Search Results - "Macpherson, Brendan P"

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    Time-Resolved Spectroscopy of the Metal-to-Metal Charge Transfer Excited State in Dinuclear Cyano-Bridged Mixed-Valence Complexes by Macpherson, Brendan P, Bernhardt, Paul V, Hauser, Andreas, Pagès, Stéphane, Vauthey, Eric

    Published in Inorganic chemistry (25-07-2005)
    “…Visible pump−probe spectroscopy has been used to identify and characterize short-lived metal-to-metal charge transfer (MMCT) excited states in a group of…”
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  3. 3

    Dinuclear Cyano-Bridged CoIII−FeII Complexes as Precursors for Molecular Mixed-Valence Complexes of Higher Nuclearity by Bernhardt, Paul V, Bozoglián, Fernando, González, Gabriel, Martínez, Manuel, Macpherson, Brendan P, Sienra, Beatriz

    Published in Inorganic chemistry (09-01-2006)
    “…The preparation and characterization of a series of trinuclear mixed-valence cyano-bridged CoIII−FeII−CoIII compounds derived from known dinuclear [{L n…”
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    Isomeric Distribution and Catalyzed Isomerization of Cobalt(III) Complexes with Pentadentate Macrocyclic Ligands. Importance of Hydrogen Bonding by Aullón, Gabriel, Bernhardt, Paul V, Bozoglián, Fernando, Font-Bardía, Mercè, Macpherson, Brendan P, Martínez, Manuel, Rodríguez, Carlos, Solans, Xavier

    Published in Inorganic chemistry (16-10-2006)
    “…We have investigated the isomeric distribution and rearrangement of complexes of the type [CoXL n ]2+,3+ (where X = Cl-, OH-, H2O, and L n represents a…”
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    Oxidation of mixed-valence Co(III)/Fe(II) complexes reversed at high pH: a kinetico-mechanistic study of water oxidation by Bernhardt, Paul V, Bozoglian, Fernando, Macpherson, Brendan P, Martínez, Manuel, Merbach, André E, González, Gabriel, Sienra, Beatriz

    Published in Inorganic chemistry (01-11-2004)
    “…The outer-sphere oxidation of Fe(II) in the mixed-valence complex trans-[L(14S)Co(III)NCFe(II)(CN)(6)](-), being L(14S) an N(3)S(2) macrocylic donor set on the…”
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    Discrete Dinuclear Cyano-Bridged Complexes by Bernhardt, Paul V, Macpherson, Brendan P, Martinez, Manuel

    Published in Inorganic chemistry (13-11-2000)
    “…The cyano-bridged complexes [L14CoIIINCFeII(CN)5]-, [L14CoIIINCFeIII(CN)5], [L15CoIIINCFeII(CN)5]-, and [L15CoIIINCFeIII(CN)5] (L14 =…”
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  7. 7

    Discrete Cyanide-Bridged Mixed-Valence Co/Fe Complexes: Outer-Sphere Redox Behaviour by Bernhardt, Paul V., Bozoglian, Fernando, Macpherson, Brendan P., Martínez, Manuel, González, Gabriel, Sienra, Beatriz

    Published in European journal of inorganic chemistry (01-07-2003)
    “…The outer‐sphere redox behaviour of a series of [LnCoIIINCFeII(CN)5]− (Ln = n‐membered pentadentate aza‐macrocycle) complexes have been studied as a function…”
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    trans-Cyano(6-methyl-1,4,8,11-tetraazacyclotetradecan-6-amine)cobalt(III) bis(perchlorate) hydrate and trans-hydroxo(6-methyl-1,4,8,11-tetraazacyclotetradecan-6-amine)cobalt(III) bis(perchlorate) by Bernhardt, Paul V., Macpherson, Brendan P.

    “…The crystal structures of a pair of closely related macrocyclic cyano‐ and hydroxopenta­amine­cobalt(III) complexes, as their perchlorate salts, are reported…”
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    Geometric isomers of chloro(6-methyl-1,4,8,11-tetraazacyclotetradecane-6-amine)cobalt(III) tetrachlorozincate(II) by Bernhardt, Paul V., Macpherson, Brendan P.

    “…The crystal structures of a pair of cis and trans isomers of the macrocyclic chloro­penta­amine title complex, as their tetra­chloro­zincate(II) salts,…”
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    Molecular mixed-valence cyanide bridged Co III–Fe II complexes by Bernhardt, Paul V., Bozoglián, Fernando, Macpherson, Brendan P., Martínez, Manuel

    Published in Coordination chemistry reviews (01-09-2005)
    “…Cyano-bridged mixed-valence compounds have been known for a long time, i.e., Prussian Blue polymeric solids. Nevertheless, the interest in discrete complexes…”
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    Oxidation of Mixed-Valence CoIII/FeII Complexes Reversed at High pH:  A Kinetico-Mechanistic Study of Water Oxidation by Bernhardt, Paul V, Bozoglian, Fernando, Macpherson, Brendan P, Martínez, Manuel, Merbach, André E, González, Gabriel, Sienra, Beatriz

    Published in Inorganic chemistry (01-11-2004)
    “…The outer-sphere oxidation of FeII in the mixed-valence complex trans-[L14SCoIIINCFeII(CN)6]-, being L14S an N3S2 macrocylic donor set on the cobalt(III)…”
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