Search Results - "Luo, Sanzhong"

Organocatalysis in Inert C–H Bond Functionalization by Qin, Yan, Zhu, Lihui, Luo, Sanzhong

“…As two coexisting and fast-growing research fields in modern synthetic chemistry, the merging of organocatalysis and C–H bond functionalization is well…”
Get full text

Asymmetric Electrochemical Catalysis by Lin, Qifeng, Li, Longji, Luo, Sanzhong

“…Asymmetric electrochemical catalysis, an emerging frontline in asymmetric catalysis and electro‐organic synthesis, is summarized. Representative works are…”
Get full text

Asymmetric α-allylic allenylation of β-ketocarbonyls and aldehydes by synergistic Pd/chiral primary amine catalysis by You, Chang, Shi, Mingying, Mi, Xueling, Luo, Sanzhong

“…We herein describe an asymmetric α -allylic allenylation of β -ketocarbonyls and aldehydes with 1,3-enynes. A synergistic chiral primary amine/Pd catalyst was…”
Get full text

Catalytic Asymmetric Disulfuration by a Chiral Bulky Three‐Component Lewis Acid‐Base by Zhang, Qi, Li, Yao, Zhang, Long, Luo, Sanzhong

“…A three‐component Lewis acid–base (Lewis trio) involving a bulky chiral primary amine, B(C6F5)3 and a bulky tertiary amine has been developed as an effective…”
Get full text

Asymmetric Retro-Claisen Reaction by Chiral Primary Amine Catalysis by Zhu, Yunbo, Zhang, Long, Luo, Sanzhong

“…The communication describes an enamine-based asymmetric retro-Claisen reaction of β-diketones by primary amine catalysis. The reaction proceeds via a sequence…”
Get full text

Asymmetric C–H Dehydrogenative Alkenylation via a Photo-induced Chiral α‑Imino Radical Intermediate by Jia, Zongbin, Cheng, Liang, Zhang, Long, Luo, Sanzhong

“…The direct alkenylation with simple alkenes stands out as the most ideal yet challenging strategy for obtaining high-valued desaturated alkanes. Here we…”
Get full text

Catalytic Regio‐ and Enantioselective [4+2] Annulation Reactions of Non‐activated Allenes by a Chiral Cationic Indium Complex by Wang, Le, Lv, Jian, Zhang, Long, Luo, Sanzhong

“…Regio‐ and enantioselective [4+2] annulation between β,γ‐unsaturated α‐keto esters and non‐activated allenes was achieved by using a chiral cationic…”
Get full text

Dynamic multiphase semi-crystalline polymers based on thermally reversible pyrazole-urea bonds by Liu, Wen-Xing, Yang, Zhusheng, Qiao, Zhi, Zhang, Long, Zhao, Ning, Luo, Sanzhong, Xu, Jian

“…Constructing responsive and adaptive materials by dynamic covalent bonds is an attractive strategy in material design. Here, we present a kind of dynamic…”
Get full text

Holistic Prediction of the pKa in Diverse Solvents Based on a Machine‐Learning Approach by Yang, Qi, Li, Yao, Yang, Jin‐Dong, Liu, Yidi, Zhang, Long, Luo, Sanzhong, Cheng, Jin‐Pei

“…While many approaches to predict aqueous pKa values exist, the fast and accurate prediction of non‐aqueous pKa values is still challenging. Based on the iBonD…”
Get full text

Visible‐Light‐Promoted Asymmetric Cross‐Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis by Yang, Qi, Zhang, Long, Ye, Chen, Luo, Sanzhong, Wu, Li‐Zhu, Tung, Chen‐Ho

“…Reported herein is an unprecedented photocatalytic asymmetric cross‐dehydrogenative coupling reaction between tertiary amines and simple ketones, and it…”
Get full text

Bio-inspired lanthanum-ortho-quinone catalysis for aerobic alcohol oxidation: semi-quinone anionic radical as redox ligand by Zhang, Ruipu, Zhang, Runze, Jian, Ruijun, Zhang, Long, Zhang, Ming-Tian, Xia, Yu, Luo, Sanzhong

“…Oxidation reactions are fundamental transformations in organic synthesis and chemical industry. With oxygen or air as terminal oxidant, aerobic oxidation…”
Get full text

Visible-Light Promoted Catalyst-Free Imidation of Arenes and Heteroarenes by Song, Lu, Zhang, Long, Luo, Sanzhong, Cheng, Jin-Pei

“…We described herein a catalyst‐free visible‐light photolytic protocol for the imidation of arenes and heteroarenes. N‐Bromosaccharin was identified as a viable…”
Get full text

Photoredox Mediated Acceptorless Dehydrogenative Coupling of Saturated N‑Heterocycles by Jia, Zongbin, Yang, Qi, Zhang, Long, Luo, Sanzhong

“…We report herein a direct unsymmetric coupling and controllable aromatization reaction of saturated N-heterocycles enabled by synergistic photoredox and acid…”
Get full text

Asymmetric Retro-Claisen Reaction by Synergistic Chiral Primary Amine/Palladium Catalysis by Han, Yanfang, Zhang, Long, Luo, Sanzhong

“…We described herein a chiral primary amine/palladium catalyzed asymmetric retro-Claisen reaction of β-diketones with salicylic carbonates. A series of chiral…”
Get full text

Catalytic Asymmetric Oxidative Enamine Transformations by Zhu, Lihui, Wang, Dehong, Jia, Zongbin, Lin, Qifeng, Huang, Mouxin, Luo, Sanzhong

“…Enamine catalysis is a prevalent strategy for the functionalization of aldehydes/ketones with electrophiles. Recently, the advent and development of oxidative…”
Get full text

Catalytic Enantioselective tert-Aminocyclization by Asymmetric Binary Acid Catalysis (ABC): Stereospecific 1,5-Hydrogen Transfer by Chen, Liujuan, Zhang, Long, Lv, Jian, Cheng, Jin-Pei, Luo, Sanzhong

“…Selective H transfer by ABC: A new asymmetric binary acid catalyst was developed to promote 1,5‐H transfer specifically and stereoselectively in…”
Get full text

Enantioselective Diels-Alder reaction of anthracene by chiral tritylium catalysis by Zhang, Qichao, Lv, Jian, Luo, Sanzhong

“…The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active…”
Get full text

Enantioselective SN1-type reaction via electrochemically generated chiral α-Imino carbocation intermediate by Lin, Qifeng, Duan, Yingdong, Li, Yao, Jian, Ruijun, Yang, Kai, Jia, Zongbin, Xia, Yu, Zhang, Long, Luo, Sanzhong

“…Electrochemical reactions via carbocation intermediates remain fundamental transformations that build up molecular functionality and complexity in a…”
Get full text

Functionalized Chiral Ionic Liquids as Highly Efficient Asymmetric Organocatalysts for Michael Addition to Nitroolefins by Luo, Sanzhong, Mi, Xueling, Zhang, Long, Liu, Song, Xu, Hui, Cheng, Jin-Pei

“…Catalytic combination: By combining the advantages of organocatalysts and ionic liquids, a functionalized chiral ionic liquid such as 1 can act as a highly…”
Get full text

Bond Energies of Enamines by Li, Yao, Zhang, Long, Luo, Sanzhong

“…Energetics of reactive intermediates underlies their reactivity. The availability of these data provides a rational basis for understanding and predicting a…”
Get full text