Search Results - "MORTREUX, Andre"
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Enantioselective Nickel Catalyzed Butadiene Hydroalkoxylation with Ethanol: from Experimental Results to Kinetics Parameters
Published in Catalysis letters (01-01-2021)“…The enantioselective hydroalkoxylation of butadiene with ethanol has been performed in the presence of nickel-based catalysts and chiral diphosphine ligands…”
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Journal Article -
2
Synthesis of C4 chain glyceryl ethers via nickel-catalyzed butadiene hydroalkoxylation reaction
Published in Molecular catalysis (01-02-2017)“…[Display omitted] •New glycerol ethers with short alkenyl (C4) tails are synthesized.•The products are easily separated according to up-scalable simple…”
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3
Alkyne metathesis catalysts: Scope and future
Published in Journal of molecular catalysis. A, Chemical (19-07-2006)“…This paper presents the evolution of alkyne metathesis since the early discoveries, essentially from the catalyst point of view. It is shown that although well…”
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Journal Article Conference Proceeding -
4
Ferrocene/ferrocenium redox shuttling: Peroxide decomposition catalysis applied to vinyl monomers polymerization under suspension conditions
Published in Polymer (Guilford) (08-11-2022)“…Ascorbic acid derivatives in combination with ferrocenyl-based activators in catalytic amounts, referred to as kickers, are described as powerful redox systems…”
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5
In situ Mo(CO)₆-based catalysts for alkyne metathesis: Silanols vs phenols as co-catalysts under thermal and photochemical activation
Published in Catalysis communications (15-04-2020)“…A systematic study on the use of silanols and phenols as effective activators in Mo(CO)₆ – based catalytic systems for metathesis of 4-decyne and…”
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6
Access to new carbohydrate-functionalized polylactides via organocatalyzed ring-opening polymerization
Published in Polymer (Guilford) (13-10-2011)“…The 4-dimethylaminopyridine (DMAP) catalyzed ring-opening polymerization of lactide using various carbohydrate initiators has been assessed for the…”
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Journal Article -
7
Synthesis of Short-Chain Alkenyl Ethers from Primary and Bio-sourced Alcohols via the Nickel-Catalyzed Hydroalkoxylation Reaction of Butadiene and Derivatives
Published in Advanced synthesis & catalysis (07-01-2016)“…Hydroalkoxylation of butadiene has been performed in the presence of nickel precatalysts associated with chelating diphosphine ligands. High butadiene…”
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Towards Selective Syntheses of Octadienylethers from the Butadiene Palladium‐catalyzed Telomerization with Polyols in Aqueous Biphasic Medium
Published in ChemCatChem (20-03-2019)“…The palladium catalyzed telomerization of butadiene with polyols has been efficiently performed under aqueous and biphasic medium leading to the corresponding…”
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Journal Article -
9
Terminal Alkyne Metathesis: A Further Step Towards Selectivity
Published in Advanced synthesis & catalysis (01-10-2006)“…Terminal alkyne metathesis has been improved by addition of quinuclidine as an external ligand to the (t‐BuO)3WCBu‐t carbyne complex, giving a yield of 80 %…”
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Journal Article -
10
Palladium catalyzed telomerization of bio-based polyols with atmospheric pressure bubbling butadiene
Published in Molecular catalysis (01-02-2021)“…Aqueous biphasic conditions with bubbling butadiene are used to efficiently synthesize glycerol monoethers and polyol monoethers. [Display omitted] •Design of…”
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Journal Article -
11
Palladium- N-heterocyclic carbene an efficient catalytic system for the carbonylative cross-coupling of pyridine halides with boronic acids
Published in Tetrahedron (15-01-2007)“…Carbonylative cross-coupling of different pyridyl halides with various boronic acids was studied using catalytic systems constituted of N-heterocyclic carbene…”
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12
Coordinative Chain Transfer Polymerization
Published in Chemical reviews (08-05-2013)“…Valente et al examine the coordinative chain transfer polymerization process…”
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Journal Article -
13
Biphasic Palladium-Catalyzed Hydroesterification in a Polyol Phase: Selective Synthesis of Derived Monoesters
Published in ChemSusChem (22-06-2015)“…The palladium‐catalyzed hydroesterification reaction was performed with polyols and olefins in a liquid/liquid biphasic system composed of unreacted polyol on…”
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Journal Article -
14
Facile Synthesis of Lanthanidocenes by the "Borohydride/Alkyl Route" and Their Application in Isoprene Polymerization
Published in European Journal of Inorganic Chemistry (01-06-2010)“…Several borohydridolanthanidocenes were synthesized by means of a straightforward approach starting from equimolar amounts of Ln(BH4)3(thf)3 (Ln = Nd, Sm) and…”
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Book Review Journal Article -
15
Cross-Metathesis of Biosourced Fatty Acid Derivatives: A Step Further Toward Improved Reactivity
Published in ChemSusChem (13-04-2015)“…The improved catalytic conversion of bioresources, namely unsaturated fatty acid derivatives, is presented. The targeted reaction is ruthenium‐catalyzed…”
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Journal Article -
16
A General and Efficient Method for the Alkoxycarbonylation of α-Chloro Ketones
Published in Advanced synthesis & catalysis (12-11-2012)“…The alkoxycarbonylation of α‐chloro ketones with carbon monoxide in alcoholic solvents could be optimized to generate β‐keto esters in high yields using much…”
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Journal Article -
17
Improved reactivity in the conversion of nitrile-functionalized olefins by metathesis
Published in Catalysis communications (05-03-2016)“…In this contribution, we study the conversion of a bio-sourced unsaturated fatty ester by cross-metathesis with nitrile-functionalized olefinic partners…”
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Journal Article -
18
Telomerisation of 1,3-butadiene with glycerol under aqueous biphasic conditions: Influence of the reaction conditions on the products distribution
Published in Applied catalysis. A, General (15-07-2010)“…The telomerisation of butadiene with glycerol catalyzed by palladium under aqueous biphasic conditions has been investigated in detail as well as under gaseous…”
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Journal Article -
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Synthesis of 1,4:3,6-Dianhydrohexitols Diesters from the Palladium-Catalyzed Hydroesterification Reaction
Published in ChemSusChem (01-11-2014)“…The hydroesterification of alpha olefins has been used to synthesize diesters from bio‐based secondary diols: isosorbide, isomannide, and isoidide. The…”
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Journal Article -
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New Synthesis of Furans: the Rhodium-Catalysed Carbonylative Addition of Arylboronic Acids to Propargylic Alcohols/ Cyclisation Sequence
Published in Advanced synthesis & catalysis (15-02-2010)“…The rhodium‐catalysed carbonylative addition of arylboronic acids to propargylic alcohols yields gamma‐hydroxy enones that are readily cyclised through a…”
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