Search Results - "MAYORAL, J. A"
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Fatty acid derivatives and their use as CFPP additives in biodiesel
Published in Bioresource technology (01-02-2011)“…One of the main drawbacks of the use of biodiesel is its bad behavior at low temperatures. In this work, we show that it is possible to take profit of the…”
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Brimonidine-LAPONITE® intravitreal formulation has an ocular hypotensive and neuroprotective effect throughout 6 months of follow-up in a glaucoma animal model
Published in Biomaterials science (21-11-2020)“…Intravitreal administration is widely used in ophthalmological practice to maintain therapeutic drug levels near the neuroretina and because drug delivery…”
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3
Pybox Monolithic Miniflow Reactors for Continuous Asymmetric Cyclopropanation Reaction under Conventional and Supercritical Conditions
Published in Journal of organic chemistry (08-06-2007)“…Supported catalysts having pybox chiral moieties were prepared as macroporous monolithic miniflow systems. These catalysts are based on styrene-divinylbenzene…”
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Theoretical (DFT) Insights into the Mechanism of Copper-Catalyzed Cyclopropanation Reactions. Implications for Enantioselective Catalysis
Published in Journal of the American Chemical Society (08-08-2001)“…The mechanism of the copper(I)-catalyzed cyclopropanation reaction has been extensively investigated for a medium-size reaction model by means of…”
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Density Functional Theory Study of a Lewis Acid Catalyzed Diels−Alder Reaction. The Butadiene + Acrolein Paradigm
Published in Journal of the American Chemical Society (18-03-1998)“…The four transition structures (TS's) of the reaction between butadiene and acrolein, both uncatalyzed and catalyzed by BF3, have been theoretically studied…”
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Synthesis of diamine functionalized mesoporous organosilicas with large pores
Published in Journal of sol-gel science and technology (01-12-2009)“…Hybrid mesoporous silicas functionalized with ethylenediamine groups have been synthesized via sol–gel process under different conditions. The best textural…”
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Bis(oxazoline)copper Complexes Covalently Bonded to Insoluble Support as Catalysts in Cyclopropanation Reactions
Published in Journal of organic chemistry (28-12-2001)“…Chiral bis(oxazolines) are readily dialkylated in the methylene bridge, opening the way to immobilization at that position, keeping the C 2 symmetry of the…”
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Polymer-Supported Bis(oxazolines) and Related Systems: Toward New Heterogeneous Enantioselective Catalysts
Published in Industrial & engineering chemistry research (09-11-2005)“…Polymer-supported bis(oxazoline) and related ligands have been prepared by grafting and by polymerization methodologies under a variety of conditions. The…”
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Clay-supported non-chiral and chiral Mn(salen) complexes as catalysts for olefin epoxidation
Published in Journal of molecular catalysis. A, Chemical (11-11-1998)“…Clay-supported non-chiral Mn(salen) catalysts have been prepared by two methods, direct exchange of the complex or treatment of the Mn-exchanged clay with the…”
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Solvent effects on the mechanism and selectivities of asymmetric Diels-Alder reactions
Published in Journal of the American Chemical Society (01-09-1993)Get full text
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Bis(oxazoline)-metal complexes immobilised by electrostatic interactions as heterogeneous catalysts for enantioselective Diels–Alder reactions
Published in Journal of molecular catalysis. A, Chemical (08-01-2001)“…The immobilisation by cationic exchange of complexes of a bis(oxazoline) with Cu(II), Mg(II) and Zn(II) has been studied with two types of anionic solid, a…”
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Supported chiral catalysts: the role of the polymeric network
Published in Reactive & functional polymers (02-05-2001)“…In the preparation of chiral-supported catalysts, the immobilization process can produce changes in the behavior of the resulting resin-supported species. The…”
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Journal Article Conference Proceeding -
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Synthesis and characterization of molecularly imprinted polymers with metallic zinc center for enrofloxacin recognition
Published in Reactive & functional polymers (01-08-2013)“…A molecularly imprinted polymer with a metallic center (MIPc) was prepared and characterized. The template molecule for MIPc was a complex…”
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Improvement of ligand economy controlled by polymer morphology: The case of polymer-Supported bis(oxazoline) catalysts
Published in Bioorganic & medicinal chemistry letters (22-07-2002)“…A functionalized chiral bis(oxazoline) is used as a chiral monomer in polymerization reactions leading to homo- and copolymers of different morphology…”
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Challenging cyclopropanation reactions on non-activated double bonds of fatty esters
Published in RSC advances (01-01-2017)“…Monounsaturated fatty esters with non-activated double bonds have been made to react with two different diazocompounds, ethyl diazoacetate (EDA) and dimethyl…”
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Antioxidant enzyme responses to salinity stress of Jatropha curcas and J. cinerea at seedling stage
Published in Russian journal of plant physiology (2014)“…The salt-sensitive humid tropical biodiesel crop, Jatropha curcas, was subjected to a 28-day exposure to salinity (0, 50, 100, and 200 mM NaCl), and activities…”
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Vanadium sites in V-K10: Characterization and catalytic properties in liquid-phase sulfide oxidation
Published in Journal of molecular catalysis. A, Chemical (01-08-2006)“…V-K10 presents both monomeric and dimeric species, that can be reversibly transformed between V 4+ and V 5+ states. The species in the highest oxidation state…”
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Do Secondary Orbital Interactions Really Exist?
Published in Accounts of chemical research (01-10-2000)“…A revision of the most typical examples used to illustrate the existence of secondary orbital interactions (SOI) has been achieved. However, our analysis…”
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Bis(oxazoline)-copper complexes, immobilized by electrostatic interactions, as catalysts for enantioselective aziridination
Published in ARKIVOC (27-12-2003)Get full text
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ZnCl2, ZnI2 and TiCl4 supported on silica gel as catalysts for the Diels-Alder reactions of furan
Published in Journal of molecular catalysis. A, Chemical (15-08-1997)Get full text
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