Search Results - "Lunelli, Bruno"
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New, optimized preparation of 1,2-dichlorocyclobuten-3,4-dione (C 4O 2Cl 2) from squaric acid and oxalyl chloride
Published in Tetrahedron letters (14-05-2007)“…A very convenient, entropy-assisted preparation of this versatile compound. 1,2-Dichlorocyclobuten-3,4-dione, a key intermediate in the chemistry of…”
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Fluorine-substituted cyclobutenes in the solid state: Crystal structures, vibrational spectra and mechanical and thermodynamic properties
Published in The Journal of physics and chemistry of solids (01-01-2022)“…The crystal structures, infrared and Raman spectra, and mechanical and thermodynamic properties of four important fluorine-substituted cyclobutene derivatives…”
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3
Designing an Effective, Low-Cost, and Convenient Air-Cooled Semi-microscale and Small Scale Inverted Cone Vapor Condenser for Waterless Reflux Cooling
Published in Journal of chemical education (11-08-2020)“…The design and operation of an inverted cone, scalable vapor condenser, drawing cooling air from beyond the boundary layer and optionally working as a part of…”
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4
Designing an Effective, Low-Cost, and Convenient Air-Cooled Semi-Microscale and Small Scale Inverted Cone Vapor Condenser for Waterless Reux Cooling
Published in Journal of chemical education (01-08-2020)“…The design and operation of an inverted cone, scalable vapor condenser, drawing cooling air from beyond the boundary layer and optionally working as a part of…”
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5
Setup for Semimicro Pressure Filtration
Published in Journal of chemical education (11-06-2019)“…Semimicro pressure filtration is carried out by pressurizing a suspension through pushing the piston of a gas-filled plastic syringe whose needle perforates…”
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6
Reactivity of Substituted Phenols Toward Alkyl Radicals
Published in Journal of the American Chemical Society (27-01-1999)“…The rate constants for the reaction of primary alkyl radicals with substituted phenolic compounds have been measured in benzene or toluene at room temperature…”
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7
Making and Using an in Situ Microfiltration Device
Published in Journal of chemical education (01-04-2010)Get full text
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8
Single pot sequential crystallization–distillation as a new purification procedure
Published in Inorganica Chimica Acta (15-02-2007)“…Sequential exploitation of different phase equilibria on the same sample provides a widely applicable purification procedure. A new purification procedure…”
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Thermodynamic Mysteries
Published in Journal of chemical education (01-01-2009)“…Commentary on an earlier article regarding "mysteries" of the first and second laws of thermodynamics…”
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pH Basics
Published in Journal of chemical education (01-02-2009)“…The exposition of the pervasive concept of pH, of its foundations and implementation as a meaningful quantitative measurement, in nonspecialist university…”
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11
Rationalizing the Effect of Halogenation on the Molecular Structure of Simple Cyclobutene Derivatives by Topological Real-Space Analysis of Their Electron Density
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-11-2011)“…The accurate gas-phase equilibrium structures on the ground-state potential energy surface of the complete series of fluorinated and chlorinated cyclobutene…”
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12
Effect of Methoxy Substituents on the Structural and Electronic Properties of Fluorinated Cyclobutenes: A Study of Hexafluorocyclobutene and Its Vinyl Methoxy Derivatives by XRD and Periodic DFT Calculations
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-04-2009)“…The effect of the methoxy substituent on the structure, crystal packing, and electrostatic properties of hexafluorocyclobutene (C4F6) was investigated in the…”
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13
The Puzzle of Bond Length Variation in Substituted Cyclobutenes. A New Example: Molecular Structure and Conformations of 1,2-Dimethoxy-3,3,4,4-tetrafluorocyclobut-1-ene
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (29-04-2010)“…The structure and composition of 1,2-dimethoxy-3,3,4,4-tetrafluorocyclobut-1-ene (DMCB) have been measured by electron diffraction from the gas at a…”
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14
Molecular structure and conformations of 1-methoxy-2,3,3,4,4-pentafluorocyclobut-1-ene
Published in Journal of molecular structure (20-08-2010)“…The structure of 1-monomethoxy-2,3,3,4,4-pentafluorocyclobut-1-ene (F5MCB) has been studied as a part of a series of investigations of the structures of…”
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15
Useful Work of a Process
Published in Journal of chemical education (01-05-2006)“…Clarifies a potentially misleading statement in the article, “Let’s Drive ‘Driving Force’ Out of Chemistry.”…”
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Redundant Assumption
Published in Journal of chemical education (01-09-2004)“…The very useful article “On the Importance of Ideality” reports that “The ideal gas is defined by the two relations." This is redundant, because eq 1 implies…”
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Partial Pressure Curve
Published in Journal of chemical education (01-09-2004)“…Figure 2 in the article "An Introduction to the Understanding of Solubility" is incorrect because when the molar fraction approaches unity, the partial vapor…”
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18
Interaction of Bovine Serum Albumin with Chrysotile: Spectroscopic and Morphological Studies
Published in Chemistry : a European journal (20-02-2006)“…The biodurability of chrysotile fibers, which is related to their cytotoxicity and mutagenic responses, is strongly affected by the surface chemical adsorption…”
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19
A Mechanical Analogue of Monotropism: Ordering of an Ensemble of Hemispheres
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (22-03-2001)“…An ensemble of randomly oriented, noninteracting, homogeneous, solid, inelastic, identical hemispheres in the gravitational field, having dropped on a rigid…”
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Gas Permeability of Polymers
Published in Journal of chemical education (01-10-2005)“…The recent article, “Applying Chemical Potential and Partial Pressure Concepts To Understand the Spontaneous Mixing of Helium and Air in a Helium-Inflated…”
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