Search Results - "MAGULL, Jörg"
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Synthesis and Characterization of [PhC(NtBu)2]SiCl: A Stable Monomeric Chlorosilylene
Published in Angewandte Chemie International Edition (12-06-2006)“…The single life: The reaction of [PhC(NtBu)2]SiCl3 (1) with potassium afforded the monomeric chlorosilylene [PhC(NtBu)2]SiCl (2). The X‐ray crystal structure…”
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2
GaCl3-catalyzed insertion of diazene derivatives into the cyclopropane ring
Published in Journal of organic chemistry (28-09-2007)Get full text
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3
Rhenium(V) Oxo Complexes with Acetylacetone Derived Schiff Bases: Structure and Catalytic Epoxidation
Published in Inorganic chemistry (20-08-2007)“…Substitution reactions of rhenium(V) oxo precursors [ReOCl3(PPh3)2] or [NBu4][ReOCl4] with the bidentate acetylacetone-derived ketoamine ligands APOH =…”
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4
A Reactivity Change of a Strontium Monohydroxide by Umpolung to an Acid
Published in Inorganic chemistry (07-07-2008)“…Controlled hydrolysis of strontium amide LSrN(SiMe3)2(thf) (L = CH(CMe2,6-i-Pr2C6H3N)2) (1) gave an unprecedented example of a hydrocarbon-soluble strontium…”
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5
(E,E)-1,2,3,4-Tetracyclopropylbuta-1,3-diene: Synthesis and Some of Its Properties
Published in European journal of organic chemistry (01-12-2012)“…(E,E)‐1,2,3,4‐Tetracyclopropylbuta‐1,3‐diene (3) and (Z,Z)‐1,4‐diodo‐1,2,3,4‐tetracyclopropylbuta‐1,3‐diene (4) were prepared from dicyclopropylacetylene via…”
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6
Selective Treatment of Cancer: Synthesis, Biological Evaluation and Structural Elucidation of Novel Analogues of the Antibiotic CC-1065 and the Duocarmycins
Published in Chemistry : a European journal (25-05-2007)“…Novel diastereomerically pure β‐D‐galactosidic prodrugs (+)‐12 a–e of the cytotoxic antibiotics CC‐1065 and the duocarmycins were prepared for an antibody…”
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7
Comprehensive Study of Okaspirodiol: Characterization, Total Synthesis, and Biosynthesis of a New Metabolite from Streptomyces
Published in Journal of organic chemistry (15-09-2006)“…The new spiro[4.5]acetal okaspirodiol (4) was isolated from Streptomyces sp. Gö TS 19 as a secondary metabolite in yields up to 380 mg/L. The structure of this…”
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8
Six- and Eightfold Palladium-Catalyzed Cross-Coupling Reactions of Hexa- and Octabromoarenes
Published in Chemistry : a European journal (01-01-2005)“…Palladium‐catalyzed sixfold coupling of hexabromobenzene (20) with a variety of alkenylboronates and alkenylstannanes provided hexaalkenylbenzenes 1 in up to…”
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9
Synthesis and Structural Characterization of a Terminal Hydroxide Containing Alumoxane via Hydrolysis of Aluminum Hydrides
Published in Inorganic chemistry (23-02-2004)“…A novel terminal hydroxide containing dinuclear alumoxane LAl(OH)OAlL(OCHN-tBu) (3; L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) was prepared by treatment of aluminum…”
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10
Spirodionic Acid, a Novel Metabolite from Streptomyces sp., Part 1: Structure Elucidation and Diels-Alder-Type Biosynthesis
Published in Chemistry : a European journal (01-01-2007)“…Spirodionic acid (1), a novel microbial metabolite with a spiro[4.5]decene skeleton, the 6‐ethyl‐2H‐pyrone 5, dihydrosarkomycin (6), and other metabolites were…”
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11
Pyrrolylaldiminato Complexes of Zn, Mg and Al
Published in European journal of inorganic chemistry (01-05-2002)“…The reaction of 2‐(2,6‐iPr2C6H3N=CH)‐5‐R‐C4H2NH (R = H, L1H; R = tBu, L2H) with one equivalent of ZnMe2 or MgnBu2 in toluene or n‐hexane afforded the…”
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12
Syntheses, Structures, and Surface Aromaticity of the New Carbaalane [(AlH)6(AlNMe3)2(CCH2R)6] (R = Ph, CH2SiMe3) and a Stepwise Functionalization of the Inner and Outer Sphere of the Cluster
Published in Journal of the American Chemical Society (15-05-2002)“…The reaction of the acetylene RC⋮CH (R = Ph, CH2SiMe3) with an excess of AlH3·NMe3 in boiling toluene leads to the carbaalane [(AlH)6(AlNMe3)2(CCH2R)6] (R = Ph…”
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13
Structurally Characterized Neutral Monoalkyl and -aryl Complexes of Manganese(II)
Published in Organometallics (15-03-2004)“…The synthesis and X-ray crystal structures of the monomethyl and -phenyl manganese complexes [LMn(μ-Me)]2 (2) and LMnPh (3) (L = HC(CMeNAr)2, Ar =…”
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14
Synthesis of Carbaalane Halogen Derivatives
Published in Inorganic chemistry (14-06-2004)“…The carbaalane halogen derivatives [(AlX)6(AlNMe3)2(CCH2CH2SiMe3)6] (X = F (9), Cl (7), Br (10), I (11)) were prepared in toluene from…”
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15
Decacyclene as Complexation Manifold: Synthesis, Structure and Properties of Its Fe2 and Fe4 Slipped Triple-Decker Complexes
Published in Chemistry : a European journal (01-02-2006)“…Reaction of [(η5‐Me4EtC5)FeIICl(tmeda)] (tmeda=N,N,N′N′‐tetramethylethylenediamine) with a polyanion solution of decacyclene (1) results in the formation of…”
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16
Octacyclopropylcubane and Some of Its Isomers
Published in Angewandte Chemie International Edition (01-01-2007)Get full text
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17
New Polyhedral Zinc Siloxanes: Synthesis and X-ray Crystal Structures of Zn8Me7(dioxane)2(O3SiR)3 and [Zn7Me2(THF)5(O3SiR)4] [R = (2,6-i-Pr2C6H3)N(SiMe3)]
Published in Organometallics (10-05-2004)“…In continuation of our previous work on the synthesis of zinc siloxanes to understand the influence of stoichiometry in the assembly of polyhedral zinc…”
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18
The Monomerization of a Binuclear Molybdenum(VI) Dioxo Complex by an Unusual Silylation Reaction
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (01-08-2007)“…The formation of a mononuclear molybdenum(VI) complex [MoO2{O(CH2)2S(CH2)2OH}(OSiButPh2)] (2) derived from its binuclear precursor [MoO2{O(CH2)2S(CH2)2O}]2 (1)…”
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19
[{HC(CMeNAr)2}2Al2P4] (Ar=2,6-iPr2C6H3): A Reduction to a Formal {P4}4− Charged Species
Published in Angewandte Chemie International Edition (28-06-2004)“…A whiter shade of PAl: The reaction of LAlI with white phosphorus yields the first main‐group complex [(LAl)2P4] (L=HC(CMeNAr)2, Ar=2,6‐iPr2C6H3) containing…”
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20
Exchange Interactions at the Supramolecular Level − Synthesis, Crystal Structure, Magnetic Properties, and EPR Spectra of [Mn(MAC)(TCNQ)2] (MAC = Pentaaza Macrocyclic Ligand; TCNQ·− = Radical Anion of 7,7,8,8-Tetracyano-p-quinodimethane)
Published in European journal of inorganic chemistry (01-05-2003)“…The reaction between [Mn(MAC)(H2O)2]Cl2·4H2O and LiTCNQ (MAC = 2,13‐dimethyl‐3,6,9,12,18‐pentaazabicyclo[12.3.1]octadeca‐1(18),2,12,14,16‐pentaene) affords a…”
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