Search Results - "Machida, Akihiko"
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Experimental elucidation of a cubane water cluster in the hydrophobic cavity of UiO-66
Published in Chemphyschem (27-10-2024)“…Nanoscale water plays a pivotal role in determining the properties and functionalities of materials, and the precise control of its quantity and atomic-scale…”
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Pressure–Volume Relationship of a Au–Al–Yb Intermediate Valence Quasicrystal and Its Crystalline Approximant
Published in MATERIALS TRANSACTIONS (01-03-2021)“…Synchrotron X-ray diffraction experiments of an icosahedral Au–Al–Yb quasicrystal and its 1/1 crystalline approximant were performed under quasi-hydrostatic…”
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Enhanced Negative Thermal Expansion Induced by Simultaneous Charge Transfer and Polar–Nonpolar Transitions
Published in Journal of the American Chemical Society (11-12-2019)“…Negative thermal expansion (NTE) induced by simultaneous mechanisms, that is, charge transfer and polar–nonpolar transitions, was observed for the first time…”
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Effects of rolling and annealing on hydrogen permeability and crystal orientation in Nb-TiNi two-phase alloys
Published in International journal of hydrogen energy (30-08-2019)“…The Nb19Ti40Ni41 alloy has a lamellar structure with bcc-Nb and B2-TiNi phases. It is known that a granule Nb phase forms in the TiNi matrix after thermal…”
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Zeolitic intralayer microchannels of magadiite, a natural layered silicate, to boost green organic synthesis
Published in Chemical science (Cambridge) (14-12-2018)“…Despite the considerable attention given to the applications of magadiite in previous research, the properties of this natural layered silicate have remained…”
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Crystal and Magnetic Structures of Double Hexagonal Close-Packed Iron Deuteride
Published in Scientific reports (18-06-2020)“…Neutron powder diffraction profiles were collected for iron deuteride (FeD x ) while the temperature decreased from 1023 to 300 K for a pressure range of 4–6…”
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Nanostructural Perspective for Destabilization of Mg Hydride Using the Immiscible Transition Metal Mn
Published in Inorganic chemistry (04-10-2021)“…Phase segregation in hydride-forming alloys may persist under the action of multiple hydrogenation/dehydrogenation cycles. We use this effect to destabilize…”
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Temperature Dependence of Yb Valence in an Au–Al–Yb Intermediate-Valence Quasicrystal Investigated by Yb L3-Edge X-ray Absorption Near-Edge Structure Spectroscopy
Published in MATERIALS TRANSACTIONS (01-10-2022)“…In this paper, we investigate the temperature dependence of Yb valence in an Au–Al–Yb intermediate-valence quasicrystal by Yb L3-edge synchrotron X-ray…”
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Mixed-valence state and structure changes of EuHx (x = 2 and 2 < x ≤ 3) under high-pressure H2 atmosphere
Published in Journal of alloys and compounds (05-06-2021)“…•Eu2+ and Eu3+ mixed-valence state phases were observed in EuHx for the first time.•Structural and valence phase diagram of EuH2 and EuHx (2< x ≤ 3) compressed…”
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Addendum: Site occupancy of interstitial deuterium atoms in face-centred cubic iron
Published in Nature communications (14-10-2024)Get full text
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Origin and Absence of Giant Negative Thermal Expansion in Reduced and Oxidized Ca2RuO4
Published in Chemistry of materials (12-10-2021)“…Negative thermal expansion (NTE) is an intriguing physical phenomenon. Layered Ca2RuO4 exhibits giant NTE over a wide temperature range from 200 to 400 K,…”
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Pressure cells for in situ neutron total scattering: time and real‐space resolution during deuterium absorption
Published in Journal of applied crystallography (01-12-2022)“…In situ gas‐loading sample holders for two‐dimensionally arranged detectors in time‐of‐flight neutron total scattering experiments have been developed to…”
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Hexagonal Close-packed Iron Hydride behind the Conventional Phase Diagram
Published in Scientific reports (23-08-2019)“…Hexagonal close-packed iron hydride, hcp FeH x , is absent from the conventional phase diagram of the Fe–H system, although hcp metallic Fe exists stably over…”
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Sequential Spin State Transition and Intermetallic Charge Transfer in PbCoO3
Published in Journal of the American Chemical Society (25-03-2020)“…Spin state transitions and intermetallic charge transfers can essentially change material structural and physical properties while excluding external chemical…”
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Unveiling Nanoscale Compositional and Structural Heterogeneities of Highly Textured Mg0.7Ti0.3Hy Thin Films
Published in Inorganic chemistry (18-05-2020)Get full text
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Condensed ferric dimers for green photocatalytic synthesis of nylon precursors
Published in Chemical science (Cambridge) (21-07-2019)“…Although iron oxides have been extensively studied as photocatalysts because of their abundance and environmental compatibility, their performance is…”
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Site occupancy of interstitial deuterium atoms in face-centred cubic iron
Published in Nature communications (26-09-2014)“…Hydrogen composition and occupation state provide basic information for understanding various properties of the metal–hydrogen system, ranging from microscopic…”
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Bragg coherent diffraction imaging allowing simultaneous retrieval of three-dimensional shape and strain distribution for 40–500 nm particles
Published in Japanese Journal of Applied Physics (01-11-2021)“…We report the improvement of an apparatus for Bragg coherent X-ray diffraction imaging (Bragg-CDI) at BL22XU in SPring-8 to expand the applicable particle size…”
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Formation of BCC TiFe hydride under high hydrogen pressure
Published in International journal of hydrogen energy (30-05-2013)“…We investigated the hydrogenation of a binary TiFe alloy at 5 GPa and 600 °C by in situ synchrotron radiation X-ray diffraction measurements. After formation…”
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