Search Results - "Lv, Ze‐Jie"
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Progress of Azametallacyclopentadienes in the New Century
Published in Chemistry : a European journal (11-05-2023)“…As the key intermediates in metal‐promoted/catalyzed C−C bond coupling reactions of nitriles and alkynes, azametallacyclopentadienes, M(N=CR1−CR2=CR3), are an…”
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Well-Defined Scandacyclopropenes: Synthesis, Structure, and Reactivity
Published in Journal of the American Chemical Society (26-12-2019)“…Although transition metallacyclopropenes have been extensively explored for more than 40 years, their analogues of rare-earth metals have remained elusive…”
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Cascade C−H Activation and Two C−C Bond Forming in Reaction of Azalutetacyclopentadiene with 2‐Methylbenzonitriles
Published in Chemistry : a European journal (19-09-2024)“…Azametallacyclopentadienes are an important class of metallacycles as the key intermediates in metal‐promoted or catalyzed carbon‐carbon coupling reaction of…”
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Insertion Chemistry of Lutetacyclopropene toward Unsaturated C−O/C−N Bonds
Published in Chemistry : a European journal (25-11-2021)“…Although the reaction chemistry of transition metallacyclopropenes has been well‐established in the last decades, the reactivity of rare‐earth…”
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Direct transformation of dinitrogen: synthesis of N -containing organic compounds via N−C bond formation
Published in National science review (01-10-2020)“…Abstract N-containing organic compounds are of vital importance to lives. Practical synthesis of valuable N-containing organic compounds directly from…”
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Direct and chlorine-free synthesis of phosphafluorenes or their oxides from white phosphorus
Published in Green synthesis and catalysis (01-11-2023)“…The known methods for the preparation of acylphosphine oxides and polyfluorobenzene-substituted triarylphosphines need to utilize PCl3, while the chlorine-free…”
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Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N–C Bond Formation
Published in Journal of the American Chemical Society (05-06-2019)“…Direct conversion of dinitrogen (N2) into organic compounds, not through ammonia (NH3), is of great significance both fundamentally and practically. Here we…”
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N‑Aryloxide-Amidinate Thorium Complexes
Published in Inorganic chemistry (25-03-2024)“…An N-aryloxide-amidine ligand (1), [ONNO] ligand, integrating phenoxide (PhO–) and amidine ligands through methylene linkers, was employed in actinide…”
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Selective Cleavage of the Strong or Weak C–C Bonds in Biphenylene Enabled by Rare-Earth Metals
Published in Journal of the American Chemical Society (29-03-2023)“…Selective cleavage of C–C bonds within arene rings is of great interest but remains elusive, especially for the molecules possessing the active and inert C–C…”
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Reactivity of Lutetacyclopropene toward Benzyl, Benzoyl, and Trimethylsilyl Nitriles Affording Diversified Lutetium Complexes
Published in Organometallics (13-12-2021)“…Although the reaction of metallacyclopropenes toward alkyl and aryl nitriles has been extensively studied, their reactivity toward other types of nitriles,…”
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Cross-carbanion coupling at a rare-earth center
Published in Cell reports physical science (19-07-2023)“…Although reductive elimination of two carbanions at a transition metal center to forge one C–C bond is a fundamental process, the analogous process is missing…”
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Synthesis, Structures and Luminescent Properties of 3D Copper(I) 1,2,4-Triazolates Containing Cubic Cu4X4 Clusters (X = Cl, Br)
Published in Journal of cluster science (01-07-2015)“…Reactions of 3,5-disubstituted-1,2,4-triazoles with CuX 2 (X = Cl, Br) under hydrothermal condition yield six copper(I) triazolates: [Cu 2 (3,5- n Bu 2 tz)Cl]…”
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Monomethylation and -protonation of Lutetium Dinitrogen Complex
Published in Journal of the American Chemical Society (03-07-2024)“…Due to the highly chemically inert nature, direct activation and transformation of dinitrogen are challenging. Here, we disclose the synthesis, isolation, and…”
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Stabilizing Doubly Deprotonated Diazomethane: Isolable Complexes with CN2 2– and CN2 – Radical Ligands
Published in Journal of the American Chemical Society (07-12-2022)“…Transition metal complexes with a doubly deprotonated diazomethane (CNN2–) ligand have been proposed as fleeting intermediates in nitrogen transfer reactions…”
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Stabilizing Doubly Deprotonated Diazomethane: Isolable Complexes with CN22- and CN2- Radical Ligands
Published in Journal of the American Chemical Society (07-12-2022)Get full text
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Selective Coupling of Lanthanide Metallacyclopropenes and Nitriles via Azametallacyclopentadiene and η2‑Pyrimidine Metallacycle
Published in Journal of the American Chemical Society (23-06-2021)“…Exploring new lanthanide metallacycles and finding their unique chemistry different from the analogues of transition metals are of great interest and…”
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Triplet carbenes with transition-metal substituents
Published in Nature chemistry (01-11-2024)“…The extraordinary advances in carbene (R 1 –C–R 2 ) chemistry have been fuelled by strategies to stabilize the electronic singlet state via π interactions. In…”
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Stabilizing Doubly Deprotonated Diazomethane: Isolable Complexes with CN 2 2- and CN 2 - Radical Ligands
Published in Journal of the American Chemical Society (07-12-2022)“…Transition metal complexes with a doubly deprotonated diazomethane (CNN ) ligand have been proposed as fleeting intermediates in nitrogen transfer reactions…”
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