Search Results - "Macpherson, Brendan P"
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Iron(III) Complex of a Crown Ether−Porphyrin Conjugate and Reversible Binding of Superoxide to Its Iron(II) Form
Published in Journal of the American Chemical Society (11-04-2007)“…The synthesis and characterization of the Fe(III) complex of a novel crown ether−porphyrin conjugate,…”
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Time-Resolved Spectroscopy of the Metal-to-Metal Charge Transfer Excited State in Dinuclear Cyano-Bridged Mixed-Valence Complexes
Published in Inorganic chemistry (25-07-2005)“…Visible pump−probe spectroscopy has been used to identify and characterize short-lived metal-to-metal charge transfer (MMCT) excited states in a group of…”
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Dinuclear Cyano-Bridged CoIII−FeII Complexes as Precursors for Molecular Mixed-Valence Complexes of Higher Nuclearity
Published in Inorganic chemistry (09-01-2006)“…The preparation and characterization of a series of trinuclear mixed-valence cyano-bridged CoIII−FeII−CoIII compounds derived from known dinuclear [{L n…”
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Isomeric Distribution and Catalyzed Isomerization of Cobalt(III) Complexes with Pentadentate Macrocyclic Ligands. Importance of Hydrogen Bonding
Published in Inorganic chemistry (16-10-2006)“…We have investigated the isomeric distribution and rearrangement of complexes of the type [CoXL n ]2+,3+ (where X = Cl-, OH-, H2O, and L n represents a…”
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Oxidation of mixed-valence Co(III)/Fe(II) complexes reversed at high pH: a kinetico-mechanistic study of water oxidation
Published in Inorganic chemistry (01-11-2004)“…The outer-sphere oxidation of Fe(II) in the mixed-valence complex trans-[L(14S)Co(III)NCFe(II)(CN)(6)](-), being L(14S) an N(3)S(2) macrocylic donor set on the…”
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Discrete Dinuclear Cyano-Bridged Complexes
Published in Inorganic chemistry (13-11-2000)“…The cyano-bridged complexes [L14CoIIINCFeII(CN)5]-, [L14CoIIINCFeIII(CN)5], [L15CoIIINCFeII(CN)5]-, and [L15CoIIINCFeIII(CN)5] (L14 =…”
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Discrete Cyanide-Bridged Mixed-Valence Co/Fe Complexes: Outer-Sphere Redox Behaviour
Published in European journal of inorganic chemistry (01-07-2003)“…The outer‐sphere redox behaviour of a series of [LnCoIIINCFeII(CN)5]− (Ln = n‐membered pentadentate aza‐macrocycle) complexes have been studied as a function…”
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trans-Cyano(6-methyl-1,4,8,11-tetraazacyclotetradecan-6-amine)cobalt(III) bis(perchlorate) hydrate and trans-hydroxo(6-methyl-1,4,8,11-tetraazacyclotetradecan-6-amine)cobalt(III) bis(perchlorate)
Published in Acta crystallographica. Section C, Crystal structure communications (01-12-2003)“…The crystal structures of a pair of closely related macrocyclic cyano‐ and hydroxopentaaminecobalt(III) complexes, as their perchlorate salts, are reported…”
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Geometric isomers of chloro(6-methyl-1,4,8,11-tetraazacyclotetradecane-6-amine)cobalt(III) tetrachlorozincate(II)
Published in Acta crystallographica. Section C, Crystal structure communications (01-11-2003)“…The crystal structures of a pair of cis and trans isomers of the macrocyclic chloropentaamine title complex, as their tetrachlorozincate(II) salts,…”
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10
Molecular mixed-valence cyanide bridged Co III–Fe II complexes
Published in Coordination chemistry reviews (01-09-2005)“…Cyano-bridged mixed-valence compounds have been known for a long time, i.e., Prussian Blue polymeric solids. Nevertheless, the interest in discrete complexes…”
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11
Dinuclear Cyano-Bridged Co III −Fe II Complexes as Precursors for Molecular Mixed-Valence Complexes of Higher Nuclearity
Published in Inorganic chemistry (01-01-2006)Get full text
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12
Oxidation of Mixed-Valence Co III /Fe II Complexes Reversed at High pH: A Kinetico-Mechanistic Study of Water Oxidation
Published in Inorganic chemistry (01-11-2004)Get full text
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Oxidation of Mixed-Valence CoIII/FeII Complexes Reversed at High pH: A Kinetico-Mechanistic Study of Water Oxidation
Published in Inorganic chemistry (01-11-2004)“…The outer-sphere oxidation of FeII in the mixed-valence complex trans-[L14SCoIIINCFeII(CN)6]-, being L14S an N3S2 macrocylic donor set on the cobalt(III)…”
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