Search Results - "MACALUSO, Robin T"
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Structural Diversity of Rare-Earth Oxychalcogenides
Published in ACS omega (15-03-2022)“…Mixed-anion systems have garnered much attention in the past decade with attractive properties for diverse applications such as energy conversion, electronics,…”
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Synthesis, structure, and magnetic behavior of (LaxCe1−x)1.33Pt4Ga10 (0⩽x⩽1)
Published in Journal of alloys and compounds (05-07-2014)“…•Single crystals of (LaxCe1−x)1.33Pt4Ga10 (0⩽x⩽1) were synthesized using Ga flux.•Compositions of (LaxCe1−x)1.33Pt4Ga10 (0⩽x⩽1) determined by electron…”
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3
First Observation of Electronic Conductivity in Mixed-Valence Tellurium Oxides
Published in Chemistry of materials (08-12-2009)Get full text
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4
Lattice Anharmonicity of Stereochemically Active Lone Pairs Controls Thermochromic Band Gap Reduction of PbVO3Cl
Published in Chemistry of materials (08-09-2020)“…Stereochemically active lone pairs of electrons play an important role in a diverse range of physical phenomena in many materials, ranging from semiconducting…”
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Phase-Pure Copper Vanadate (α-CuV2O6): Solution Combustion Synthesis and Characterization
Published in Chemistry of materials (28-07-2020)“…This study addresses a perennial problem in the synthesis of copper vanadates, namely, that of phase purity. A time-efficient solution combustion synthesis…”
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6
Vacancy-Driven Disorder and Elevated Dielectric Response in the Pyrochlore Pb1.5Nb2O6.5
Published in Inorganic chemistry (21-11-2022)“…Lone pair-driven distortions are a hallmark of many technologically important lead (Pb)-based materials. The role of Pb2+ in polar perovskites is well…”
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Versatility of Tellurium in Heteroanionic Ln2O2Te (Ln = La, Ce, Pr) and Tellurate Ln2TeO6 (Ln = La, Pr)
Published in Inorganic chemistry (14-11-2022)“…Heteroanionic compounds continue to gain interest in materials design because the expanded composition space provides opportunities to discover new phases and…”
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Arc Synthesis, Crystal Structure, and Photoelectrochemistry of Copper(I) Tungstate
Published in ACS applied materials & interfaces (21-07-2021)“…A little-studied p-type ternary oxide semiconductor, copper(I) tungstate (Cu2WO4), was assessed by a combined theoretical/experimental approach. A detailed…”
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Role of f Electrons in the Optical and Photoelectrochemical Behavior of Ca(La 1- x Ce x ) 2 S 4 (0 ≤ x ≤ 1)
Published in Inorganic chemistry (01-04-2019)“…This study focuses on a solid solution series, Ca(La Ce ) S (0 ≤ x ≤ 1), where the f electron density is absent in CaLa S and is progressively increased until…”
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Role of f Electrons in the Optical and Photoelectrochemical Behavior of Ca(La1–x Ce x )2S4 (0 ≤ x ≤ 1)
Published in Inorganic chemistry (01-04-2019)“…This study focuses on a solid solution series, Ca(La1–x Ce x )2S4 (0 ≤ x ≤ 1), where the f electron density is absent in CaLa2S4 and is progressively…”
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11
Rapid One-Pot Synthesis and Photoelectrochemical Properties of Copper Vanadates
Published in ACS applied energy materials (22-04-2019)“…Solution combustion synthesis (SCS) is shown to be versatile for the rapid-one-pot synthesis of three compounds and four polymorphs in the Cu–V–O ternary…”
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12
Silver Oxide‐Based Semiconductors for Solar Fuels Production and Environmental Remediation: a Solid‐State Chemistry Approach
Published in ChemElectroChem (02-01-2019)“…A solid‐state perspective is offered for a discussion of silver‐based ternary and quaternary oxide semiconductors for applications related to solar fuels…”
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13
Crystal Structure and Physical Properties of Polymorphs of LnAlB4 (Ln = Yb, Lu)
Published in Chemistry of materials (17-04-2007)“…Single crystals of YbAlB4 were grown in excess Al flux. Plate- and needle-shaped crystals were found. The plates are found to be β-YbAlB4, which crystallizes…”
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14
Synthesis, structure, and magnetism of a new heavy-fermion antiferromagnet, CePdGa6
Published in Journal of solid state chemistry (01-09-2003)Get full text
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15
Crystal Growth and Structure Determination of LaMIn5 (M=Co, Rh, Ir)
Published in Journal of solid state chemistry (01-06-2002)“…The compounds CeMIn5 (M=Co, Rh, Ir) have been shown to exhibit heavy fermion behavior. In order to better understand this effect and the nature of the observed…”
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CsTe2O6–x : Novel Mixed-Valence Tellurium Oxides with Framework-Deficient Pyrochlore-Related Structure
Published in Inorganic chemistry (05-09-2011)“…Structures of CsTe2O6–x phases were investigated by single-crystal X-ray diffraction and neutron powder diffraction. Stoichiometric CsTe2O6 is a mixed-valence…”
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Crystal growth and structure of R2Ir2O7 (R=Pr, Eu) using molten KF
Published in Materials research bulletin (03-05-2007)Get full text
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18
Synthesis, structure and dielectric characterization of Ln2Ti2-2xM2xO7(Ln = Gd, Er; M = Zr, Sn, Si)
Published in Materials research bulletin (01-10-2002)Get full text
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Structures and phase transitions of CePd3+xGa8-x: new variants of the BaHg11 structure type
Published in Journal of the American Chemical Society (08-08-2012)“…New distorted variants of the cubic BaHg11 structure type have been synthesized in Ga flux. Multiple phases of CePd3+xGa8-x, which include an orthorhombic Pmmn…”
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Structure and properties of rhombohedral CePd3Ga8: A variant of the cubic parent compound with BaHg11 structure type
Published in Journal of solid state chemistry (01-12-2011)Get full text
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