First mass spectrometric measurements of positive ions in the stratosphere

Three experiments were made at high latitudes by using rocketborne cryogenically pumped quadrupole mass filters. Mass spectra of positive ions at stratospheric heights were obtained between 24 and 60 km during descent portions of the rocket flights. The mass numbers of the most abundant ions detecte...

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Bibliographic Details
Published in:Nature (London) Vol. 267; no. 5606; pp. 30 - 32
Main Authors: ARNOLD, F, KRANKOWSKY, D, MARIEN, K. H
Format: Journal Article
Language:English
Published: 01-01-1977
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Summary:Three experiments were made at high latitudes by using rocketborne cryogenically pumped quadrupole mass filters. Mass spectra of positive ions at stratospheric heights were obtained between 24 and 60 km during descent portions of the rocket flights. The mass numbers of the most abundant ions detected are tabulated along with tentative identifications (19 plus or minus 2, 29 plus or minus 2, 37 plus or minus 2, 42 plus or minus 2, 55 plus or minus 2, 60 plus or minus 2, and 80 plus or minus 2 AMU). Figures indicate the fractional abundance on non-proton hydrates; number densities of the unknown reaction partner X as derived from the data, total gas density, and a theoretical CH sub(2) O profile; and a simplified reaction scheme for stratospheric positive ions at heights above 24 km.
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ISSN:0028-0836
1476-4687
DOI:10.1038/267030a0