Search Results - "Luther, George W"
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Commemorating Two Centuries of Iodine Research: An Interdisciplinary Overview of Current Research
Published in Angewandte Chemie International Edition (02-12-2011)“…Iodine was discovered as a novel element in 1811 during the Napoleonic Wars. To celebrate the bicentennial anniversary of this event we reflect on the history…”
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Abundant Porewater Mn(III) Is a Major Component of the Sedimentary Redox System
Published in Science (American Association for the Advancement of Science) (23-08-2013)“…Soluble manganese(III) [Mn(III)] can potentially serve as both oxidant and reductant in one-electron-transfer reactions with other redox species. In…”
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Soluble Mn(III) in Suboxic Zones
Published in Science (American Association for the Advancement of Science) (29-09-2006)“…Soluble manganese(III) [Mn(III)] has been thought to disproportionate to soluble Mn(II) and particulate MnIVO2 in natural waters, although it persists as…”
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Role of One- and Two-Electron Transfer Reactions in Forming Thermodynamically Unstable Intermediates as Barriers in Multi-Electron Redox Reactions
Published in Aquatic geochemistry (01-06-2010)“…In the aquatic geochemical literature, a redox half-reaction is normally written for a multi-electron process (n > 2); e.g., sulfide oxidation to sulfate. When…”
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Redox reactions and weak buffering capacity lead to acidification in the Chesapeake Bay
Published in Nature communications (28-08-2017)“…The combined effects of anthropogenic and biological CO 2 inputs may lead to more rapid acidification in coastal waters compared to the open ocean. It is less…”
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Chemistry of Iron Sulfides
Published in Chemical reviews (01-02-2007)“…Iron and sulphur chemistry in marine systems is discussed. The chemical formation and kinetics of iron sulphide compounds by natural processes is explored…”
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Review on the physical chemistry of iodine transformations in the oceans
Published in Frontiers in Marine Science (15-02-2023)“…The transformation between iodate ( IO 3 − ), the thermodynamically stable form of iodine, and iodide (I - ), the kinetically stable form of iodine, has…”
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Iron and sulfide nanoparticle formation and transport in nascent hydrothermal vent plumes
Published in Nature communications (08-04-2019)“…Deep-sea hydrothermal vents are a significant source of dissolved metals to the global oceans, producing midwater plumes enriched in metals that are…”
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Microbial iron mats at the Mid-Atlantic Ridge and evidence that Zetaproteobacteria may be restricted to iron-oxidizing marine systems
Published in PloS one (11-03-2015)“…Chemolithoautotrophic iron-oxidizing bacteria play an essential role in the global iron cycle. Thus far, the majority of marine iron-oxidizing bacteria have…”
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Influence of Organic Ligands on the Redox Properties of Fe(II) as Determined by Mediated Electrochemical Oxidation
Published in Environmental science & technology (21-06-2022)“…Fe(II) has been extensively studied due to its importance as a reductant in biogeochemical processes and contaminant attenuation. Previous studies have shown…”
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Abiotic synthesis of graphite in hydrothermal vents
Published in Nature communications (15-11-2019)“…Deciphering the origin, age, and composition of deep marine organic carbon remains a challenge in understanding the dynamics of the marine carbon cycle. In…”
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Fe-catalyzed sulfide oxidation in hydrothermal plumes is a source of reactive oxygen species to the ocean
Published in Proceedings of the National Academy of Sciences - PNAS (05-10-2021)“…Historically, the production of reactive oxygen species (ROS) in the ocean has been attributed to photochemical and biochemical reactions. However,…”
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Iodide accumulation provides kelp with an inorganic antioxidant impacting atmospheric chemistry
Published in Proceedings of the National Academy of Sciences - PNAS (13-05-2008)“…Brown algae of the Laminariales (kelps) are the strongest accumulators of iodine among living organisms. They represent a major pump in the global…”
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Comparison of pyrite (FeS2) synthesis mechanisms to reproduce natural FeS2 nanoparticles found at hydrothermal vents
Published in Geochimica et cosmochimica acta (01-11-2013)“…Here we report the synthesis of pyrite in micrometer and nanometer sizes and with varied morphology. The purpose of these syntheses was to mimic natural pyrite…”
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Evidence for the role of endosymbionts in regional-scale habitat partitioning by hydrothermal vent symbioses
Published in Proceedings of the National Academy of Sciences - PNAS (20-11-2012)“…Deep-sea hydrothermal vents are populated by dense communities of animals that form symbiotic associations with chemolithoautotrophic bacteria. To date, our…”
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Occurrence and Mammalian Cell Toxicity of Iodinated Disinfection Byproducts in Drinking Water
Published in Environmental science & technology (15-11-2008)“…An occurrence study was conducted to measure five iodo-acids (iodoacetic acid, bromoiodoacetic acid, (Z)-3-bromo-3-iodo-propenoic acid,…”
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Low-oxygen and chemical kinetic constraints on the geochemical niche of neutrophilic iron(II) oxidizing microorganisms
Published in Geochimica et cosmochimica acta (15-07-2008)“…Neutrophilic iron oxidizing bacteria (FeOB) must actively compete with rapid abiotic processes governing Fe(II) oxidation and as a result have adapted to…”
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The molecular biogeochemistry of manganese(II) oxidation
Published in Biochemical Society transactions (01-12-2012)“…Micro-organisms capable of oxidizing the redox-active transition metal manganese play an important role in the biogeochemical cycle of manganese. In the…”
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Evidence for the presence of strong Mn(III)-binding ligands in the water column of the Chesapeake Bay
Published in Marine chemistry (01-04-2015)“…Soluble manganese speciation was determined in suboxic and anoxic waters of the Chesapeake Bay using a water soluble porphyrin ligand as spectrophotometric…”
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Acetylenotrophy: a hidden but ubiquitous microbial metabolism?
Published in FEMS microbiology ecology (01-08-2018)“…Acetylene (IUPAC name: ethyne) is a colorless, gaseous hydrocarbon, composed of two triple bonded carbon atoms attached to hydrogens (C2H2). When…”
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