Search Results - "MACK, James"
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Ruthenium-Catalyzed C–H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives
Published in Journal of the American Chemical Society (19-07-2017)“…The identification, optimization, and evaluation of a new catalytic protocol for sp3 C–H hydroxylation is described. Reactions are performed in aqueous acid…”
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Intermolecular C(sp3)−H Amination of Complex Molecules
Published in Angewandte Chemie International Edition (23-04-2018)“…A general and operationally convenient method for intermolecular amination of C(sp3)−H bonds is described. This technology allows for efficient…”
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3
Plastid genomes reveal support for deep phylogenetic relationships and extensive rate variation among palms and other commelinid monocots
Published in The New phytologist (01-01-2016)“…Despite progress based on multilocus, phylogenetic studies of the palms (order Arecales, family Arecaceae), uncertainty remains in resolution/support among…”
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4
Pharmacology of Valinate and tert-Leucinate Synthetic Cannabinoids 5F-AMBICA, 5F-AMB, 5F-ADB, AMB-FUBINACA, MDMB-FUBINACA, MDMB-CHMICA, and Their Analogues
Published in ACS chemical neuroscience (21-09-2016)“…Indole and indazole synthetic cannabinoids (SCs) featuring l-valinate or l-tert-leucinate pendant group have recently emerged as prevalent recreational drugs,…”
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5
Decoupling the Arrhenius equation via mechanochemistry
Published in Chemical science (Cambridge) (01-08-2017)“…Mechanochemistry continues to reveal new possibilities in chemistry including the opportunity for "greening" reactions. Nevertheless, a clear understanding of…”
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Mechanistic Study of Ruthenium-Catalyzed C–H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest
Published in Journal of the American Chemical Society (16-01-2019)“…We have recently disclosed [(dtbpy)2RuCl2] as an effective precatalyst for chemoselective C–H hydroxylation of C(sp3)–H bonds and have noted a marked…”
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7
Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity
Published in Journal of the American Chemical Society (24-02-2016)“…Dirhodium-catalyzed C–H amination is hypothesized to proceed via Rh2-nitrene intermediates in either the Rh2(II,II) or Rh2(II,III) redox state. Herein, we…”
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8
Electrochemical Ruthenium-Catalyzed C–H Hydroxylation of Amine Derivatives in Aqueous Acid
Published in Organic letters (18-09-2020)“…The development of an electrochemically driven, ruthenium-catalyzed C–H hydroxylation reaction of amine-derived substrates bearing tertiary C–H bonds is…”
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9
Comparative transcriptomics of Venus flytrap (Dionaea muscipula) across stages of prey capture and digestion
Published in PloS one (12-08-2024)“…The Venus flytrap, Dionaea muscipula, is perhaps the world's best-known botanical carnivore. The act of prey capture and digestion along with its rapidly…”
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10
Evolution of rapid blue‐light response linked to explosive diversification of ferns in angiosperm forests
Published in The New phytologist (01-05-2021)“…Summary Ferns appear in the fossil record some 200 Myr before angiosperms. However, as angiosperm‐dominated forest canopies emerged in the Cretaceous period…”
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11
A Universal Probe Set for Targeted Sequencing of 353 Nuclear Genes from Any Flowering Plant Designed Using k-Medoids Clustering
Published in Systematic biology (01-07-2019)“…Sequencing of target-enriched libraries is an efficient and cost-effective method for obtaining DNA sequence data from hundreds of nuclear loci for phylogeny…”
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12
Monocot plastid phylogenomics, timeline, net rates of species diversification, the power of multi-gene analyses, and a functional model for the origin of monocots
Published in American journal of botany (01-11-2018)“…Premise of the Study We present the first plastome phylogeny encompassing all 77 monocot families, estimate branch support, and infer monocot‐wide divergence…”
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13
150 Years of Coevolution Research: Evolution and Ecology of Yucca Moths (Prodoxidae) and Their Hosts
Published in Annual review of entomology (25-01-2024)“…Yucca moths ( Tegeticula and Parategeticula ) are specialized pollinators of yucca plants, possessing unique, tentacle-like mouthparts used to actively collect…”
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14
Interchromosomal linkage disequilibrium and linked fitness cost loci associated with selection for herbicide resistance
Published in The New phytologist (01-05-2023)“…Summary The adaptation of weeds to herbicide is both a significant problem in agriculture and a model of rapid adaptation. However, significant gaps remain in…”
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15
Green plant genomes: What we know in an era of rapidly expanding opportunities
Published in Proceedings of the National Academy of Sciences - PNAS (25-01-2022)“…Green plants play a fundamental role in ecosystems, human health, and agriculture. As de novo genomes are being generated for all known eukaryotic species as…”
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The Choice Is Yours: Using Liquid-Assisted Grinding To Choose between Products in the Palladium-Catalyzed Dimerization of Terminal Alkynes
Published in ACS catalysis (05-02-2016)“…Herein, we report on the dimerization of terminal alkynes using various palladium catalysts under solvent-free mechanochemical conditions. When…”
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Selecting Superior De Novo Transcriptome Assemblies: Lessons Learned by Leveraging the Best Plant Genome
Published in PloS one (05-01-2016)“…Whereas de novo assemblies of RNA-Seq data are being published for a growing number of species across the tree of life, there are currently no broadly accepted…”
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18
Comprehending Cornales: phylogenetic reconstruction of the order using the Angiosperms353 probe set
Published in American journal of botany (01-07-2021)“…Premise Cornales is an order of flowering plants containing ecologically and horticulturally important families, including Cornaceae (dogwoods) and…”
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Shifts in gene expression profiles are associated with weak and strong Crassulacean acid metabolism
Published in American journal of botany (01-03-2018)“…Premise of the Study The relative ease of high throughput sequencing is facilitating comprehensive phylogenomic and gene expression studies, even for nonmodel…”
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Evolution of chloroplast retrograde signaling facilitates green plant adaptation to land
Published in Proceedings of the National Academy of Sciences - PNAS (12-03-2019)“…Chloroplast retrograde signaling networks are vital for chloroplast biogenesis, operation, and signaling, including excess light and drought stress signaling…”
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