, have been prepared, and the structures, electrochemical properties and rates of…”
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Pressure-Stabilized Low-Spin State for Binuclear Iron(III) Spin-Crossover Compounds
Published in Bulletin of the Chemical Society of Japan (01-12-2001)“…Binuclear iron(III) spin-crossover complexes with salten ligand [Fe2(salten)2(L)](BPh4)2 were synthesized and characterized by single-crystal X-ray…”
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Synthesis and Magnetic Properties of Binuclear Iron(III) Complexes Containing Photoisomerization Ligand
Published in Chemistry letters (01-10-1998)“…Binuclear iron(III) spin-crossover complex [Fe2(salten)2(az)](BPh4)2 (az = azobis(4-pyridine)) was synthesized and characterized by X-ray single-crystal…”
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Photo‐Induced Spin Transition of Iron(III) Compounds with π–π Intermolecular Interactions
Published in Chemistry : a European journal (23-03-2009)“…Photo‐switching: The LIESST effect could be observed by introducing π–π intermolecular interaction even for iron(III) spin‐crossover (SCO) compounds being the…”
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Spectroscopic Characterization of a Hydroperoxo-Heme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex
Published in Angewandte Chemie (23-11-2009)“…So könnte O2 aktiviert werden: Die Protonierung eines siebenfach koordinierten „Side‐on“‐Peroxo‐Hämkomplexes führt zu einem Wechsel vom High‐spin‐ in den…”
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Valence Delocalization and Crystal Structure of [Fe3O(pazo)6(py)3]·3py: An Example of the Mixed Valence Delocalization between Two Iron Atoms
Published in Bulletin of the Chemical Society of Japan (01-10-1999)“…The oxo-centered, trinuclear, mixed-valence complex [Fe3O(pazo)6(py)3]·3py, where pazo is 4-phenylazobenzoic acid, has been prepared, and the intramolecular…”
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