Search Results - "Maassarani, Fida"

Cyclopalladation of 2-[(Dimethylamino)methyl]-Substituted Naphthalenes: 1- vs 3-Palladation. Crystal Structures of [Hydrotris(pyrazolyl)borato][2-[(dimethylamino)methyl)]-3-naphthyl]palladium and trans-[4,4-Dimethyl-2-(2-naphthyl)oxazoline]palladium Dichloride by Valk, Jean-Marc, Maassarani, Fida, van der Sluis, Paul, Spek, Anthony L, Boersma, Jaap, van Koten, Gerard

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Controlled synthesis of heterocyclic compounds through ring enlargement by alkyne insertions into the Pd-C bonds of cyclopalladated amines followed by subsequent ring closure by MAASSARANI, F, PFEFFER, M, LE BORGNE, G

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Stepwise insertion of one, two, and three alkyne molecules into the Pd-C bond of a six-membered palladocycle. One-pot synthesis of spirocyclic compounds by MAASSARANI, F, PFEFFER, M, LE BORGNE, G

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Formal C-C triple-bond splitting in an organopalladium compound by MAASSARANI, F, PFEFFER, M, LE BORGNE, G

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Reactivity of cyclopalladated compounds. 19. Regioselective formation of .eta.3-allylic ligands via the reaction of alkynes with [cyclic] [{Pd(CH(SiMe3)C6H4NMe2-2)(.mu.-Cl)}2] by Maassarani, Fida, Pfeffer, Michel, Van Koten, Gerard

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Reactivity of cyclopalladated compounds. 23. Formal carbon-carbon triple-bond splitting in an organopalladium compound by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy

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Stabilization and reaction behaviour of a terminal phosphido unit on a mononuclear Pt(II) centre. Synthesis and X-ray structure of a cationic diphenylphosphine complex [Pt{C6H3(CH2NMe2)2-2,6}(PHPh2)][OSO2CF3] and a diphenylphosphido-bridged Pt(II)/Pd(II) complex [Pt{C6H3(CH2NMe2)2-2,6}(μ-PPh2)Pd(C6H4CH2NMe2-2)-(H2O)][BF4]·CH2Cl2 by Maassarani, Fida, Davidson, Michael F., Wehman-Ooyevaar, Ingrid C.M., Grove, David M., van Koten, Martijn A., Smeets, Wilberth J.J., Spek, Anthony L., van Koten, Gerard

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Stabilization and reaction behaviour of a terminal phosphido unit on a mononuclear Pt(II) centre. Synthesis and X-ray structure of a cationic diphenylphosphine complex [Pt{C 6H 3(CH 2NMe 2) 2-2,6}(PHPh 2)][OSO 2CF 3] and a diphenylphosphido-bridged Pt(II)/Pd(II) complex [Pt{C 6H 3(CH 2NMe 2) 2-2,6}(μ-PPh 2)Pd(C 6H 4CH 2NMe 2-2)-(H 2O)][BF 4]·CH 2Cl 2 by Maassarani, Fida, Davidson, Michael F., Wehman-Ooyevaar, Ingrid C.M., Grove, David M., van Koten, Martijn A., Smeets, Wilberth J.J., Spek, Anthony L., van Koten, Gerard

“…Reaction of diphenylphosphine with the complexes [Pt(NCN)(H 2O)]X (NNCC 6H 3(CH 2NMe 2) 2-2,6; XBF 4 ( 1a), OSO 2CF 3 ( 1b)) leads to substitution of the H…”
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Organopalladium compounds with a chiral palladated carbon atom. Facile isolation of optically active cyclopalladated complexes containing the (S)- or (R)-[2-NMe2C6H4CH(SiMe3)] monoanion. Molecular structure of {2-[1-(S)-(dimethylamino)ethyl]phenyl}[2-(dimethylamino)-α-(trimethylsilyl)benzyl]palladium(II) by MAASSARANI, F, PFEFFER, M, LE BORGNE, G

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Reaction of cyclopalladated compounds. 15. Controlled synthesis of heterocyclic compounds through ring enlargement by alkyne insertions into the palladium-carbon bonds of cyclopalladated amines followed by ring closure by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy

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Reaction of cyclopalladated compounds Part 16. Stepwise insertion of one, two, and three alkyne molecules into the palladium-carbon bond of a six-membered palladocycle. One-pot synthesis of spirocyclic compounds by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy

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Reactivity of cyclopalladated compounds. Part 12. Insertion of 3,3-dimethylcyclopropenes into the palladium-carbon bond of cyclopalladated dimethylbenzylamine, leading to carbon-carbon bond cleavage or cyclopropyl ring retention. X-ray crystal and molecular structure of [cyclic][Pd[C(CO2Me)CMe2CHC6H4CH2NMe2]pyCl] by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy, Grandjean, Daniel

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A novel olefin bridged dinuclear arylpalladium compound. X-ray crystal structure of [cyclic] [NMe2CH2C6H4Pd-.mu.-{C(CF3):C(CF3)C(CF3):C(CF3)}PdCH(SiMe3)C6H4NMe2] by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy, Wehman, Erik, Van Koten, Gerard

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Reactivity of cyclopalladated compounds. 13. Organopalladium compounds with a chiral palladated carbon atom. Facile isolation of optically active cyclopalladated complexes containing the (S)- or (R)-[2-Me2NC6H4CH(SiMe3)] monoanion. Molecular structure of [2-[1-(S)-(dimethylamino)ethyl]phenyl][2-(dimethylamino)-.alpha.-(trimethylsilyl)benzyl]palladium(II) by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy, Jastrzebski, Johann T. B. H, Van Koten, Gerard

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Reactivity of mixed cyclometalated palladium compounds containing the [2-Me2NC6H4C(H)SiMe3] monoanion. Part 2. Transmetalation reaction and formation of a novel .mu.-alkylidene compound (x-ray) bis(.mu.-chloro)bis{.mu.-C,.sigma.-N-[2-(dimethylamino)benzylidene](.mu.-chloro)(diethyl sulfide)dipalladium(II)} by Maassarani, Fida, Pfeffer, Michel, Spek, Anthony L, Schreurs, Antoine M. M, Van Koten, Gerard

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