Search Results - "MARDER, B"

Recent developments in and perspectives on three-coordinate boron materials: a bright future by Ji, Lei, Griesbeck, Stefanie, Marder, Todd B

“…The empty p z -orbital of a three-coordinate organoboron compound leads to its electron-deficient properties, which make it an excellent π-acceptor in…”
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Recent advances in asymmetric borylation by transition metal catalysis by Hu, Jiefeng, Ferger, Matthias, Shi, Zhuangzhi, Marder, Todd B

“…Chiral organoboronates have played a critical role in organic chemistry and in the development of materials science and pharmaceuticals. Much effort has been…”
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Photoinduced Borylation for the Synthesis of Organoboron Compounds by Tian, Ya-Ming, Guo, Xiao-Ning, Braunschweig, Holger, Radius, Udo, Marder, Todd B

“…Organoboron compounds have important synthetic value and can be applied in numerous transformations. The development of practical and convenient ways to…”
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Will We Soon Be Fueling our Automobiles with Ammonia-Borane by Marder, Todd B

“…The B all and N all? Ammonia–borane (AB, H3NBH3) contains 19.6 weight % H, and is one of the materials currently being examined as a possible H2 source for use…”
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First-Row d‑Block Element-Catalyzed Carbon–Boron Bond Formation and Related Processes by Bose, Shubhankar Kumar, Mao, Lujia, Kuehn, Laura, Radius, Udo, Nekvinda, Jan, Santos, Webster L, Westcott, Stephen A, Steel, Patrick G, Marder, Todd B

“…Organoboron reagents represent a unique class of compounds because of their utility in modern synthetic organic chemistry, often affording unprecedented…”
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Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse by Neeve, Emily C, Geier, Stephen J, Mkhalid, Ibraheem A. I, Westcott, Stephen A, Marder, Todd B

“…Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural…”
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(Hetero)arene-fused boroles: a broad spectrum of applications by He, Jiang, Rauch, Florian, Finze, Maik, Marder, Todd B

“…(Hetero)arene-fused boroles are a class of compounds containing a 5-membered boron diene-ring. Based on their molecular framework, the (hetero)arene-fused…”
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Synthetic Approaches to Triarylboranes from 1885 to 2020 by Berger, Sarina M., Ferger, Matthias, Marder, Todd B.

“…In recent years, research in the fields of optoelectronics, anion sensors and bioimaging agents have been greatly influenced by novel compounds containing…”
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Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents by Kleeberg, Christian, Dang, Li, Lin, Zhenyang, Marder, Todd B

“…A simple but effective copper-catalyzed borylation of aryl halides, including electron-rich and sterically hindered aryl bromides, with alkoxy diboron reagents…”
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Copper‐Catalyzed Triboration of Terminal Alkynes Using B2pin2: Efficient Synthesis of 1,1,2‐Triborylalkenes by Liu, Xiaocui, Ming, Wenbo, Friedrich, Alexandra, Kerner, Florian, Marder, Todd B.

“…We report herein the catalytic triboration of terminal alkynes with B2pin2 (bis(pinacolato)diboron) using readily available Cu(OAc)2 and PnBu3. Various…”
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B----N versus C----C: How Similar Are They by Liu, Zhiqiang, Marder, Todd B

“…One of these bonds is not like the others: Cyclic π systems in which BN units replace their isoelectronic CC counterparts have intrigued chemists and…”
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Selective Photocatalytic C–F Borylation of Polyfluoroarenes by Rh/Ni Dual Catalysis Providing Valuable Fluorinated Arylboronate Esters by Tian, Ya-Ming, Guo, Xiao-Ning, Kuntze-Fechner, Maximilian W, Krummenacher, Ivo, Braunschweig, Holger, Radius, Udo, Steffen, Andreas, Marder, Todd B

“…A highly selective and general photocatalytic C–F borylation protocol that employs a rhodium biphenyl complex as a triplet sensitizer and the nickel catalyst…”
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Persistent Room Temperature Phosphorescence from Triarylboranes: A Combined Experimental and Theoretical Study by Wu, Zhu, Nitsch, Jörn, Schuster, Julia, Friedrich, Alexandra, Edkins, Katharina, Loebnitz, Marcel, Dinkelbach, Fabian, Stepanenko, Vladimir, Würthner, Frank, Marian, Christel M., Ji, Lei, Marder, Todd B.

“…Achieving highly efficient phosphorescence in purely organic luminophors at room temperature remains a major challenge due to slow intersystem crossing (ISC)…”
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Synthesis, Structure, and Reactivity of Anionic sp2-sp3 Diboron Compounds: Readily Accessible Boryl Nucleophiles by Pietsch, Sabrina, Neeve, Emily C., Apperley, David C., Bertermann, Rüdiger, Mo, Fanyang, Qiu, Di, Cheung, Man Sing, Dang, Li, Wang, Jianbo, Radius, Udo, Lin, Zhenyang, Kleeberg , Christian, Marder , Todd B.

“…Lewis base adducts of tetra‐alkoxy diboron compounds, in particular bis(pinacolato)diboron (B2pin2), have been proposed as the active source of nucleophilic…”
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Copper‐Catalyzed Triboration: Straightforward, Atom‐Economical Synthesis of 1,1,1‐Triborylalkanes from Terminal Alkynes and HBpin by Liu, Xiaocui, Ming, Wenbo, Zhang, Yixiao, Friedrich, Alexandra, Marder, Todd B.

“…A convenient and efficient one‐step synthesis of 1,1,1‐triborylalkanes was achieved via sequential dehydrogenative borylation and double hydroborations of…”
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Switching on and off Interlayer Correlations and Porosity in 2D Covalent Organic Frameworks by Sick, Torben, Rotter, Julian M, Reuter, Stephan, Kandambeth, Sharath, Bach, Nicolai N, Döblinger, Markus, Merz, Julia, Clark, Timothy, Marder, Todd B, Bein, Thomas, Medina, Dana D

“…Two-dimensional covalent organic frameworks (2D COFs) attract great interest owing to their well-defined pore structure, thermal stability, high surface area,…”
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A leap ahead for activating C-H bonds by Bose, Shubhankar Kumar, Marder, Todd B

“…Boron-based catalysts add functional groups to normally unreactive carbon-hydrogen bonds [Also see Report by Légaré et al. ] Although great strides have been…”
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C−H Activation for the Construction of C−B Bonds by Mkhalid, Ibraheem A. I, Barnard, Jonathan H, Marder, Todd B, Murphy, Jaclyn M, Hartwig, John F

“…Chemical reactions involving the activation of carbon-hydrogen bonds for the purpose of forming carbon-boron bonds are examined. The barriers to cleavage of…”
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Fluorinated Aryl Boronates as Building Blocks in Organic Synthesis by Budiman, Yudha P., Westcott, Stephen A., Radius, Udo, Marder, Todd B.

“…Organoboron compounds are well known building blocks for many organic reactions. However, under basic conditions, polyfluorinated aryl boronic acid derivatives…”
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Zinc-Catalyzed Dual C-X and C-H Borylation of Aryl Halides by Bose, Shubhankar Kumar, Deißenberger, Andrea, Eichhorn, Antonius, Steel, Patrick G., Lin, Zhenyang, Marder, Todd B.

“…A zinc‐catalyzed combined CX and CH borylation of aryl halides using B2pin2 (pin=OCMe2CMe2O) to produce the corresponding 1,2‐diborylarenes under mild…”
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